发明授权
- 专利标题: Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
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申请号: US15033203申请日: 2014-10-27
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公开(公告)号: US09963408B2公开(公告)日: 2018-05-08
- 发明人: Philipp Grüne , Oliver Hammen , Christine Schmitt , Ragavendra Prasad Balegedde Ramachandran , Jan Pablo Josch , Christian Walsdorff
- 申请人: BASF SE
- 申请人地址: DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE
- 代理机构: Drinker Biddle & Reath LLP
- 优先权: EP13190897 20131030
- 国际申请: PCT/EP2014/072978 WO 20141027
- 国际公布: WO2015/063019 WO 20150507
- 主分类号: C07C5/48
- IPC分类号: C07C5/48 ; B01J23/00 ; B01J23/887 ; C07C7/08 ; C07C7/11 ; B01J37/00
摘要:
A process for preparing butadiene from n-butenes, comprising the steps of: absorbing C4 hydrocarbons comprising butadiene and n-butenes, obtained from oxidative dehydrogenation of n-butenes, in an aromatic hydrocarbon solvent as an absorbent and removing uncondensable and low-boiling gas constituents comprising oxygen, low-boiling hydrocarbons, any carbon oxides, aromatic hydrocarbon solvent and any inert gases as gas stream d2, giving an absorbent stream laden with C4 hydrocarbons and the gas stream d2, and then desorbing the C4 hydrocarbons from the laden absorbent stream, giving a C4 product gas stream d1; and at least partly recycling the gas stream d2 as cycle gas stream a2 into the oxidative dehydrogenation zone, wherein the content of aromatic hydrocarbon solvent in the cycle gas stream a2 is limited to less than 1% by volume.
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