- Patent Title: Method for preparing methyl formate and coproducing dimethyl ether
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Application No.: US15526868Application Date: 2014-11-17
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Publication No.: US09938227B2Publication Date: 2018-04-10
- Inventor: Youming Ni , Wenliang Zhu , Yong Liu , Hongchao Liu , Zhongmin Liu , Lina Li , Shiping Liu , Hui Zhou
- Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Applicant Address: CN Liaoning Province
- Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Current Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Current Assignee Address: CN Liaoning Province
- Agency: Nath, Goldberg & Meyer
- Agent Tanya E. Harkins; Stanley N. Protigal
- International Application: PCT/CN2014/091291 WO 20141117
- International Announcement: WO2016/077968 WO 20160526
- Main IPC: C07C69/00
- IPC: C07C69/00 ; C07C67/39 ; C07C67/00 ; C07C69/06 ; C07C41/50 ; C07C43/04 ; C07C43/30 ; B01J39/05 ; B01J29/08 ; B01J29/18 ; B01J29/40 ; B01J29/65 ; B01J29/70 ; B01J31/10 ; B01J39/20 ; C07C41/18

Abstract:
Method for preparing methyl formate and coproducing dimethyl ether by reacting a formaldehyde and methanol raw material (molar ratio range of 1:4 to 1:0.05) in a First Reaction Region at ranges from 50° C. to 100° C. with Catalyst A resulting in post-reaction material separated into Constituent I. Reacting Constituent I in a Second Reaction Region at ranges from 50° C. to 200° C. and from 0.1 MPa to 10 MPa with Catalyst B resulting in post-reaction material, which is separated into methyl formate, dimethyl ether and Constituent II. At least 1% of dimethyl ether is product, and recycling the rest to the First Reaction Region. Constituent II is recycled to the Second Reaction Region. Each component is gaseous phase and/or liquid phase, independently. The method shows long catalyst life, mild reaction condition, high utilization ratio of raw materials, continuous production and large scale industrial application potential.
Public/Granted literature
- US20170320807A1 Method for Preparing Methyl Formate and Coproducing Dimethyl Ether Public/Granted day:2017-11-09
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