发明申请
WO2007137155A1 CATALYST FREE POLYMERIZATION OF 3,4-ALKYLENEDIOXYPYRROLE AND 3,4-ALKYLENEDIOXYFURAN
审中-公开
3,4-亚烷基二咪唑和3,4-亚乙基二氧化硅的无催化聚合
- 专利标题： CATALYST FREE POLYMERIZATION OF 3,4-ALKYLENEDIOXYPYRROLE AND 3,4-ALKYLENEDIOXYFURAN
- 专利标题（中）： 3,4-亚烷基二咪唑和3,4-亚乙基二氧化硅的无催化聚合
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申请号： PCT/US2007/069228申请日： 2007-05-18
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公开(公告)号： WO2007137155A1公开(公告)日： 2007-11-29
- 发明人: REYNOLDS, John, Robert , WALCZAK, Ryan, Michael
- 申请人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. , REYNOLDS, John, Robert , WALCZAK, Ryan, Michael
- 申请人地址： 223 Grinter Hall Gainesville, FL 32611 US
- 专利权人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.,REYNOLDS, John, Robert,WALCZAK, Ryan, Michael
- 当前专利权人： UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.,REYNOLDS, John, Robert,WALCZAK, Ryan, Michael
- 当前专利权人地址： 223 Grinter Hall Gainesville, FL 32611 US
- 代理机构： BUESE, Mark, A.
- 优先权： US60/801,519 20060518
- 主分类号： C08G61/12
- IPC分类号： C08G61/12
摘要：
A method to prepare halogen end-capped polypyrroles, polyfurans or copolymeric pyrroles and furans is presented that readily occurs in a liquid state as well as a solid state without the need of a catalyst from a dihalopyrrole monomer, dihalofuran monomer, or a mixture of monomers. The polymerization mixture can be modified to include a monohalo-monomer for the introduction of a specific end-group or a polyhalo-monomer to form a branched polymer or network. An initiating species can be included in the polymerization mixture to avoid an induction period or to commence the polymerization process on demand. The electroactive polymers can be formed as a bulk material, a coating, or as a film.
