Advantageous films and coatings (e.g., transparent conductive films), and improved methods for fabricating such films and/or coatings, are provided. The improved methods for fabricating transparent conductive films/coatings may involve trapping at least a portion of a layered material (e.g., graphene sheet(s) or layer(s) of graphite) at an interface of a phase separated system (e.g., at an interface of two non-mixing solvents). Transparent, one to four layer, conductive films/coatings of pristine natural flake graphene are produced by kinetically trapping graphene sheets at an interface of a phase separated system (e.g., at an oil/water interface).