- 专利标题: Use of a catalyst comprising a phosphorous modified zeolite in an alcohol dehydration process
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申请号: US14236726申请日: 2012-07-25
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公开(公告)号: US09862653B2公开(公告)日: 2018-01-09
- 发明人: Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
- 申请人: Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
- 申请人地址: FR Rueil Malmaison BE Seneffe
- 专利权人: IFP ENERGIES NOUVELLES,TOTAL RESEARCH & TECHNOLOGY FELUY
- 当前专利权人: IFP ENERGIES NOUVELLES,TOTAL RESEARCH & TECHNOLOGY FELUY
- 当前专利权人地址: FR Rueil Malmaison BE Seneffe
- 代理商 Albert Shung
- 优先权: EP11290360 20110803
- 国际申请: PCT/EP2012/064579 WO 20120725
- 国际公布: WO2013/017496 WO 20130207
- 主分类号: C07C1/24
- IPC分类号: C07C1/24 ; B01J37/10 ; B01J37/28 ; B01J29/40 ; B01J29/85
摘要:
A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.
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