Invention Grant
- Patent Title: Process for preparing a furan-based polyamide, a furan-based oligomer and compositions and articles comprising the furan-based polyamide
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Application No.: US15029296Application Date: 2014-10-21
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Publication No.: US09938376B2Publication Date: 2018-04-10
- Inventor: Ate Duursma , Rene Aberson , Dee Dee Smith , Joel Flores , Matheus Adrianus Dam , Gerardus Johannes Maria Gruter
- Applicant: Furanix Technologies B.V.
- Applicant Address: NL Amsterdam
- Assignee: Synvina C.V.
- Current Assignee: Synvina C.V.
- Current Assignee Address: NL Amsterdam
- Agency: Hoffmann & Baron, LLP
- Priority: NL2011656 20131021
- International Application: PCT/NL2014/050732 WO 20141021
- International Announcement: WO2015/060718 WO 20150430
- Main IPC: C08L77/00
- IPC: C08L77/00 ; C08G69/26 ; C08G69/28 ; C08L77/06 ; C08J5/18 ; C08K11/00 ; C09D177/06

Abstract:
A furan-based polyamide is prepared by the following steps: (1) preparing a furan-based oligomer of formula (1) H2N—R—(NH—CO—F—CO—NH—R)n—NH2 (1) where R is a hydrocarbon moiety and F is a furan (cyclo-C4H2O) moiety and n represents the average degree of oligomerization, and where n is within the range of 1 to 10 by reacting 2,5-furandicarboxylic acid or its derivative with a diamine at a temperature of at most 100° C.; (2) contacting the oligomer of step (1) with a bifunctional linker selected from an acid or a derivative thereof where the acid is furandicarboxylic acid or a non-aromatic dicarboxylic acid; provided that if the hydrocarbon moiety R is aromatic, then the bifunctional linker is an aromatic dicarboxylic acid or a derivative thereof, at a mole ratio of the oligomer to the difunctional linker within the range of 0.8 to 1.5 at polycondensation conditions, and (3) isolating the resulting polyamide.
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