Invention Grant
- Patent Title: Method for producing a blank of fluorine-doped and titanium-doped glass having a high silicic-acid content and a blank produced according to the method
- Patent Title (中): 根据该方法制造具有高硅酸含量的氟掺杂和钛掺杂玻璃的坯料的方法
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Application No.: US14862707Application Date: 2015-09-23
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Publication No.: US09568818B2Publication Date: 2017-02-14
- Inventor: Stefan Ochs , Klaus Becker
- Applicant: Heraeus Quarzglas GmbH & Co. KG
- Applicant Address: DE Hanau
- Assignee: Heraeus Quarzglas GmbH & Co. KG
- Current Assignee: Heraeus Quarzglas GmbH & Co. KG
- Current Assignee Address: DE Hanau
- Agency: Panitch Schwarze Belisario & Nadel LLP
- Priority: EP14186139 20140924
- Main IPC: C03C3/06
- IPC: C03C3/06 ; G03F1/22 ; C03B19/06 ; C03C3/04 ; C03B19/14 ; C03C23/00 ; C03B32/00 ; G03F7/00

Abstract:
A method for producing a silica glass blank co-doped with titanium and fluorine for use in EUV lithography includes (a) producing a TiO2—SiO2 soot body by flame hydrolysis of silicon- and titanium-containing precursor substances, (b) fluorinating the TiO2—SiO2 soot body to form a fluorine-doped TiO2—SiO2 soot body, (c) treating the fluorine-doped TiO2—SiO2 soot body in a water vapor-containing atmosphere to form a conditioned soot body, and (d) vitrifying the conditioned soot body to form the blank. The blank has an internal transmission of at least 60% in the wavelength range of 400 to 700 nm at a sample thickness of 10 mm, a mean OH content in the range of 10 to 100 wt. ppm and a mean fluorine content in the range of 2,500 to 10,000 wt. ppm. Titanium is present in the blank in the oxidation forms Ti3+ and Ti4+.
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