There is provided a multilayer ceramic electronic component including: a ceramic body in which internal electrodes and dielectric layers containing a barium titanate-based compound containing calcium (Ca) are alternately stacked; and external electrodes disposed on outer surfaces of the ceramic body and electrically connected to the internal electrodes. The dielectric layer includes interfacial portions adjacent to the internal electrodes and a central portion disposed between the interfacial portions, the interfacial portion having a calcium (Ca) concentration higher than that of the central portion.