Invention Application
- Patent Title: PROCESS FOR CIS-1,1,1,4,4,4,-HEXAFLUORO-2-BUTENE
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Application No.: PCT/US2011/037310Application Date: 2011-05-20
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Publication No.: WO2011146820A3Publication Date: 2011-11-24
- Inventor: POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael
- Applicant: HONEYWELL INTERNATIONAL INC. , POSS, Andrew Joseph , NALEWAJEK, David , NAIR, Haridasan K. , VAN DER PUY, Michael
- Applicant Address: Patent Services M/S AB/2B 101 Columbia Road P. O. Box 2245 Morristown, New Jersey 07962-2245 US
- Assignee: HONEYWELL INTERNATIONAL INC.,POSS, Andrew Joseph,NALEWAJEK, David,NAIR, Haridasan K.,VAN DER PUY, Michael
- Current Assignee: HONEYWELL INTERNATIONAL INC.,POSS, Andrew Joseph,NALEWAJEK, David,NAIR, Haridasan K.,VAN DER PUY, Michael
- Current Assignee Address: Patent Services M/S AB/2B 101 Columbia Road P. O. Box 2245 Morristown, New Jersey 07962-2245 US
- Agency: BEATUS, Carrie
- Priority: US13/110,979 20110519; US61/347,134 20100521
- Main IPC: C07C17/25
- IPC: C07C17/25 ; C07C17/23 ; C07C21/18
Abstract:
Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl 4 with a compound having the formula CF 3 CX=CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF 3 CXClCXHCCl 3 ; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF 3 CXHCXHCF 3 ; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF 3 C = CCF 3 ; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula (I).
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