Invention Application
- Patent Title: METHOD OF MAKING A TRIHALOSILANE
- Patent Title (中): 制备三羟甲基纤维素的方法
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Application No.: PCT/US2011/064544Application Date: 2011-12-13
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Publication No.: WO2012082686A1Publication Date: 2012-06-21
- Inventor: BERGER, Stephanie , KATSOULIS, Dimitris , LARSEN, Robert, Thomas , MCLAUGHLIN, Matthew, J. , PILLAI, Unnikrishnan, R. , WINELAND, Jonathan, David
- Applicant: DOW CORNING CORPORATION , BERGER, Stephanie , KATSOULIS, Dimitris , LARSEN, Robert, Thomas , MCLAUGHLIN, Matthew, J. , PILLAI, Unnikrishnan, R. , WINELAND, Jonathan, David
- Applicant Address: 2200 West Salzburg Road Midland, MI 48686-0994 US
- Assignee: DOW CORNING CORPORATION,BERGER, Stephanie,KATSOULIS, Dimitris,LARSEN, Robert, Thomas,MCLAUGHLIN, Matthew, J.,PILLAI, Unnikrishnan, R.,WINELAND, Jonathan, David
- Current Assignee: DOW CORNING CORPORATION,BERGER, Stephanie,KATSOULIS, Dimitris,LARSEN, Robert, Thomas,MCLAUGHLIN, Matthew, J.,PILLAI, Unnikrishnan, R.,WINELAND, Jonathan, David
- Current Assignee Address: 2200 West Salzburg Road Midland, MI 48686-0994 US
- Agency: PURCHASE, Claude, F.
- Priority: US61/424,118 20101217
- Main IPC: C07F7/02
- IPC: C07F7/02 ; C01B33/107
Abstract:
A method of making a trihalosilane comprising contacting an organotrihalosilane according to the formula RS1X3 (I), wherein R is C 1 -C 10 hydrocarbyl and each X independently is halo, with hydrogen, wherein the mole ratio of the organotrihalosilane to hydrogen is from 0.009:1 to 1:2300, in the presence of a catalyst comprising a metal selected from (i) Re, (ii) a mixture comprising Re and at least one element selected from Pd, Ru, Mn, Cu, and Rh, (iii) a mixture comprising Ir and at least one element selected from Pd and Rh, (iv) Mn, (v) a mixture comprising Mn and Rh, (vi) Ag, (vii) Mg, and (viii) Rh at from 300 to 800 °C to form a trihalosilane.
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