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公开(公告)号：US10059649B2
公开(公告)日：2018-08-28
申请号：US15103076
申请日：2013-12-16
发明人： Yong Liu , Wenliang Zhu , Hongchao Liu , Youming Ni , Zhongmin Liu , Shuanghe Meng , Lina Li , Shiping Liu , Hui Zhou
IPC分类号： C07C29/154 , C07C29/149 , B01J23/72 , B01J23/78 , B01J23/80 , B01J23/86 , B01J23/889 , C07C29/156
CPC分类号： C07C29/154 , B01J23/72 , B01J23/78 , B01J23/80 , B01J23/868 , B01J23/8892 , C07C29/149 , C07C29/156 , C07C2521/04 , C07C2521/10 , C07C2523/02 , C07C2523/06 , C07C2523/26 , C07C2523/28 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2523/755 , Y02P20/52 , C07C31/04 , C07C31/08
摘要： A method for producing ethanol and coproducing methanol on a catalyst in a reactor using a co-feed of a synthesis gas and acetate as a reaction raw material comprising passing a raw material gas containing an acetate and a synthesis gas through a reactor loaded with a catalyst to produce ethanol and coproduce methanol under conditions of a reaction temperature of 150-350° C., a reaction pressure of 0.1-20.0 MPa, a reaction volume hourly space velocity of 100-45000 mlg−1h−1, and an acetate weight hourly space velocity of 0.01-5.0 h−1; and the active components of the catalyst are copper and optionally zinc and/or aluminum, which greatly facilitates the conversion of carbon monoxide to methanol, while an extremely high activity of acetate hydrogenation is maintained.
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2.发明授权公开(公告)号：US09708240B2
公开(公告)日：2017-07-18
申请号：US15105364
申请日：2013-12-23
发明人： Youming Ni , Wenliang Zhu , Hongchao Liu , Yong Liu , Zhongmin Liu , Shuanghe Meng , Lina Li , Shiping Liu , Hui Zhou
IPC分类号： C07C67/37 , C07C67/38 , C07C69/708
CPC分类号： C07C67/37 , C07C67/38 , C07C69/708
摘要： A method for preparing a polyoxymethylene dimethyl ether carbonyl compound and/or methyl methoxyacetate as intermediates for producing ethylene glycol, which comprises passing a raw material: polyoxymethylene dimethyl ether or methylal together with carbon monoxide and hydrogen gas through a reactor carrying an acidic molecular sieve catalyst, and performing a reaction to prepare a corresponding product under an appropriate condition where no other solvent is added, in which the process of the reaction is a gas-liquid-solid three-phase reaction, the raw material of polyoxymethylene dimethyl ether or methylal has a high conversion rate, each product has a high selectivity, the catalyst has a long service life, additional solvents are not required to be used, and reaction conditions are relatively mild.
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公开(公告)号：US09440226B2
公开(公告)日：2016-09-13
申请号：US14650589
申请日：2014-01-28
发明人： Youming Ni , Wenliang Zhu , Hongchao Liu , Yong Liu , Zhongmin Liu , Shuanghe Meng , Lina Li , Shiping Liu , Hui Zhou
CPC分类号： B01J31/0244 , B01J29/18 , B01J31/0237 , B01J31/0238 , B01J37/0203 , B01J2229/34 , C07C67/37 , C07C69/14
摘要： The present invention provides a method for preparing methyl acetate, in which a feed gas containing an organic amine, dimethyl ether, carbon monoxide and optional hydrogen gas goes through a reactor loaded with a H-type mordenite catalyst, to produce methyl acetate; wherein said H-type mordenite catalyst is a H-type mordenite catalyst with adsorption of an organic amine. The method in the present invention improves the catalyst stability and prolongs the catalyst life, by using the H-type mordenite catalyst with adsorption of an organic amine as the catalyst and adding the organic amine in the feed gas to replenish the organic amine desorbed from the catalyst during the reaction.
摘要翻译： 本发明提供了一种制备乙酸甲酯的方法，其中含有有机胺，二甲醚，一氧化碳和任选的氢气的进料气体经过负载有H型丝光沸石催化剂的反应器，生产乙酸甲酯; 其中所述H型丝光沸石催化剂是吸附有机胺的H型丝光沸石催化剂。 本发明的方法通过使用H型丝光沸石催化剂吸附有机胺作为催化剂，并在进料气体中加入有机胺，从而提高催化剂的稳定性并延长催化剂寿命，从而补充从 催化剂。
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公开(公告)号：US10040739B2
公开(公告)日：2018-08-07
申请号：US15537928
申请日：2014-12-22
发明人： Youming Ni , Wenliang Zhu , Hongchao Liu , Yong Liu , Zhongmin Liu , Lina Li , Shiping Liu , Hui Zhou
摘要： Disclosed is a method for preparing a double end capped glycol ether, the method comprising: introducing into a reactor a raw material comprising a glycol monoether and a monohydric alcohol ether, and enabling the raw material to contact and react with an acidic molecular sieve catalyst to generate a double end capped glycol ether, a reaction temperature being 50-300° C., a reaction pressure being 0.1-15 MPa, a WHSV of the glycol monoether in the raw material being 0.01-15.0 h−1 , and a mole ratio of the monohydric alcohol ether to the glycol monoether in the raw material being 1-100:1. The method of the present invention enables a long single-pass lifespan of the catalyst and repeated regeneration, has a high yield and selectivity of a target product, low energy consumption during separation of the product, a high economic value of a by-product, and is flexible in production scale and application.
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公开(公告)号：US09944588B2
公开(公告)日：2018-04-17
申请号：US15526780
申请日：2014-11-17
发明人： Youming Ni , Wenliang Zhu , Yong Liu , Hongchao Liu , Zhongmin Liu , Lina Li , Shiping Liu , Hui Zhou
IPC分类号： C07C69/00 , C07C69/06 , C07C67/39 , B01D3/14 , B01J29/70 , B01J29/40 , C07C53/02 , C07C43/10 , C07C43/04 , C08F212/36 , C08F212/08
CPC分类号： C07C69/06 , B01D3/14 , B01J29/40 , B01J29/7038 , C07C41/56 , C07C43/043 , C07C43/10 , C07C53/02 , C07C67/39 , C08F212/08 , C08F212/36 , C07C43/30
摘要： A method for preparing methyl formate in which a raw material containing formaldehyde, methanol and/or dimethyl ether is introduced into a first reaction zone to come into contact with a catalyst A, and a component I is obtained by separation, the component I is introduced into a second reaction zone to come into contact with a catalyst B so as to obtain, by separation, methyl formate as a product, dimethyl ether that is returned to the first reaction zone and a component II that is returned to the second reaction zone, the catalysts have a long service life, the reaction conditions are mild, and the utilization rate of the raw material is high, thus enabling a continuous production for large-scale industrial application.
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公开(公告)号：US09938227B2
公开(公告)日：2018-04-10
申请号：US15526868
申请日：2014-11-17
发明人： Youming Ni , Wenliang Zhu , Yong Liu , Hongchao Liu , Zhongmin Liu , Lina Li , Shiping Liu , Hui Zhou
IPC分类号： C07C69/00 , C07C67/39 , C07C67/00 , C07C69/06 , C07C41/50 , C07C43/04 , C07C43/30 , B01J39/05 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/70 , B01J31/10 , B01J39/20 , C07C41/18
CPC分类号： C07C67/39 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J29/7038 , B01J31/10 , B01J39/05 , B01J39/20 , B01J2231/50 , B01J2231/70 , C07C41/18 , C07C41/50 , C07C43/04 , C07C43/30 , C07C67/00 , C07C69/06
摘要： Method for preparing methyl formate and coproducing dimethyl ether by reacting a formaldehyde and methanol raw material (molar ratio range of 1:4 to 1:0.05) in a First Reaction Region at ranges from 50° C. to 100° C. with Catalyst A resulting in post-reaction material separated into Constituent I. Reacting Constituent I in a Second Reaction Region at ranges from 50° C. to 200° C. and from 0.1 MPa to 10 MPa with Catalyst B resulting in post-reaction material, which is separated into methyl formate, dimethyl ether and Constituent II. At least 1% of dimethyl ether is product, and recycling the rest to the First Reaction Region. Constituent II is recycled to the Second Reaction Region. Each component is gaseous phase and/or liquid phase, independently. The method shows long catalyst life, mild reaction condition, high utilization ratio of raw materials, continuous production and large scale industrial application potential.
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