A Zr-based amorphous alloy is provided; the formula of the Zr-based amorphous alloy is (Zr, Hf, Nb)aCubNicAldRee, where a, b, c, d, and e are corresponding atomic percent content of elements in the Zr-based amorphous alloy, 45≦a≦65, 15≦b≦40, 0.1≦c≦15, 5≦d≦15, 0.05≦e≦5, a+b+c+d+e≦100, and Re is one of or any combination of elements La, Ce, Po, Ho, Er, Nd, Gd, Dy, Sc, Eu, Tm, Tb, Pr, Sm, Yb, and Lu, or Re is combined with Y and one of or any combination of elements La, Ce, Po, Ho, Er, Nd, Gd, Dy, Sc, Eu, Tm, Tb, Pr, Sm, Yb, and Lu.