发明授权
- 专利标题: Method for continuously preparing biodegradable aliphatic/aromatic polyester copolymer
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申请号: US14423641申请日: 2013-05-20
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公开(公告)号: US09637589B2公开(公告)日: 2017-05-02
- 发明人: Gyung Don Kang , Ki Chull Yun , Sang Yob Kim , Kil Seuk Byun , Jung Ryum , Boo Seong Kim , Sei Hoon Kim , Sung Bae Park
- 申请人: LOTTE FINE CHEMICAL CO., LTD. , S-ENPOL CO., LTD.
- 申请人地址: KR KR
- 专利权人: LOTTE FINE CHEMICAL CO., LTD.,S-ENPOL CO., LTD.
- 当前专利权人: LOTTE FINE CHEMICAL CO., LTD.,S-ENPOL CO., LTD.
- 当前专利权人地址: KR KR
- 代理机构: Fitch Even Tabin & Flannery LLP
- 优先权: KR10-2012-0097877 20120904
- 国际申请: PCT/KR2013/004389 WO 20130520
- 国际公布: WO2014/038774 WO 20140313
- 主分类号: C08G64/00
- IPC分类号: C08G64/00 ; C08G63/78 ; C08G63/181 ; C08G63/02
摘要:
Provided is a method of continuous preparation of a biodegradable aliphatic/aromatic polyester copolymer, the method including: performing a first esterification reaction of an aliphatic dihydroxy compound and an aliphatic dicarboxylic acid at a temperature of 185° C. or less; continuously performing a second esterification reaction of a reaction product obtained by the first esterification reaction; obtaining a pre-polymer by continuously performing a first polycondensation reaction of a reaction product obtained by the second esterification reaction; and continuously performing polycondensation reaction of the pre-polymer, wherein an aromatic carboxylic acid is added to a reactor in which the first esterification reaction or the second esterification reaction is performed, to prepare the biodegradable aliphatic/aromatic polyester copolymer. According to the method of continuous preparation of the biodegradable aliphatic/aromatic polyester copolymer as described above, the amount of the aliphatic dihydroxy compound used, which is a starting material, is reduced and accordingly, manufacturing costs are reduced.
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