摘要:
A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.
摘要:
A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.
摘要:
A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译:描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料,每个所述球形颗粒由基于氧化硅和氧化铝的基体构成,孔径在1.5至30nm的范围内,Si / Al 摩尔比至少为1,具有厚度在1至20nm范围内的非晶壁,所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
摘要:
The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要:
A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.
摘要:
The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.
摘要:
The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.
摘要:
The invention concerns a process for producing middle distillates from effluents obtained by Fischer-Tropsch synthesis, comprising a step for hydrotreatment and purification and/or decontamination by passage over a multifunctional guard bed. The invention also concerns a facility.
摘要:
A combustion catalyst comprising a monolithic substrate, a porous support based on refractory inorganic oxide and an active phase formed by cerium, iron and at least one metal selected from the group formed by palladium and platinum, the content of porous support being between 100 and 400 g per liter of catalyst; the content of cerium being between 0.3 and 20% by weight with respect to the porous support; the content of iron being between 0.01 and 3.5% of iron by weight with respect to the porous support; and the content of palladium and/or platinum being between 3 and 20 g per liter of catalyst. The catalyst of the invention is used in particular in processes for the catalytic combustion of hydrocarbons, carbon monoxide, hydrogen or mixtures thereof, in processes involving one or more catalytic stages.
摘要:
Described is a process of catalytic combustion with staged fuel injection that comprises: a first injection of fuel and air, the passage of the air-fuel mixture that is formed into a catalytic zone, and a second fuel injection into the flow of output from said catalytic zone; with said process being characterized in that said catalytic zone comprises at least one catalyst that comprises a monolithic substrate, a porous support based on a refractory inorganic oxide, and an active phase that comprises cerium, iron, and optionally zirconium, as well as at least one metal that is selected from the group that is formed by palladium and platinum; the content of porous support is between 100 and 400 g per liter of catalyst; the cerium content is between 0.3 and 20% by weight relative to the porous support; the zirconium content is between 0 and 20% by weight relative to the porous support; with the iron content being between 0.01 and 3.5% by weight of iron relative to the porous support; and the palladium and/or platinum content is greater than 3 g per liter of catalyst. The process that uses such a catalyst produces improved performance levels by avoiding the fluctuating nature of combustion and the deactivation of the catalyst.