Systems and methods for sensing fuel vapor pressure are provided. In one example, a method for a vehicle comprises: during an engine start after the engine has been off for at least a minimum duration, actively controlling fuel pressure in the fuel system to a vapor-liquid volume ratio greater than zero and then recording sensed fuel pressure and temperature in the fuel system. In this way, the vapor pressure of a fuel at a given temperature may be accurately measured during isothermal conditions, thereby improving an estimation of fuel volatility.