Modified aluminium hydrides, their preparation and their use in reducing acetylnaphthalene derivatives
    6.
    发明公开
    Modified aluminium hydrides, their preparation and their use in reducing acetylnaphthalene derivatives 失效
    改性铝酸盐,它们的制备及其在减少乙酰苯胺衍生物中的用途

    公开(公告)号:EP0035355A3

    公开(公告)日:1982-01-20

    申请号:EP81300754

    申请日:1981-02-24

    CPC分类号: C07C43/23 C07F5/069

    摘要: A modified lithium aluminium hydride type reducing agent is useful for reducing organic compounds having a carbonyl group-(ketone group of aldehyde group) in their structure to the corresponding alcohols. It is obtained by reacting one equivalent of lithium aluminium hydride with one equivalent of an optically active N-substituted ephedrine of the formula,
    (wherein R, is a C i -C 4 alkyl group or benzyl group and Ph is phenyl group)
    and two equivalents of an N-substituted aniline of the formula,
    (wherein R 2 is a C 1 -C 4 alkyl group or phenyl group, and Ph is phenyl group). The reducing agent is particularly useful for reducing 2-acetyl-5, 8-dimethoxy-3, 4-dihydronaphthalene to the corresponding 2-(1'-hydroxy)ethyl compound, and, by selecting a particular modified aluminium hydride the unsymmetrical ketone can be reduced to selectively produce either an alcohol in which the asymmetric carbon atom bonded to the hydroxy group is in R-configuration or an alcohol in which said asymmetric carbon atom is in S-configuration.

    Production of aluminum alkyls
    7.
    发明公开
    Production of aluminum alkyls 失效
    生产铝合金

    公开(公告)号:EP0024462A3

    公开(公告)日:1981-10-07

    申请号:EP80100069

    申请日:1980-01-07

    申请人: CONOCO INC.

    IPC分类号: C07F05/06 B01D29/30

    CPC分类号: C07F5/063

    摘要: An improved method is disclosed for continuously purifying crude aluminum alkyls containing solid contaminants such as aluminum particles comprising passing crude aluminum alkyls into a first holding vessel, the contents of said vessel being continuously passed under pressure through a tubular filter having an upstream inner surface and a downstream outer surface, solids-containing aluminum alkyls passing through said tubularfilter returning to the holding vessel, and purified aluminum alkyls passing through the filter wall exiting through the downstream outer surface, and recovered; monitoring the solids content of the holding vessel and ceasing crude aluminum alkyl flow into said holding vessel when solid contents reach undesirably high levels, thereafter passing said crude aluminum alkyls into an alternate holding vessel and filter, then further passing the contents of said first holding vessel through said tubular filter until substantially all remaining aluminum alkyls have passed through the filter to recovery, and purging the contents of said first holding vessel before filtration is resumed.

    摘要翻译: 公开了一种改进的方法,用于连续纯化含有固体污染物的粗烷基铝,所述固体污染物包括使粗烷基铝通过第一保持容器,所述容器的内容物在压力下连续通过具有上游内表面和 下游外表面,通过所述管状过滤器返回到保持容器的含固体的烷基铝烷,以及经过通过下游外表面离开的过滤壁的纯化烷基铝,并回收; 监测固定容器的固体含量,并且当固体含量达到不期望的高水平时停止粗铝烷基流入所述保持容器,之后将所述粗制烷基铝烷基转化成替代的保持容器和过滤器,然后进一步使所述第一保持容器 通过所述管式过滤器直到基本上剩余的所有的烷基铝都已经通过过滤器以回收,并且在过滤之前,清除所述第一保持容器的内容物。

    Coupling agent system of aluminium
    8.
    发明公开
    Coupling agent system of aluminium 失效
    铝联轴器系统

    公开(公告)号:EP0198374A3

    公开(公告)日:1988-07-20

    申请号:EP86104686

    申请日:1986-04-05

    CPC分类号: C07C51/418 C07F5/069

    摘要: The present invention relates to aluminate coupling agents, their synthesis and appliations. metallic aluminum is reacted with lower alcohols, then reacted with selected longer chain alcohols, phenols, carboxylic acids etc., satisfied the coordination num- be l of aluminum to give aluminate coupling agents having good hydrolytic stability and lower associativity. They can be used directly as typical coupling agents in processing of composition products such as plastics, rubber, coatings and laminates etc., and as adhesive promoter or primer to treat fillers, pigments and various materials in order to improve the processing and the quality of products, to increase the dosage of filler, to develop new products, to reduce energy consuming and cost of products.