Invention Application
WO01018082A1 RETROREFLECTIVE ARTICLES INCLUDING A CURED CERAMER COMPOSITE COATING
审中-公开
包括固化陶瓷复合涂层的回归文章
- Patent Title: RETROREFLECTIVE ARTICLES INCLUDING A CURED CERAMER COMPOSITE COATING
- Patent Title (中): 包括固化陶瓷复合涂层的回归文章
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Application No.: PCT/US2000/022390Application Date: 2000-08-07
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Publication No.: WO01018082A1Publication Date: 2001-03-15
- Main IPC: C08F2/44
- IPC: C08F2/44 ; C08F283/12 ; C08F290/14 ; C08L51/10 ; C09D4/00 ; C09D151/10 ; C09D183/08 ; E01F9/619 ; C08F292/00 ; C04B35/622 ; E01F9/015 ; G02B1/10
Abstract:
A retroreflective article comprising a substrate and a cured ceramer coating provided on at least a portion of a surface of the substrate. The coated portion of the surface is retroreflective. The coating comprises a cured ceramer composite derived from ingredients comprising a free radically curable binder precursor and a plurality of surface treated, colloidal inorganic oxide components. The colloidal inorganic oxide components are surface treated with a surface treatment agent comprising a fluoro/silane component comprising a hydrolyzable silane moiety and a fluorinated moiety, and a crosslinkable silane component comprising a hydrolyzable silane moiety and a free radically crosslinkable moiety. The weight ratio of the crosslinkable silane component to the fluoro/silane component is from about 4:1 to 20:1, and the weight ratio of the free radically curable binder precursor to the colloidal inorganic oxide components is from about 1:10 to 8:10. A method of making a retroreflective article by coating a substrate with a ceramer composite coating is also described. A method of making a dew-resistant retroreflective article by coating a substrate with a ceramer composite coating and then surface treating the coating is also described.
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