发明申请
- 专利标题: CATIONIC SURFACE SIZING AGENT
- 专利标题(中): 阳离子表面施胶剂
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申请号: PCT/FI2016/050931申请日: 2016-12-28
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公开(公告)号: WO2017115012A1公开(公告)日: 2017-07-06
- 发明人: LEPO, Anneli , TURUNEN, Elsi , TURKKI, Tarja
- 申请人: KEMIRA OYJ
- 申请人地址: Porkkalankatu 3 00180 Helsinki FI
- 专利权人: KEMIRA OYJ
- 当前专利权人: KEMIRA OYJ
- 当前专利权人地址: Porkkalankatu 3 00180 Helsinki FI
- 代理机构: KOLSTER OY AB
- 优先权: FI20156045 20151231
- 主分类号: D21H17/45
- IPC分类号: D21H17/45 ; D21H21/16 ; C08F20/12 ; C08F212/08 ; C08F220/34 ; C08F2/06 ; C08F257/02 ; C08L33/06 ; C08L25/08 ; C09D133/06 ; C09D125/08
摘要:
Provided herein is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (b) 15 to 100 % by weight of at least one Cl-C4-alkyl (meth)acrylate, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising Cl-6-carboxylic acid and Cl-6-carboxylic acid anhydride a second ethylenically unsaturated monomer blend comprising (i) 5 to 50 % by weight of at least one ethylenically unsaturated quaternary amine selected from quaternary salt of N,N,N-tri(Cl-4-alkyl) amino Cl-4-alkyl(meth)acrylate with a mineral acid or an organic acid and/or quaternary salt of N,N,N-tri(Cl-4-alkyl)amino Cl-4-alkyl(meth)acrylamide with a mineral acid or an organic acid, and (iii) 10 to 95 % by weight of at least one optionally substituted styrene, in the presence of a second free radical initiator, and adding water to the obtained polymer dispersion to obtain the aqueous prepolymer composition.