Invention Application
- Patent Title: OLEFIN POLYMERIZATION CATALYST AND METHODS
- Patent Title (中): 烯烃聚合催化剂和方法
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Application No.: PCT/US1991002900Application Date: 1991-04-26
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Publication No.: WO1991017190A1Publication Date: 1991-11-14
- Inventor: QUANTUM CHEMICAL CORPORATION , MASINO, Albert, P.
- Applicant: QUANTUM CHEMICAL CORPORATION
- Assignee: QUANTUM CHEMICAL CORPORATION
- Current Assignee: QUANTUM CHEMICAL CORPORATION
- Priority: US516,754 19900430
- Main IPC: C08F04/64
- IPC: C08F04/64
Abstract:
A solid catalyst component, a method of making the same, a catalyst system incorporating the solid catalyst component, and a method of polymerizing one or more 1-olefins using the catalyst system are disclosed wherein the catalyst component is prepared by contacting, in the presence of an inert liquid hydrocarbon, silica, a soluble organomagnesium compound, an SiCl4 magnesium fixing agent, an alcohol, TiCl4, and a diester compound, followed by extraction with a TiCl4-containing extraction liquid. The inventive catalyst system allows ready control of product molecular weight by control of hydrogen concentration in the reactor, and allows the production of high MI or MF polymers at high productivities.
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