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    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE
    1.
    发明申请
    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE 审中-公开
    制备十六烷基-2-丁基的方法

    公开(公告)号：WO2011146812A2

    公开(公告)日：2011-11-24

    申请号：PCT/US2011037298

    申请日：2011-05-20

    Applicant: HONEYWELL INT INC ,  POSS ANDREW JOSEPH ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA

    Inventor： POSS ANDREW JOSEPH ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA

    CPC classification number: C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

    Abstract: Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX=CXCF3, where X = halogen; and (b) treating CF3CX=CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX=CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX=CHCF3 is greatly reduced or eliminated.

    Abstract translation: 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下用脱卤催化剂处理CF 3 C X = CXCF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = CXCF 3转移到卤素受体化合物。 由于Y不是氢，CF3CX = CHCF3的形成大大降低或消除。

    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE
    2.
    发明申请
    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE 审中-公开
    制备氟化苯乙烯的方法

    公开(公告)号：WO2011146792A2

    公开(公告)日：2011-11-24

    申请号：PCT/US2011/037268

    申请日：2011-05-20

    Applicant: HONEYWELL INTERNATIONAL INC. ,  POSS, Andrew Joseph ,  VAN DER PUY, Michael ,  SINGH, Rajiv Ratna ,  NALEWAJEK, David ,  NAIR, Haridasan K.

    Inventor： POSS, Andrew Joseph ,  VAN DER PUY, Michael ,  SINGH, Rajiv Ratna ,  NALEWAJEK, David ,  NAIR, Haridasan K.

    CPC classification number: C07C17/23 ,  C07B2200/09 ,  C07C17/10 ,  C07C17/206 ,  C07C17/278 ,  C07C21/18 ,  C07C19/10

    Abstract: Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).

    Abstract translation: 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。

    ISOMERIZATION OF 1,1,3,3-TETRAFLUOROPROPENE
    4.
    发明申请
    ISOMERIZATION OF 1,1,3,3-TETRAFLUOROPROPENE 审中-公开
    1,1,3,3-四氢呋喃的异构化

    公开(公告)号：WO2010083349A2

    公开(公告)日：2010-07-22

    申请号：PCT/US2010021093

    申请日：2010-01-15

    Applicant: HONEYWELL INT INC ,  WANG HAIYOU ,  POKROWSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  VAN DER PUY MICHAEL

    Inventor： WANG HAIYOU ,  POKROWSKI KONSTANTIN A ,  TUNG HSUEH SUNG ,  VAN DER PUY MICHAEL

    IPC: C07C17/358 ,  C07C21/18

    CPC classification number: C07C17/25 ,  C07B2200/09 ,  C07C17/087 ,  C07C17/358 ,  C07C17/383 ,  C07C21/18 ,  Y02P20/582 ,  C07C19/08

    Abstract: The present invention involves methods for isomerization of 1234zc. Also provided are methods for managing 1,1,3,3-tetrafluoropropene produced as a byproduct in a process for synthesizing trans-1,3,3,3-tetrafluoropropene from 245fa, wherein 1234zc is converted into trans/cis-1234ze with the help of a catalyst in the absence of HF and in an isomerization reactor, or is converted into 1234zc and/or 245fa with the help of a catalyst in the presence of HF in a separate reactor or preferably in the same reactor of 245fa dehydrofluorination.

    Abstract translation: 本发明涉及1234zc的异构化方法。 还提供了在用于从245fa合成反式-1,3,3,3-四氟丙烯的方法中管理作为副产物生产的1,1,3,3-四氟丙烯的方法，其中1234zc被转化成反式/顺式1234ze， 在不存在HF的情况下和在异构化反应器中的催化剂的帮助下，或者在HF存在下，在单独的反应器中，或优选在245fa脱氟化氢的相同反应器中，借助催化剂转化为1234zc和/或245fa。

    PROCESS FOR THE PREPARATION OF PERFLUORINATED CIS-ALKENE
    5.
    发明申请
    PROCESS FOR THE PREPARATION OF PERFLUORINATED CIS-ALKENE 审中-公开
    制备全氟化苯乙烯的方法

    公开(公告)号：WO2010014548A2

    公开(公告)日：2010-02-04

    申请号：PCT/US2009051847

    申请日：2009-07-27

    Applicant: HONEYWELL INT INC ,  VAN DER PUY MICHAEL ,  MA JING-JI

    Inventor： VAN DER PUY MICHAEL ,  MA JING-JI

    IPC: C07C17/354 ,  B01J23/04 ,  B01J23/44 ,  B01J23/745 ,  C07C21/18

    CPC classification number: C07C21/18 ,  B01J23/58 ,  B01J23/628 ,  C07C17/354

    Abstract: A process for the preparation of perfluorinated cis-alkene comprising: reducing a perfluorinated alkyne with hydrogen over a palladium catalyst in the presence of a non-aromatic amine catalyst modifier to form a product which comprises a perfluorinated cis-alkene, wherein the perfluorinated alkyne has the general structure: RfC=CRf wherein Rf is a perfluorinated alkyl group having a carbon number in the range between about 1 to 6.

    Abstract translation: 一种制备全氟化顺式烯烃的方法，包括：在非芳族胺催化剂改性剂存在下，用钯催化剂，用氢还原全氟化炔烃以形成包含全氟化顺式 - 烯烃的产物，其中全氟化炔烃具有 一般结构：RfC = CRf其中Rf是碳数在约1至6之间的全氟化烷基。

    METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS
    6.
    发明申请
    METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
    生产氟化有机化合物的方法

    公开(公告)号：WO2007079431A2

    公开(公告)日：2007-07-12

    申请号：PCT/US2007/000056

    申请日：2007-01-03

    Applicant: HONEYWELL INTERNATIONAL INC. ,  TUNG, Hsueh, Sung ,  MUKHOPAHYAY, Sudip ,  VAN DER PUY, Michael ,  MA, Jing, Ji ,  BORTZ, Cheryl ,  LIGHT, Barbara ,  PHILLIPS, Steven, D. ,  DUBEY, Rajesh ,  MERKEL, Daniel, C.

    Inventor： TUNG, Hsueh, Sung ,  MUKHOPAHYAY, Sudip ,  VAN DER PUY, Michael ,  MA, Jing, Ji ,  BORTZ, Cheryl ,  LIGHT, Barbara ,  PHILLIPS, Steven, D. ,  DUBEY, Rajesh ,  MERKEL, Daniel, C.

    CPC classification number: C07C19/10 ,  C07C17/04 ,  C07C17/06 ,  C07C17/087 ,  C07C17/206 ,  C07C17/21 ,  C07C17/25 ,  C07C21/18 ,  C07C19/01 ,  C07C21/073

    Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF 3 CF=CH 2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCI 2 =CCICH 2 CI (which may be purchased or synthesized from 1,2,3- trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CFaCCl=CH2, preferably in a 80-96% selectivity. The CF 3 CCl=CH 2 is preferably converted to CF 3 CFClCH 3 (244-isomer) using a SbCl 5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture Of Cr2O3 and FeCl 3 /C is preferably used as the catalyst to achieve high selectivity to CF 3 CCl=CH 2 (96%). In the second step, SbCl 5 /C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF 3 CFClCH 3 . The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

    Abstract translation: 公开了生产氟化烯烃的方法，优选适于CF 3 CH 2 CH 2（1234yf）的商业化。 优选实施方案中可以使用三个步骤，其中原料如CCI 2 = CCICH 2 Cl（其可以从1,2,3-三氯丙烷购买或合成） 被氟化（优选在催化剂存在下在气相中用HF）合成化合物如CFaClCl = CH 2，优选为80-96％的选择性。 CF 3 3 CCl = CH 2 2优选使用以下化合物转化为CF 3 CFClCH 3（244-异构体） SbCl 5作为催化剂，然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中进行。 对于第一步，优选使用Cr 2 O 3和FeCl 3/3的混合物作为催化剂以实现对CF 3 CCl = CH 2的高选择性， （96％）。 在第二步中，优选使用SbCl 5 / C作为将1233xf转化为244-异构体CF 3 CFClCH 3的选择性催化剂。 中间体优选通过蒸馏分离和纯化，并用于下一步骤而不进一步纯化，优选纯度高于约95％。

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