폴리부텐의 제조방법
    2.
    发明申请
    폴리부텐의 제조방법 审中-公开
    聚氨酯制备方法

    公开(公告)号:WO2016028123A1

    公开(公告)日:2016-02-25

    申请号:PCT/KR2015/008776

    申请日:2015-08-21

    摘要: C4 혼합물 중 이소부텐의 활용을 극대화함으로써, 기존의 C4 혼합물로 폴리부텐을 생산하던 것보다 증량 생산이 가능한 폴리부텐의 제조방법이 개시된다. 상기 폴리부텐의 제조방법은, C4 혼합물이 이성화 반응기에 공급되어, 이성화 영역에서는 이성화 촉매를 이용한 수소이성화 반응에 의해 1-부텐이 2-부텐으로 이성화되고, 분별 증류 영역에서는 이소부텐 및 2-부텐이 분별 증류되어 분리되는 단계; 상기 이성화 반응기에서 분리된 2-부텐이 포함된 C4 혼합물이 골격 이성화 반응기로 공급되어, 골격 이성화 촉매를 이용한 골격 이성화 반응에 의해, 노르말부텐 중 일부가 이소부텐으로 골격 이성화되고, 이로부터 얻어진 골격 이성화 혼합물은, 상기 이성화 반응기로 공급되어 재순환되는 단계; 및 상기 이성화 반응기에서 분리된 고농도의 이소부텐이 포함된 반응 원료 및 중합 촉매가 폴리부텐 중합 반응기에 공급되어, 중합 반응에 의해 폴리부텐이 생성되는 단계를 포함한다.

    摘要翻译: 公开了一种使C4混合物中异丁烯的利用最大化的聚丁烯制备方法,从而使得能够生产比使用先前的C4混合物的聚丁烯生产中更高量的聚丁烯。 聚丁烯涂布方法包括以下步骤:将C4混合物供给异构化反应器,使得异丁烯化反应中使用异构化催化剂通过氢异构化反应将异丁烯异丁烯化到异丁烯化区域中的2-丁烯异丁烯和2-丁烯, 在分馏区通过分馏分离丁烯; 将包含从异构化反应器分离的2-丁烯的C4混合物供给到骨架异构化反应器中,使得一部分正丁烯通过使用骨架异构化催化剂的骨架异构化反应骨架异构化成异丁烯,得到骨架异构化混合物 从而将其从异构化反应器供应并因此被再循环; 将聚合催化剂和从异构化反应器分离出的含有高浓度异丁烯的反应材料供给到聚丁烯聚合反应器中,从而通过聚合反应制备聚丁烯。

    BUTYL RUBBER IONOMER-THERMOPLASTIC GRAFT COPOLYMERS AND METHODS FOR PRODUCTION THEREOF
    3.
    发明申请
    BUTYL RUBBER IONOMER-THERMOPLASTIC GRAFT COPOLYMERS AND METHODS FOR PRODUCTION THEREOF 审中-公开
    丁基橡胶离子热塑性共聚物及其生产方法

    公开(公告)号:WO2014124535A1

    公开(公告)日:2014-08-21

    申请号:PCT/CA2014/050098

    申请日:2014-02-12

    申请人: LANXESS INC.

    摘要: The present invention is directed to the functionalization of butyl rubber ionomer and optionally the grafting of polyamide to halobutyl rubber ionomers. Specifically, disclosed are methods and products resulting therefrom for creating functionalized ionomers and grafting polyamide to halobutyl ionomers via reactive extrusion. The process comprises reacting a halobutyl polymer with at least one nitrogen and/or phosphorous based nucleophile to provide a halobutyl ionomer comprising conjugated diene units; grafting of an amine-reactive dienophile to said ionomer to form a functionalized ionomer; and optionally blending the resulting functionalized ionomer with polyamide.

    摘要翻译: 本发明涉及丁基橡胶离聚物的官能化和任选地将聚酰胺接枝到卤代丁基橡胶离聚物上。 具体地,公开了由此产生的用于产生官能化离聚物并通过反应性挤出将聚酰胺接枝到卤代丁基离聚物的方法和产物。 该方法包括使卤代丁基聚合物与至少一种基于氮和/或磷的亲核试剂反应以提供包含共轭二烯单元的卤代丁基离聚物; 将胺反应性亲二烯体接枝到所述离聚物以形成官能化的离聚物; 并任选地将得到的官能化离聚物与聚酰胺共混。

    ACTIVITY MONITORING AND POLYMERIZATION PROCESS CONTROL
    5.
    发明申请
    ACTIVITY MONITORING AND POLYMERIZATION PROCESS CONTROL 审中-公开
    活动监测和聚合过程控制

    公开(公告)号:WO2012045597A1

    公开(公告)日:2012-04-12

    申请号:PCT/EP2011/066559

    申请日:2011-09-23

    摘要: The present invention relates to a method to control a liquid feed stream carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity. In a further aspect the invention relates to a controlled process for the preparation of polymers in a polymerization reactor by contacting liquid feed streams comprising monomers and initiators or catalysts, whereby the control of the feed streams entering the polymerization reactor and/ or the initiator or catalyst preparation is carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity within the polymerization reactor. More particularly, the invention relates to a method for controlling the activity of aluminium containing initiators in a process for the co-polymerisation of isolefins and multiolefins, in particular isobutylene and isoprene. The present invention further to device and a chemical plant suitable to operate said process.

    摘要翻译: 本发明涉及一种控制液体进料流的方法,所述方法是通过测量包含引发剂或催化剂的至少一个光谱的液体进料物流,使用基于所述光谱的预测模型确定其活性并调节进料流 和/或包含引发剂或催化剂的进料流的制备条件以获得或保持期望的总活性水平。 在另一方面,本发明涉及通过使包含单体和引发剂或催化剂的液体进料流接触而在聚合反应器中制备聚合物的受控方法,由此控制进入聚合反应器和/或引发剂或催化剂的进料流 通过测量包含引发剂或催化剂的液体进料流的至少一个谱线,基于所述光谱使用预测模型确定其活性并调节进料流和/或进料流的制备条件来进行制备,所述进料流和/ 引发剂或催化剂,以获得或保持聚合反应器内所需的总活性水平。 更具体地说,本发明涉及在异烯烃和多烯烃,特别是异丁烯和异戊二烯的共聚合方法中控制含铝引发剂的活性的方法。 本发明还涉及适用于操作所述方法的装置和化学设备。

    BOROHYDRIDE METALLOCENE COMPLEX OF A LANTHANIDE, CATALYTIC SYSTEM INCLUDING SAID COMPLEX, POLYMERISATION METHOD USING SAME AND ETHYLENE/BUTADIENE COPOLYMER OBTAINED USING SAID METHOD
    10.
    发明申请
    BOROHYDRIDE METALLOCENE COMPLEX OF A LANTHANIDE, CATALYTIC SYSTEM INCLUDING SAID COMPLEX, POLYMERISATION METHOD USING SAME AND ETHYLENE/BUTADIENE COPOLYMER OBTAINED USING SAID METHOD 审中-公开
    镧系硼氢化物金属茂络合物,包含所述络合物的催化体系,使用该聚合物的聚合方法和使用所述方法获得的乙烯/丁二烯共聚物

    公开(公告)号:WO2007054223A3

    公开(公告)日:2007-10-25

    申请号:PCT/EP2006010452

    申请日:2006-10-31

    IPC分类号: C07F17/00 C08F4/52 C08F210/12

    摘要: The invention relates to a borohydride metallocene complex of a lanthanide, the preparation method thereof, a catalytic system including said borohydride metallocene complex and a method for the copolymerisation of olefins using said catalytic system. The inventive complex has one of the following formulas (A and B), wherein, in formula A, two ligands Cp 1 and Cp 2 are linked to the lanthanide Ln, such as Nd, said ligands each consisting of a cyclopentadienyl group, and, in formula B, a ligand molecule is linked to the lanthanide Ln, said ligand molecule consisting of two cyclopentadienyl groups Cp 1 and Cp 2 which are interlinked by means of a bridge P having formula MR 1 R 2 , in which M is an element from column IVA, such as Si, and R 1 and R 2 , which may be identical or different, represent an alkyl group having between 1 and 20 carbon atoms. According to the invention, L represents an alkali metal, such as Li, N represents a molecule of a complexing solvent, such as THF, x is an integer or a non-integer which is greater than 0, p is an integer which is equal to or greater than 1 and y is an integer which is equal to or greater than 0.

    摘要翻译: 本发明涉及镧系元素的硼氢化物金属茂配合物,其制备方法,包括所述硼氢化物金属茂配合物的催化体系以及使用所述催化体系进行烯烃共聚的方法。 本发明的配合物具有下式(A和B)之一,其中在式A中,两个配体C p1 SUB和C p SUB 2连接至镧系元素Ln,例如 作为Nd,所述配体各自由环戊二烯基组成,并且在式B中,配体分子与镧系元素Ln连接,所述配体分子由两个环戊二烯基Cp1和Cp2组成, 2 ,它们通过具有公式MR 1 R 2 的桥P相互连接,其中M是来自列IVA的元素,例如Si,以及 R 1和R 2可以相同或不同,表示具有1至20个碳原子的烷基。 根据本发明,L表示碱金属如Li,N表示配位溶剂例如THF的分子,x是大于0的整数或非整数,p是相等的整数 等于或大于1,并且y是等于或大于0的整数。