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    PROPYLENE POLYMERIZATION CATALYST AND METHOD
    1.
    发明申请
    PROPYLENE POLYMERIZATION CATALYST AND METHOD 审中-公开
    丙烯聚合催化剂和方法

    公开(公告)号：WO1989000584A1

    公开(公告)日：1989-01-26

    申请号：PCT/US1988002295

    申请日：1988-07-08

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  BUEHLER, Charles, K. ,  SENGER, Cindy, S. ,  JOHNSON, Kenneth, W.

    IPC: C08F04/64

    CPC classification number: C08F10/00 ,  C08F2/50 ,  C08F110/06 ,  C08F4/616 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18

    Abstract: A catalyst component useful in propylene polymerization in combination with a dialkyl aluminum halide cocatalyst comprises the product of reaction of TiCl3 which is substantially free of extraneous halide with a selected electron donor compound which is dissolved in a liquid hydrocarbon solvent in which the TiCl3 is dispersed. The electron donor compound is selected from certain organic acid esters, hindered phenolic compounds and silyl esters. The catalyst of the invention provides increased activity, molecular weight control, increased isotacticity of propylene polymer products and prevents catalyst feed line pluggage, among other advantages.

    Abstract translation: 用于丙烯聚合的二烷基卤化铝助催化剂的催化剂组分包括基本上不含外来卤化物的TiCl 3与溶解在其中分散有TiCl 3的液态烃溶剂中的选定电子给体化合物的反应产物。 电子给体化合物选自某些有机酸酯，受阻酚化合物和甲硅烷基酯。 本发明的催化剂提供了增加的活性，分子量控制，增加的丙烯聚合物产物的全同立构规整度，并且防止了催化剂进料线插入物以及其它优点。

    BIAXIALLY-ORIENTED POLYPROPYLENE FILMS
    2.
    发明申请
    BIAXIALLY-ORIENTED POLYPROPYLENE FILMS 审中-公开
    双向聚对苯二甲酸乙二醇酯膜

    公开(公告)号：WO1996027491A1

    公开(公告)日：1996-09-12

    申请号：PCT/US1995002951

    申请日：1995-03-08

    Applicant: QUANTUM CHEMICAL CORPORATION ,  DAVIS, Alan, M. ,  KRIGAS, Thomas, M.

    Inventor： QUANTUM CHEMICAL CORPORATION

    IPC: B29C47/06

    CPC classification number: C08J5/18 ,  B29C55/023 ,  B29C55/12 ,  B29K2023/086 ,  B29K2023/12 ,  B29K2091/00 ,  B32B27/32 ,  C08J2323/10

    Abstract: A biaxially-oriented polypropylene (BOPP) film with improved barrier properties, and a method of making the film are provided. The MVTR of a multi-layer BOPP film is improved by blending wax in the core layer resin, and providing a polyolefin cap layer on each side of the core layer. Significant additional improvements are seen when the film is heated at a temperature below the melting point of the core layer resin, below the distortion temperature of the film, and above the melting point of the wax for a time generally extending from at least five minutes to several hours or more in length, depending on the temperature.

    Abstract translation: 提供了具有改进的阻挡性能的双轴取向聚丙烯（BOPP）膜以及制备该膜的方法。 多层BOPP膜的MVTR通过在芯层树脂中混合蜡而提高，并且在芯层的每一侧上提供聚烯烃盖层。 当薄膜在低于芯层树脂的熔点，低于膜的变形温度和高于蜡的熔点的温度下加热时，通常从至少五分钟延伸至 几个小时或更长的长度，取决于温度。

    SUPPORTED HIGH ACTIVITY POLYOLEFIN CATALYST COMPONENT WITH REGULAR DISTRIBUTION OF MAGNESIUM VALUES PROVIDED UTILIZING A CONTROLLED DRYING PROTOCOL
    3.
    发明申请
    SUPPORTED HIGH ACTIVITY POLYOLEFIN CATALYST COMPONENT WITH REGULAR DISTRIBUTION OF MAGNESIUM VALUES PROVIDED UTILIZING A CONTROLLED DRYING PROTOCOL 审中-公开
    支持的高活性聚烯烃催化剂组分，通过使用控制干燥协议提供的镁值的定期分布

    公开(公告)号：WO1993000368A1

    公开(公告)日：1993-01-07

    申请号：PCT/US1992005069

    申请日：1992-06-19

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  BUEHLER, Charles, K. ,  MASINO, Albert, P. ,  MENON, Raghu

    IPC: C08F04/654

    CPC classification number: C08F10/00 ,  C08F4/6565 ,  C08F4/6567 ,  C08F4/6578

    Abstract: A novel catalyst support and a method for preparation thereof, characterized by the presence of selected amounts of a hydrocarbon soluble magnesium-containing compound applied to the support relative to solvent, wherein a surface uniformly and essentially continuously moistened with the solvated magnesium compound is achieved in a condition of incipient precipitation to permit the formation of a regular essentially continuous distribution of the magnesium compound onto and conforming to the support material. The drying process under these conditions is effective in maintaining to a high degree the effective surface area and pore volume of the material. The support containing the adsorbed magnesium in then dried in a controlled manner to essential incipient wetness conditions providing a regular spatial distribution of stacked reticular magnesium values at a level of one to five molecular monolayers on the support. A representative process for polymerizing or copolymerizing olefins providing stereospecific polymers such as propylene is disclosed.

    Abstract translation: 一种新颖的催化剂载体及其制备方法，其特征在于相对于溶剂存在选择量的可溶于烃的可溶性镁化合物，其中用溶剂化镁化合物均匀且基本上连续润湿的表面在 初始沉淀的条件允许形成规则的基本上连续的镁化合物分布到载体材料上并与之相符合。 在这些条件下的干燥过程有效地保持材料的有效表面积和孔体积的高度。 含有吸附的镁的载体以受控的方式干燥以达到必需的初始湿度条件，从而提供在载体上1-5个分子单层水平的堆叠网状镁值的规则空间分布。 公开了提供立体特异性聚合物如丙烯的烯烃聚合或共聚的代表性方法。

    MIXED CHROMIUM CATALYSTS AND POLYMERIZATIONS UTILIZING SAME
    4.
    发明申请
    MIXED CHROMIUM CATALYSTS AND POLYMERIZATIONS UTILIZING SAME 审中-公开
    混合的铬催化剂和使用它们的聚合物

    公开(公告)号：WO1992017511A1

    公开(公告)日：1992-10-15

    申请号：PCT/US1992002337

    申请日：1992-03-18

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  KATZEN, Stanley, J. ,  PULLUKAT, Thomas, J. ,  LYNCH, Michael, W. ,  REKERS, Louis, J.

    IPC: C08F04/648

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F2410/04 ,  C08F4/22 ,  C08F4/69 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/13 ,  C08F4/025

    Abstract: Mixed catalyst compositions comprised of a first supported chromium-containing catalyst component and a second supported chromium-containing catalyst component and which additionally have one or more metallic or non-metallic catalytic agents associated therewith are provided. The additional metallic or non-metallic elements associated with the catalyst components can be aluminium, titanium, zirconium, boron, phosphorous or combinations thereof. The pore volume of the silica supports used for the first and second catalyst components differs by at least 0.3 cc/g. The mixed catalyst compositions of the invention are useful for the preparation of polyolefins. They are particularly useful of polymerization of ethylene in particle form polymerizations to produce high density polyethylene blow molding resins having good processability and physical properties. The improved particle form polymerizations process and products obtained thereby using the above-described mixed catalyst compositions are also described.

    Abstract translation: 提供由第一负载的含铬催化剂组分和第二负载的含铬催化剂组分组成的并且另外具有与其相关的一种或多种金属或非金属催化剂的混合催化剂组合物。 与催化剂组分相关的另外的金属或非金属元素可以是铝，钛，锆，硼，磷或它们的组合。 用于第一和第二催化剂组分的二氧化硅载体的孔体积至少为0.3cc / g。 本发明的混合催化剂组合物可用于制备聚烯烃。 它们特别可用于以颗粒形式聚合的乙烯聚合，以生产具有良好加工性能和物理性能的高密度聚乙烯吹塑树脂。 还描述了改进的颗粒形式聚合方法和由此使用上述混合催化剂组合物获得的产物。

    VANADIUM-CONTAINING CATALYST SYSTEM
    5.
    发明申请
    VANADIUM-CONTAINING CATALYST SYSTEM 审中-公开
    含钒的催化剂体系

    公开(公告)号：WO1996031274A2

    公开(公告)日：1996-10-10

    申请号：PCT/US1996004367

    申请日：1996-03-29

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  WINSLOW, Linda, N. ,  KLENDWORTH, Douglas, D. ,  MENON, Raghu ,  LYNCH, Michael, W. ,  FIELDS, Garry, L. ,  JOHNSON, Kenneth, W.

    IPC: B01J00/00

    CPC classification number: B01J31/2226 ,  B01J31/128 ,  B01J31/143 ,  B01J31/1616 ,  B01J2531/56 ,  C08F10/00 ,  C08F210/16 ,  C08F4/68 ,  C08F210/14 ,  C08F2500/17

    Abstract: A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica or silica pretreated with hexaalkyldisilazane, with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group III metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. Where the catalyst system involves the preheated silica, the product of the step of contacting with compounds (1) and (2) is contacted with a vanadium compound which includes at least one halogen atom. Where the catalyst system involves the silica pretreated with hexaalkyldisilazane, the product of the step of contacting with compounds (1) and (2) is washed and then contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.

    Abstract translation: 一种特别适用于可吹塑烯烃聚合物聚合的含钒催化剂体系。 该催化剂体系包括通过将预处理的二氧化硅或六烷基二硅氮烷预处理的二氧化硅与（1）包含至少一个碳 - 镁共价键的化合物或络合物接触而制备的负载的第一催化剂组分和（2）包含至少一种 碳至III族金属共价键。 二氧化硅与化合物（1）和化合物（2）的接触顺序是任选的。 然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则该接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。 当催化剂体系涉及预热的二氧化硅时，与化合物（1）和（2）接触的步骤的产物与包含至少一个卤素原子的钒化合物接触。 当催化剂体系涉及用六烷基二硅氮烷预处理的二氧化硅时，将与化合物（1）和（2）接触的步骤的产物洗涤，然后与包含至少一个卤素原子的钒化合物接触。 最后，将钒化合物接触步骤的产物与醇接触。 催化剂体系的第二组分是有机铝化合物助催化剂。 催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。

    POLYMER-SUPPORTED CATALYST FOR OLEFIN POLYMERIZATION
    6.
    发明申请
    POLYMER-SUPPORTED CATALYST FOR OLEFIN POLYMERIZATION 审中-公开
    聚合物支持的烯烃聚合催化剂

    公开(公告)号：WO1996030122A1

    公开(公告)日：1996-10-03

    申请号：PCT/US1996004356

    申请日：1996-03-29

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  DiMAIO, Anthony-J. ,  MEVERDEN, Craig, C.

    IPC: B01J103/19

    CPC classification number: C08F10/00 ,  C08F4/027

    Abstract: The present invention is directed to a novel supported Ziegler-Natta catalyst useful for the polymerization of alpha -olefins. More specifically, the supported Ziegler-Natta catalyst of the present invention comprises a particulate functionalized copolymeric support, an organometallic compound and a transition metal compound. A novel method of preparing the particulate functionalized copolymeric supports of the instant invention is also provided.

    Abstract translation: 本发明涉及一种可用于α-烯烃聚合的新型载体齐格勒 - 纳塔催化剂。 更具体地，本发明的载体齐格勒 - 纳塔催化剂包含颗粒官能化共聚载体，有机金属化合物和过渡金属化合物。 还提供了制备本发明的颗粒状官能化共聚物载体的新方法。

    SUPPORTED POLYMERIZATION CATALYST
    7.
    发明申请
    SUPPORTED POLYMERIZATION CATALYST 审中-公开
    支持聚合催化剂

    公开(公告)号：WO1994025156A1

    公开(公告)日：1994-11-10

    申请号：PCT/US1994004381

    申请日：1994-04-21

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  BUEHLER, Charles, K.

    IPC: B01J31/00

    CPC classification number: B01J31/0214 ,  B01J31/0212 ,  B01J31/0274 ,  B01J31/128 ,  B01J31/143 ,  C08F10/00 ,  C08F4/025 ,  C08F4/651

    Abstract: A catalyst component useful in the polymerization of olefins is disclosed. The catalyst component comprises the product obtained by contacting silica with at least one magnesium-containing compound; contacting this product with a heterocyclic fused ring compound substituted with at least one oxygen atom and a modifying compound with the proviso that the heterocyclic compound and the modifying compound be present such that the molar ratio of the modifying compound to the heterocyclic compound is at least about 4:1; and contacting the product obtained with a titanium-containing compound having the structural formula TiXm(OR)n, where X is halogen; R is hydrocarbyl; m is an integer of 1 to 4; and n is 0 or an integer of 1 to 3 with the proviso that the sum of m and n is 4. A process for polymerizing alpha-olefins utilizing the above catalyst component and other components is described.

    Abstract translation: 公开了可用于烯烃聚合的催化剂组分。 催化剂组分包括通过使二氧化硅与至少一种含镁化合物接触而获得的产物; 使该产物与被至少一个氧原子取代的杂环稠环化合物和修饰化合物接触，条件是杂环化合物和改性化合物存在使得修饰化合物与杂环化合物的摩尔比至少约为 4：1; 并使所得产物与具有结构式TiXm（OR）n的含钛化合物接触，其中X为卤素; R是烃基; m为1〜4的整数。 并且n为0或1〜3的整数，条件是m和n的和为4.使用上述催化剂组分和其它组分聚合α-烯烃的方法。

    OLEFIN POLYMERIZATION CATALYST AND METHODS
    8.
    发明申请
    OLEFIN POLYMERIZATION CATALYST AND METHODS 审中-公开
    烯烃聚合催化剂和方法

    公开(公告)号：WO1991017190A1

    公开(公告)日：1991-11-14

    申请号：PCT/US1991002900

    申请日：1991-04-26

    Applicant: QUANTUM CHEMICAL CORPORATION

    Inventor： QUANTUM CHEMICAL CORPORATION ,  MASINO, Albert, P.

    IPC: C08F04/64

    CPC classification number: C08F10/00 ,  C08F4/6565

    Abstract: A solid catalyst component, a method of making the same, a catalyst system incorporating the solid catalyst component, and a method of polymerizing one or more 1-olefins using the catalyst system are disclosed wherein the catalyst component is prepared by contacting, in the presence of an inert liquid hydrocarbon, silica, a soluble organomagnesium compound, an SiCl4 magnesium fixing agent, an alcohol, TiCl4, and a diester compound, followed by extraction with a TiCl4-containing extraction liquid. The inventive catalyst system allows ready control of product molecular weight by control of hydrogen concentration in the reactor, and allows the production of high MI or MF polymers at high productivities.

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