摘要:
A polymerizable thioxanthone according to Formula (I):
wherein, A represents a thioxanthone moiety; R1 and R2 are independently selected from the group consisting of a hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group and a heteroaryl group; n represent 1 or 2; and R3 represents a moiety comprising at least one free radical polymerizable group selected from the group consisting of an acrylate, a methacrylate, an acrylamide, a methacrylamide, a styrene group, a maleate, a fumarate, an itaconate, a vinyl ether, a vinyl ester, an allyl ether and an allyl ester.
摘要翻译:根据式(I)的可聚合噻吨酮:其中,A表示噻吨酮部分; R 1和R 2独立地选自氢,烷基,烯基,炔基,芳基和杂芳基; n表示1或2; 并且R 3表示包含至少一个选自丙烯酸酯,甲基丙烯酸酯,丙烯酰胺,甲基丙烯酰胺,苯乙烯基,马来酸酯,富马酸酯,衣康酸酯,乙烯基醚,乙烯基醚的自由基可聚合基团的部分 酯,烯丙基醚和烯丙基酯。
摘要:
A radiation curable liquid including at least one free radical polymerizable monomer or oligomer, at least one diffusion hindered acetalysation catalyst and at least one diffusion hindered hydroxyl containing compound. The radiation curable liquid applied to a substrate prevents migration of very low viscous monomers, such as vinyl ether acrylate monomers, into the substrate.
摘要:
A polymeric dispersant including at least one oxalylamide structural unit according to Formula (I):
wherein: R1 represents a first polymeric moiety selected from the group consisting of a linear polymeric moiety, a star shaped polymeric moiety, a dendritic polymeric moiety, a branched polymeric moiety and a hyperbranched polymeric moiety; and R2 represents a second polymeric moiety selected from the group consisting of a polyester, a polyether, a polyamide, a polyacrylate, a polymethacrylate or copolymers thereof. Methods of preparation and non-aqueous pigment dispersions with the polymeric dispersant are also disclosed.
摘要:
A free radical curable liquid for inkjet printing of food packaging materials comprising no initiator or otherwise one or more initiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric initiators, polymeric initiators and polymerizable initiators; wherein the polymerizable composition of said liquid consists essentially of: a) 25 - 100 wt% of one or more polymerizable compounds A having at least one acrylate group G1 and at least one second ethylenically unsaturated polymerizable functional group G2 different from the group G1; b) 0 - 55 wt% of one or more polymerizable compounds B selected from the group consisting of monofunctional acrylates and difunctional acrylates; and c) 0 - 55 wt% of one or more polymerizable compounds C selected from the group consisting of trifunctional acrylates, tetrafunctional acrylates, pentafunctional acrylates and hexafunctional acrylates, with the proviso that if the weight percentage of compounds B > 24 wt%, then the weight percentage of compounds C > 1 wt%;
and wherein all weight percentages of A, B and C are based upon the total weight of the polymerizable composition; with the proviso that at least one polymerizable compound B or C is present in the polymerizable composition if the free radical curable liquid contains no initiator; wherein the polymerizable compound A has a copolymerization ratio of
with r 1 and r 2 representing the copolymerization parameters of methyl-G1 respectively methyl-G2 determined according to the method of Kelen-Tudos.
摘要:
A liquid radiation curable composition for inkjet printing comprising a photoinitiating system consisting of one or more diffusion hindered photoinitiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric or polymeric initiators and polymerizable initiators and one or more polymerizable co-initiators wherein at least one of the polymerizable co-initiators is a polymerizable aromatic tertiary amine. Inkjet inks, an inkjet printing process and packaging materials are also disclosed.
摘要:
A method of making a lithographic printing plate comprising the steps of: a) providing a lithographic printing plate precursor comprising (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer, (ii) a coating on said support, comprising a photopolymerizable layer, and, optionally, an intermediate layer between the photopolymerizable layer and the support,
wherein said photopolymerizable layer comprises a polymerizable compound, a polymerization initiator and a binder, b) image-wise exposing said coating in a plate setter, c) optionally, heating the precursor in a preheating unit, d) developing the precursor off-press in a gumming unit by treating the coating of the precursor with a gum solution, thereby removing the non-exposed areas of the photopolymerizable layer from the support,
wherein said polymerization initiator comprises a solubilizing group capable of solubilizing the initiator in the gum solution.