公开(公告)号：WO2017037347A1

公开(公告)日：2017-03-09

申请号：PCT/FI2016/050610

申请日：2016-09-02

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  TURUNEN, Elsi ,  TURKKI, Tarja ,  ÜBERBACHER, Bernhard

IPC分类号： C08L33/08 ,  C08L33/10 ,  C08L33/20 ,  C08L25/14 ,  D21H21/16 ,  D21H21/54 ,  D21H23/22 ,  C08F2/20 ,  C08F20/18 ,  C08F220/44 ,  C08F212/08 ,  C08F20/14 ,  C08F220/16 ,  C08L3/02 ,  C09D133/08 ,  D21H19/22

CPC分类号： C09D133/08 ,  C08F212/08 ,  C08F220/18 ,  C08F251/00 ,  C08F285/00 ,  C08L3/02 ,  C08L2207/53 ,  D21H17/20 ,  D21H19/22 ,  D21H21/16 ,  D21H21/54 ,  D21H23/22 ,  C08F2220/1825 ,  C08F220/44

摘要： The present invention provides a core/shell polymer particle for surface sizing of cellulosic products, wherein the core polymer and the shell polymer of the core/shell polymer par- ticle are polymerized from monomers comprising at least 40%, by weight of monomers selected from branched C3-10- alkyl (meth)acrylate, styrene, linear C1-10-alkyl (meth)acry- late, and acrylonitrile, based on the total weight of the mon- omers of the core/shell polymer particle; provided that the polymer of the core/shell polymer particle comprises at least 40% by weight of branched C3-6-alkyl (meth)acrylate and at least 50% by combined weight of branched C3-10- alkyl (meth)acrylate and styrene, linear C1-10-alkyl (meth)acrylate, and/or acrylonitrile, based on the total weight of the monomers of the core/shell polymer particle.

摘要翻译： 本发明提供了一种用于纤维素产品的表面施胶的核/壳聚合物颗粒，其中芯/壳聚合物颗粒的芯聚合物和壳聚合物由包含至少40重量％的选自以下的单体的单体聚合： 支链C 3-10 - （甲基）丙烯酸烷基酯，苯乙烯，（甲基）丙烯酸直链C 1-10烷基酯和丙烯腈，基于芯/壳聚合物颗粒的单体总重量; 核/壳聚合物颗粒的聚合物包含至少40重量％的（甲基）丙烯酸支链C 3-6 - 烷基酯和至少50重量％的支链C 3-10 - （甲基）丙烯酸烷基酯和苯乙烯 ，（甲基）丙烯酸线性C 1-10烷基酯和/或丙烯腈，基于芯/壳聚合物颗粒的单体的总重量。

公开(公告)号：WO2013020855A1

公开(公告)日：2013-02-14

申请号：PCT/EP2012/064921

申请日：2012-07-31

申请人： KEMIRA OYJ ,  POLVERARI, Marco ,  LEPO, Anneli ,  O'TOOLE, Michael

发明人： POLVERARI, Marco ,  LEPO, Anneli ,  O'TOOLE, Michael

IPC分类号： C08L79/02 ,  D21H21/10 ,  C08L33/26

CPC分类号： C08L79/02 ,  C08L39/02 ,  C08L2201/54 ,  D21H17/56 ,  D21H21/10 ,  C08L101/00 ,  C08L33/26

摘要： The present invention relates to a composition comprising dispersion, having an aqueous phase containing a dissolved water soluble cationic coagulant polymer and if needed a dissolved inorganic salt. The aqueous phase further contains a dispersed water soluble flocculant polymer, wherein the water soluble flocculant polymer is formed of a water soluble ethylenically unsaturated monomer or monomer blend which are polymerized in the aqueous phase. The water soluble cationic coagulant polymer is cationic poly(alkyleneamine), which is the reaction product of the following reaction: H 2 N-(CH 2 ) m -NR-(CH 2 ) m -NH 2 + Cl-CH 2 CH 2 -CI, wherein R is selected from the group consisting alkyl radicals containing from 1 to 4 carbon atoms m is an integer of from 1 to 4. The amount of dissolved inorganic salt is less that 10% by weight of the composition, and the composition is in a stable, pourable, dispersion form.

摘要翻译： 本发明涉及包含分散体的组合物，其具有含有溶解的水溶性阳离子凝结剂聚合物的水相，并且如果需要，涉及溶解的无机盐。 水相还含有分散的水溶性絮凝剂聚合物，其中水溶性絮凝剂聚合物由在水相中聚合的水溶性烯属不饱和单体或单体共混物形成。 水溶性阳离子凝结剂聚合物是阳离子聚（亚烷基胺），其是以下反应的反应产物：H 2 N - （CH 2）m -NR - （CH 2）m -NH 2 + Cl-CH 2 CH 2 -C 1，其中R选自 包含1至4个碳原子的烷基的基团m为1至4的整数。溶解的无机盐的量小于组合物的10重量％，并且组合物处于稳定的可倾倒的分散体 形成。

公开(公告)号：WO2017115012A1

公开(公告)日：2017-07-06

申请号：PCT/FI2016/050931

申请日：2016-12-28

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  TURUNEN, Elsi ,  TURKKI, Tarja

IPC分类号： D21H17/45 ,  D21H21/16 ,  C08F20/12 ,  C08F212/08 ,  C08F220/34 ,  C08F2/06 ,  C08F257/02 ,  C08L33/06 ,  C08L25/08 ,  C09D133/06 ,  C09D125/08

CPC分类号： C08F2/06 ,  C08F20/12 ,  C08F212/08 ,  C08F220/34 ,  C08F257/02 ,  C08L33/06 ,  C09D125/14 ,  C09D133/06 ,  D21H17/45 ,  D21H21/16 ,  C08F2220/1825 ,  C08F2/22

摘要： Provided herein is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (b) 15 to 100 % by weight of at least one Cl-C4-alkyl (meth)acrylate, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising Cl-6-carboxylic acid and Cl-6-carboxylic acid anhydride a second ethylenically unsaturated monomer blend comprising (i) 5 to 50 % by weight of at least one ethylenically unsaturated quaternary amine selected from quaternary salt of N,N,N-tri(Cl-4-alkyl) amino Cl-4-alkyl(meth)acrylate with a mineral acid or an organic acid and/or quaternary salt of N,N,N-tri(Cl-4-alkyl)amino Cl-4-alkyl(meth)acrylamide with a mineral acid or an organic acid, and (iii) 10 to 95 % by weight of at least one optionally substituted styrene, in the presence of a second free radical initiator, and adding water to the obtained polymer dispersion to obtain the aqueous prepolymer composition.

摘要翻译： 本文提供通过自由基乳液共聚第一烯属不饱和单体共混物获得的含水聚合物分散体（A），所述第一烯属不饱和单体共混物包含（b）15-100重量％的至少一种C 1 -C 4烷基（ 在包含用于自由基乳液共聚的第一自由基引发剂的水溶性氧化还原体系和在含有C 1-6 - 羧酸的聚合溶剂中通过自由基乳液共聚获得的含水预聚物组合物（B） （i）5至50重量％的至少一种选自N，N，N-三（C 1-4 - 烷基）氨基酸的季盐的烯键式不饱和季胺，其中所述烯键式不饱和季胺选自N， 烷基）氨基C 1-4烷基（甲基）丙烯酸酯与无机酸或有机酸和/或N，N，N-三（C 1-4 - 烷基）氨基C 1-4 - 烷基（甲基）丙烯酰胺的季盐 与无机酸或有机酸，和（iii）10至95重量％的原油 在一种第二自由基引发剂的存在下，将一种任选取代的苯乙烯加入到所得聚合物分散体中，得到含水预聚物组合物。

公开(公告)号：WO2017109277A1

公开(公告)日：2017-06-29

申请号：PCT/FI2016/050877

申请日：2016-12-15

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  TURUNEN, Elsi ,  TURKKI, Tarja

IPC分类号： D21H21/16 ,  D21H17/23 ,  D21H17/28 ,  D21H17/00 ,  D21H19/54 ,  D21H19/58

CPC分类号： D21H21/16 ,  D21H17/23 ,  D21H17/28 ,  D21H17/72 ,  D21H19/54 ,  D21H19/58

摘要： The present invention relates to a sizing agent composition comprising starch, lignosulfonate and poly(alkyl acrylate), poly(alkyl (meth)acrylate), a mixture of poly(alkyl acrylate) and poly(alkyl methacrylate) or a copolymer of alkyl acry- late and alkyl (meth)acrylate. The present invention further relates to a method for preparing the sizing agent composition, and use of the sizing agent compo- sition for sizing paper, paper products or board.

摘要翻译： 本发明涉及包含淀粉，木质素磺酸盐和聚（丙烯酸烷基酯），聚（烷基（甲基）丙烯酸酯），聚（丙烯酸烷基酯）和聚（甲基丙烯酸烷基酯）的混合物的施胶剂组合物 ）或烷基丙烯酸和（甲基）丙烯酸烷基酯的共聚物。 本发明还涉及上浆剂组合物的制备方法和上浆剂组合物在上浆纸，纸制品或纸板上的用途。

公开(公告)号：WO2022058656A1

公开(公告)日：2022-03-24

申请号：PCT/FI2021/050613

申请日：2021-09-16

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  HIRSILÄ, Paula

IPC分类号： D21H17/23 ,  D21H17/28 ,  D21H17/66 ,  D21H21/16

摘要： The invention relates to a surface size composition for surface sizing of paper, board, or the like. The composition comprises at least an aluminium compound and an anionic lignin-carbohydrate complex.

公开(公告)号：WO2017162921A1

公开(公告)日：2017-09-28

申请号：PCT/FI2017/050198

申请日：2017-03-22

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  PEURANEN, Helena

IPC分类号： D21H19/44 ,  D21H19/54 ,  D21H19/58 ,  D21H19/38

摘要： The invention relates to a composition for modifying rheology of coating colour and its use. The composition comprises an aqueous polymer dispersion, comprising a copolymer of monomer (a), which is at least one optionally substituted styrene, and monomer (b), which is at least one C1-C4-alkyl (meth)acrylate. The copolymer has a particle size D50

摘要翻译： 本发明涉及用于改变涂料流变性的组合物及其用途。 该组合物包含含水聚合物分散体，其包含至少一种任选取代的苯乙烯的单体（a）和至少一种（甲基）丙烯酸C 1 -C 4 - 烷基酯的单体（b）的共聚物。 该共聚物的粒径D50 < 100纳米。 组合物还包含平均分子量Mn < 1000克/摩尔。

公开(公告)号：WO2023067246A1

公开(公告)日：2023-04-27

申请号：PCT/FI2022/050697

申请日：2022-10-20

申请人： KEMIRA OYJ

发明人： HILTUNEN, Jaakko ,  LEPO, Anneli ,  TURKKI, Tarja

IPC分类号： D21H17/00 ,  D21H17/25 ,  D21H17/26 ,  D21H17/27 ,  D21H19/34 ,  D21H19/52 ,  D21H21/16

摘要： The present invention relates to a coating composition for a sheet like cellulosic fibrous web comprising one or more enzyme hydrolysed water-soluble cellulose derivatives and to a method of preparing such a composition. The present invention further relates to a coated sheet like cellulosic fibrous web or a product comprising said coated sheet like cellulosic fibrous web substrate and also to a method of coating a sheet like cellulosic fibrous web. Still further the invention relates to use of the enzyme hydrolysed water-soluble cellulose derivatives as a coating composition for a sheet like cellulosic fibrous web.

公开(公告)号：WO2021176144A1

公开(公告)日：2021-09-10

申请号：PCT/FI2021/050157

申请日：2021-03-04

申请人： KEMIRA OYJ

发明人： NYMAN, Ville ,  LEPO, Anneli

IPC分类号： D21H17/26 ,  B32B29/08 ,  D21H19/52 ,  D21H21/16 ,  D21H21/18 ,  D21H21/20 ,  D21H27/10

摘要： The invention relates to the use of a surface size composition comprising at least one cellulose derivative selected from cellulose ethers, excluding carboxyalkyl celluloses, for providing compression strength for a fibrous web, such as paper, board or the like, preferably comprising recycled cellulosic fibres. The invention relates also to a method for surface sizing of paper, board or the like.

公开(公告)号：WO2018178255A1

公开(公告)日：2018-10-04

申请号：PCT/EP2018/058117

申请日：2018-03-29

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  TURKKI, Tarja ,  TURUNEN, Elsi

IPC分类号： D21H17/35 ,  D21H17/36 ,  D21H17/37 ,  D21H17/66 ,  D21H19/20 ,  D21H19/22 ,  D21H19/64 ,  D21H21/16

摘要： The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75 % by weight of at least one optionally substituted styrene, (b) 15 to 100 % by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6- carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50 % by weight of at least one ethylenically unsaturated quaternary amine selected from quaternary salt of N,N,N-tri(C1-4-alkyl)amino C1-4-alkyl(meth)acrylate with a mineral acid or an organic acid and/or quaternary salt of N,N,N-tri(C1-4-alkyl)amino C1-4-alkyl(meth)acrylamide with a mineral acid or an organic acid, (ii) 0 to 40 %, preferably 0 %, by weight of at least one ethylenically unsaturated tertiary amine selected from N,N-di(C1-4-alkyl)amino C1-4- alkyl(meth)acrylate and/or N,N-di(C1-4-alkyl)amino C1-4- alkyl(meth)acrylamide, (iii) 10 to 95 % by weight of at least one optionally substituted styrene, (iv) 0 to 50% by weight of at least one C1-C4-alkyl (meth)acrylate, and (v) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (i)+(ii)+(iii)+(iv)+(v) is 100%, in the presence of a second free radical initiator, and adding water to the obtained polymer dispersion to obtain the aqueous prepolymer composition. The present invention further relates to production thereof and use on cellulosic materials.

公开(公告)号：WO2017162922A1

公开(公告)日：2017-09-28

申请号：PCT/FI2017/050199

申请日：2017-03-22

申请人： KEMIRA OYJ

发明人： LEPO, Anneli ,  PEURANEN, Helena

IPC分类号： D21H19/58 ,  C08F220/18 ,  C08F251/00 ,  D21H21/10

摘要： The invention relates to an aqueous polymer dispersion having a viscosity of ≤150 m Pas at 40 % solids content and comprising polymer particles having a particle size D50 less than 85 nm. The polymer dispersion is obtainable by free radical emulsion copolymerisation of at least monomer (a) and monomer (b), where monomer (a) is at least one optionally substituted styrene and monomer (b) is at least one C1-C4-alkyl (meth)acrylate, in a reaction mixture comprising degraded starch which has an average molecular weight Mn

摘要翻译： 本发明涉及一种聚合物水分散体，其在40％固体含量下具有≤150mPa.s的粘度并且包含具有小于85nm的粒径D50的聚合物颗粒。 聚合物分散体可通过至少单体（a）和单体（b）的自由基乳液共聚获得，其中单体（a）为至少一种任选取代的苯乙烯，单体（b）为至少一种C 1 -C 4 - 烷基 （甲基）丙烯酸酯）在包含降解淀粉（其平均分子量Mn < 1000克/摩尔。 本发明还涉及该聚合物分散体及其制备方法的用途。