发明申请
- 专利标题: METHOD FOR PRODUCING TINPLATE AND PRODUCT PRODUCED THEREWITH
- 专利标题(中): 生产锡板及其生产产品的方法
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申请号: PCT/EP2013/063912申请日: 2013-07-02
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公开(公告)号: WO2014006031A1公开(公告)日: 2014-01-09
- 发明人: PENNING, Jan, Paul , SCHNETZ, Kokkie
- 申请人: TATA STEEL IJMUIDEN BV
- 申请人地址: P.O. Box 10000 NL-1970 CA IJmuiden NL
- 专利权人: TATA STEEL IJMUIDEN BV
- 当前专利权人: TATA STEEL IJMUIDEN BV
- 当前专利权人地址: P.O. Box 10000 NL-1970 CA IJmuiden NL
- 代理机构: BODIN, Andre
- 优先权: EP12174561.6 20120702
- 主分类号: C25D5/48
- IPC分类号: C25D5/48 ; C25D11/34 ; C25D3/30
摘要:
The invention relates to a method for forming a passivation layer on a strip of packaging steel for producing a packaging container or a can, said strip having at least one tinplated surface having excellent sulphide staining resistance. The method comprises the steps of: (i) subjecting said tin-plated surface to an anodic treatment at a pH of from 8 to 12 in a suitable aqueous electrolyte, wherein the suitable electrolyte is a phosphate solution, borate solution, sulphate solution or a carbonate solution, wherein the electrolyte for the anodic treatment does not contain mono-atomic halogen anions (Group 17) such as CI-, F-, wherein the thickness of the tin oxide layer (D), expressed in Coulomb/m2 and representing the total charge needed to reduce the layer to metallic tin is related to anodic treatment time (t), current density (A) by D = E x A x t, where E is the efficiency of the electrochemical reaction, and wherein D is at least 30 C/m2; wherein the electrolyte comprises monoatomic cations from Group 1 or 2 from the periodic table or polyatomic cations, and polyatomic anions; (ii) optionally rinsing and drying the anodically treated tin-plated surface - subjecting the anodically treated tin-plated surface to a chemical passivation treatment free from using hexavalent chromium compounds; (iii) drying of the passivated anodically treated tin-plated surface; (iv) final processing such as oiling, winding, cutting etc.