- 专利标题: Method for preparing methyl formate and coproducing dimethyl ether
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申请号: US15526868申请日: 2014-11-17
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公开(公告)号: US09938227B2公开(公告)日: 2018-04-10
- 发明人: Youming Ni , Wenliang Zhu , Yong Liu , Hongchao Liu , Zhongmin Liu , Lina Li , Shiping Liu , Hui Zhou
- 申请人: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- 申请人地址: CN Liaoning Province
- 专利权人: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- 当前专利权人: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- 当前专利权人地址: CN Liaoning Province
- 代理机构: Nath, Goldberg & Meyer
- 代理商 Tanya E. Harkins; Stanley N. Protigal
- 国际申请: PCT/CN2014/091291 WO 20141117
- 国际公布: WO2016/077968 WO 20160526
- 主分类号: C07C69/00
- IPC分类号: C07C69/00 ; C07C67/39 ; C07C67/00 ; C07C69/06 ; C07C41/50 ; C07C43/04 ; C07C43/30 ; B01J39/05 ; B01J29/08 ; B01J29/18 ; B01J29/40 ; B01J29/65 ; B01J29/70 ; B01J31/10 ; B01J39/20 ; C07C41/18
摘要:
Method for preparing methyl formate and coproducing dimethyl ether by reacting a formaldehyde and methanol raw material (molar ratio range of 1:4 to 1:0.05) in a First Reaction Region at ranges from 50° C. to 100° C. with Catalyst A resulting in post-reaction material separated into Constituent I. Reacting Constituent I in a Second Reaction Region at ranges from 50° C. to 200° C. and from 0.1 MPa to 10 MPa with Catalyst B resulting in post-reaction material, which is separated into methyl formate, dimethyl ether and Constituent II. At least 1% of dimethyl ether is product, and recycling the rest to the First Reaction Region. Constituent II is recycled to the Second Reaction Region. Each component is gaseous phase and/or liquid phase, independently. The method shows long catalyst life, mild reaction condition, high utilization ratio of raw materials, continuous production and large scale industrial application potential.
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