- 专利标题: ANIONIC COPOLYMERS SUITABLE AS SCALING INHIBITORS
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申请号: PCT/JP2019/046588申请日: 2019-11-28
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公开(公告)号: WO2021106148A1公开(公告)日: 2021-06-03
- 发明人: MATHEIS Jurgen , WOLF Florian , HATER Wolfgang
- 申请人: KURITA WATER INDUSTRIES LTD.
- 申请人地址: 10-1, Nakano 4-chome, Nakano-ku, Tokyo
- 专利权人: KURITA WATER INDUSTRIES LTD.
- 当前专利权人: KURITA WATER INDUSTRIES LTD.
- 当前专利权人地址: 10-1, Nakano 4-chome, Nakano-ku, Tokyo
- 代理机构: SHIGENO, Tsuyoshi et al.
- 主分类号: C02F5/00
- IPC分类号: C02F5/00 ; C02F5/12 ; C02F5/14
摘要:
The present invention relates to anionic copolymers, which are suitable as scaling inhibitors in water bearing systems, in particular as inhibitors for the formation of antimony(III) sulfide-containing scale. The present invention also relates to a method for reducing scaling in water bearing systems, in particular in water loops of geothermal power plants, in which the formation of sulfide-containing scale and especially the formation of antimony(III) sulfide-containing scale may occur. The anionic copolymers have the following characteristics: 1) The copolymers comprise a. polymerized units of a monomer M1, which is a primary amide of a monoethylenically unsaturated monocarboxylic acid having 3 to 6 C atoms and b. polymerized units of a monoethylenically unsaturated monomer M2, which is selected from monoethylenically unsaturated monomer having a sulfonate group and or a sulfate group and monoethylenically unsaturated monomer having a carboxyl group and mixtures thereof; 2) The copolymers have an anionic charge density in the range from 0.5 to 6.0 mol/kg, 3) The sodium salts of the copolymers have a weight average molecular weight Mw of at least 10000 g/mol, as determined by gel permeation chromatography.