Invention Application
- Patent Title: REFORMATE BENZENE REDUCTION VIA TRANSALKYLATION
- Patent Title (中): 通过转化降解苯并噻吩
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Application No.: PCT/US2009/044418Application Date: 2009-05-19
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Publication No.: WO2010021771A1Publication Date: 2010-02-25
- Inventor: ROCK, Kerry, L. , BOYER, Christopher, C. , SMITH, Lawrence, A.
- Applicant: CATALYTIC DISTILLATION TECHNOLOGIES , ROCK, Kerry, L. , BOYER, Christopher, C. , SMITH, Lawrence, A.
- Applicant Address: 10100 Bay Area Blvd. Pasadena, TX 77507 US
- Assignee: CATALYTIC DISTILLATION TECHNOLOGIES,ROCK, Kerry, L.,BOYER, Christopher, C.,SMITH, Lawrence, A.
- Current Assignee: CATALYTIC DISTILLATION TECHNOLOGIES,ROCK, Kerry, L.,BOYER, Christopher, C.,SMITH, Lawrence, A.
- Current Assignee Address: 10100 Bay Area Blvd. Pasadena, TX 77507 US
- Agency: BERGMAN, Jeffrey, S. et al.
- Priority: US12/195,113 20080820
- Main IPC: C07C2/66
- IPC: C07C2/66 ; C07B31/00 ; B01J29/00 ; C10L1/16
Abstract:
A process for reducing benzene content in a reformate stream, including: fractionating a full range reformate comprising benzene, C 7 to C 9 monoalkyl aromatics, and C 1O+ polyalkyl aromatics into at least three fractions including a light reformate fraction comprising the benzene; a medium reformate fraction comprising the C 7 to C 9 monoalkyl aromatics; and a heavy reformate fraction comprising the C 10+ polyalkyl aromatics; feeding the light reformate fraction, the heavy reformate fraction and a transalkylation catalyst to a transalkylation reaction zone; contacting the light fraction and the heavy fraction in presence of the transalkylation catalyst in the transalkylation reaction zone to react at least a portion of the benzene with C 1O+ polyalkyl aromatics to form monoalkyl aromatics; separating an effluent from the transalkylation reaction zone to form a catalyst fraction and a liquid fraction comprising the monoalkyl aromatics.
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