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1.发明公开Providing hydrophobic surfaces on hydrophilic inorganic materials with metal glycolates 失效在含有金属甘油酯的疏水性无机材料上提供疏水性表面
公开(公告)号：EP0133702A3
公开(公告)日：1986-04-16
申请号：EP84109443
申请日：1984-08-08
发明人： Inoue, Tetsuyu , Tsuruga, Kouji , Harada, Masashi
CPC分类号： C07F9/09 , C01P2002/82 , C01P2004/10 , C01P2004/61 , C01P2004/62 , C01P2006/22 , C01P2006/60 , C01P2006/90 , C07F5/069 , C07F7/006 , C07F7/2232 , C07F9/098 , C08K9/04 , C09C3/08
摘要： Hydrophilic inorganic materials are provided with a hydrophobic surface by treatment with a metal glycolate compound having the formula:
wherein:
Me is Sn, Ti, Zr or Al; when Me is Sn, Ti or Zr, m is 1, and when Me is Al, m is 0;
R is alkyl having from about eight to about fifty carbon atoms; X, and X 2 are independently selected from the group consisting of -R,. -OR,, -OCOR 1 , -SR,, -S(CH 2 ) n COOR 1 ,
X 1 and X 2 can be combined to form
R 1 is selected from the group consisting of alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms; R 2 is alkylene having from one to about fifty carbon atoms; R 3 is selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms; r is 0 or 1.-
2.发明授权Providing hydrophobic surfaces on hydrophilic inorganic materials with metal glycolates 失效在含有金属甘油酯的疏水性无机材料中提供疏水性表面
公开(公告)号：EP0133702B1
公开(公告)日：1989-03-01
申请号：EP84109443.6
申请日：1984-08-08
发明人： Inoue, Tetsuyu , Tsuruga, Kouji , Harada, Masashi
CPC分类号： C07F9/09 , C01P2002/82 , C01P2004/10 , C01P2004/61 , C01P2004/62 , C01P2006/22 , C01P2006/60 , C01P2006/90 , C07F5/069 , C07F7/006 , C07F7/2232 , C07F9/098 , C08K9/04 , C09C3/08
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3.发明公开Providing hydrophobic surfaces on hydrophilic inorganic materials with metal glycolates 失效疏水性表面的制备亲水性无机材料，金属甘醇酸。
公开(公告)号：EP0133702A2
公开(公告)日：1985-03-06
申请号：EP84109443.6
申请日：1984-08-08
发明人： Inoue, Tetsuyu , Tsuruga, Kouji , Harada, Masashi
CPC分类号： C07F9/09 , C01P2002/82 , C01P2004/10 , C01P2004/61 , C01P2004/62 , C01P2006/22 , C01P2006/60 , C01P2006/90 , C07F5/069 , C07F7/006 , C07F7/2232 , C07F9/098 , C08K9/04 , C09C3/08
摘要： Hydrophilic inorganic materials are provided with a hydrophobic surface by treatment with a metal glycolate compound having the formula:
wherein:
Me is Sn, Ti, Zr or Al;
when Me is Sn, Ti or Zr, m is 1, and when Me is Al, m is 0;
R is alkyl having from about eight to about fifty carbon atoms;
X, and X 2 are independently selected from the group consisting of -R,. -OR,, -OCOR 1 , -SR,, -S(CH 2 ) n COOR 1 ,
X 1 and X 2 can be combined to form
R 1 is selected from the group consisting of alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms;
R 2 is alkylene having from one to about fifty carbon atoms;
R 3 is selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; alkenyl having from three to about eighteen carbon atoms; cycloalkyl having from five to about eight carbon atoms; and aryl and alkaryl having from six to about eighteen carbon atoms;
r is 0 or 1.-
4.发明授权Chlorinated organic compounds having their resistance to deterioration enhanced by 1,3-dicarbonyl compounds 无效具有抗1,3-丁二烯化合物增强作用的氯化有机化合物
公开(公告)号：EP0035268B1
公开(公告)日：1984-09-19
申请号：EP81101490.1
申请日：1981-03-02
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5.发明公开Chlorinated organic compounds having their resistance to deterioration enhanced by 1,3-dicarbonyl compounds 无效通过1,3-二羰基化合物与氯化增加的稳定性的有机化合物。
公开(公告)号：EP0035268A1
公开(公告)日：1981-09-09
申请号：EP81101490.1
申请日：1981-03-02
摘要： Chlorinated organic compounds having their resistance to deterioration (when heated, exposed to light or water, or in contact with certain metals such as iron and aluminum) enhanced by a 1,3-dicarbonyl compound having the formula:
wherein:
R is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR,, ester COOR I , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms;
R 2 is defined as R 1 except that it cannot be hydrogen;
R, is defined as R, and can additionallv stand for
as well as metal and organotin enolate salts thereof.
The compounds are effective in enhancing the resistance to deterioration of chlorinated hydrocarbons and chlorinated higher fatty acid esters.
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