发明申请
WO2014152850A1 DENSELY FUNCTIONALIZED POLYMERS DERIVED FROM BAYLIS-HILLMAN ADDUCTS
审中-公开
来自BAYLIS-HILLMAN ADDUCTS的DENSELY功能化聚合物
- 专利标题： DENSELY FUNCTIONALIZED POLYMERS DERIVED FROM BAYLIS-HILLMAN ADDUCTS
- 专利标题（中）： 来自BAYLIS-HILLMAN ADDUCTS的DENSELY功能化聚合物
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申请号： PCT/US2014/027967申请日： 2014-03-14
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公开(公告)号： WO2014152850A1公开(公告)日： 2014-09-25
- 发明人: JOY, Abraham , PENG, Chao
- 申请人： JOY, Abraham , PENG, Chao , THE UNIVERSITY OF AKRON
- 申请人地址： 514 Silver Ridge Drive Copley, Ohio 44321 US
- 专利权人： JOY, Abraham,PENG, Chao,THE UNIVERSITY OF AKRON
- 当前专利权人： JOY, Abraham,PENG, Chao,THE UNIVERSITY OF AKRON
- 当前专利权人地址： 514 Silver Ridge Drive Copley, Ohio 44321 US
- 代理机构： WEBER, Mark et al.
- 优先权： US61/781,888 20130314
- 主分类号： C08G18/32
- IPC分类号： C08G18/32 ; C07C49/24
摘要：
A method of preparing a polymer is provided comprising preparing a Baylis-Hillman adduct by reacting an activated alkene with a carbon electrophile; and polymerizing the Baylis-Hillman adduct. The Baylis-Hillman reaction provides an efficient platform for the synthesis of densely functionalized monomers, from which polymers with multiple functional groups can be readily synthesized. It has been discovered that that Baylis-Hillman adducts are versatile monomers for both controlled radical and step-growth polymerizations.
