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发明申请
WO2007054223A3 BOROHYDRIDE METALLOCENE COMPLEX OF A LANTHANIDE, CATALYTIC SYSTEM INCLUDING SAID COMPLEX, POLYMERISATION METHOD USING SAME AND ETHYLENE/BUTADIENE COPOLYMER OBTAINED USING SAID METHOD 审中-公开
镧系硼氢化物金属茂络合物，包含所述络合物的催化体系，使用该聚合物的聚合方法和使用所述方法获得的乙烯/丁二烯共聚物

BOROHYDRIDE METALLOCENE COMPLEX OF A LANTHANIDE, CATALYTIC SYSTEM INCLUDING SAID COMPLEX, POLYMERISATION METHOD USING SAME AND ETHYLENE/BUTADIENE COPOLYMER OBTAINED USING SAID METHOD
摘要：
The invention relates to a borohydride metallocene complex of a lanthanide, the preparation method thereof, a catalytic system including said borohydride metallocene complex and a method for the copolymerisation of olefins using said catalytic system. The inventive complex has one of the following formulas (A and B), wherein, in formula A, two ligands Cp 1 and Cp 2 are linked to the lanthanide Ln, such as Nd, said ligands each consisting of a cyclopentadienyl group, and, in formula B, a ligand molecule is linked to the lanthanide Ln, said ligand molecule consisting of two cyclopentadienyl groups Cp 1 and Cp 2 which are interlinked by means of a bridge P having formula MR 1 R 2 , in which M is an element from column IVA, such as Si, and R 1 and R 2 , which may be identical or different, represent an alkyl group having between 1 and 20 carbon atoms. According to the invention, L represents an alkali metal, such as Li, N represents a molecule of a complexing solvent, such as THF, x is an integer or a non-integer which is greater than 0, p is an integer which is equal to or greater than 1 and y is an integer which is equal to or greater than 0.
摘要（中）：

本发明涉及镧系元素的硼氢化物金属茂配合物，其制备方法，包括所述硼氢化物金属茂配合物的催化体系以及使用所述催化体系进行烯烃共聚的方法。 本发明的配合物具有下式（A和B）之一，其中在式A中，两个配体C p1 SUB和C p SUB 2连接至镧系元素Ln，例如 作为Nd，所述配体各自由环戊二烯基组成，并且在式B中，配体分子与镧系元素Ln连接，所述配体分子由两个环戊二烯基Cp1和Cp2组成， 2 ，它们通过具有公式MR 1 R 2 的桥P相互连接，其中M是来自列IVA的元素，例如Si，以及 R 1和R 2可以相同或不同，表示具有1至20个碳原子的烷基。 根据本发明，L表示碱金属如Li，N表示配位溶剂例如THF的分子，x是大于0的整数或非整数，p是相等的整数 等于或大于1，并且y是等于或大于0的整数。

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