发明授权
- 专利标题: Process for the preparation of methionine
- 专利标题(中): 制备甲硫氨酸的方法
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申请号: US14850207申请日: 2015-09-10
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公开(公告)号: US09464045B2公开(公告)日: 2016-10-11
- 发明人: Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
- 申请人: Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
- 申请人地址: DE Essen
- 专利权人: EVONIK DEGUSSA GmbH
- 当前专利权人: EVONIK DEGUSSA GmbH
- 当前专利权人地址: DE Essen
- 代理机构: Oblon, McClelland, Maier & Neustadt, L.L.P.
- 优先权: EP12160257 20120320
- 主分类号: C07C319/28
- IPC分类号: C07C319/28 ; C07C319/20 ; C07C319/26 ; C07C319/12 ; C07C323/52
摘要:
This disclosure relates to a process for preparing D,L-methionine by feeding carbon dioxide to an aqueous potassium methioninate solution obtained by hydrolysis of 5-(2-methylmercaptoethyl)hydantoin, in order to precipitate out crude methionine, which is separated off and purified. In this process an aqueous solution of the separated-off crude methionine is purified by recrystallization from a solution containing potassium ions and also a crystallization additive. The crystallization additive is a nonionic or anionic surfactant, or a mixture of different nonionic or anionic surfactants. The recrystallization occurs by introducing a 60 to 110° C.-hot methionine solution into a 35 to 80° C.-warm methionine suspension, a temperature of which is lower than that of the introduced solution, such that the temperature of the methionine suspension being maintained between 35 and 80° C. during the addition. The crystallization additive is a sorbitan fatty acid ester or a mixture of different sorbitan fatty acid esters.
公开/授权文献
- US20160068480A1 PROCESS FOR THE PREPARATION OF METHIONINE 公开/授权日:2016-03-10
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