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1.发明公开Catalyst formulation and polymerization processes 失效Katalysatorformulierung und Polymerisationsverfahren。
公开(公告)号：EP0559633A2
公开(公告)日：1993-09-08
申请号：EP93870038.2
申请日：1993-03-02
CPC分类号： C08F10/00 , C08F4/60 , C08F110/06 , C08F2/00 , C08F4/6465
摘要： The present invention relates to a method for producing a mixture of a Ziegler-type catalyst formulation comprising a transition metal component, an external electron donor component, and a cocatalyst component to be charged to a polymerization reactor.
摘要翻译： 本发明涉及一种用于制备齐格勒型催化剂制剂的混合物的方法，其包含过渡金属组分，外电子给体组分和待加入到聚合反应器中的助催化剂组分。
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公开(公告)号：EP0559633B1
公开(公告)日：1999-06-30
申请号：EP93870038.2
申请日：1993-03-02
CPC分类号： C08F10/00 , C08F4/60 , C08F110/06 , C08F2/00 , C08F4/6465
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公开(公告)号：EP0531270B1
公开(公告)日：1996-07-24
申请号：EP92870124.2
申请日：1992-08-17
CPC分类号： C08F10/00 , C08F4/6094 , C08F4/602
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公开(公告)号：EP0559633A3
公开(公告)日：1994-07-13
申请号：EP93870038.2
申请日：1993-03-02
CPC分类号： C08F10/00 , C08F4/60 , C08F110/06 , C08F2/00 , C08F4/6465
摘要： The present invention relates to a method for producing a mixture of a Ziegler-type catalyst formulation comprising a transition metal component, an external electron donor component, and a cocatalyst component to be charged to a polymerization reactor.
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公开(公告)号：EP0531270A1
公开(公告)日：1993-03-10
申请号：EP92870124.2
申请日：1992-08-17
CPC分类号： C08F10/00 , C08F4/6094 , C08F4/602
摘要： The invention is for a catalyst system, a process for making the catalyst system and a process for olefin polymerization using the catalyst system. The catalyst system comprises alcohol or diethylaluminum alkoxide added to a conventional Ziegler-Natta catalyst component, an aluminum alkyl co-catalyst and, optionally, an electron donor. The aluminum alkyl is preferably triethyl aluminum
Addition of alcohol in a range of from 0.03 to 0.25 results in a increase in catalyst efficiency and polymerization yield. Normal or linear chain alcohols, such as methanol and ethanol, seem to have a positive effect whereas branched alcohols appears to have no positive effect.
The mole-to-mole ratio of diethylaluminum alkoxide to aluminum alkyl ranges from 0.05 to 0.2. This invention is effective for the aluminum/transition metal ratio for the polymerization of olefins ranges from about 100 to about 500. Polymerization yield increases of greater than 10% are realized. The diethylaluminum alkoxide is preferably diethylaluminum ethoxide.摘要翻译： 本发明涉及催化剂体系，制备催化剂体系的方法和使用该催化剂体系的烯烃聚合方法。 催化剂体系包括加入常规齐格勒 - 纳塔催化剂组分的醇或二乙基铝醇盐，烷基铝催化剂和任选的电子给体。 烷基铝优选为三乙基铝。在0.03至0.25的范围内添加醇导致催化剂效率和聚合产率的提高。 正链或直链醇如甲醇和乙醇似乎具有积极的作用，而支链醇似乎没有积极的作用。 二烷基铝与烷基铝的摩尔比摩尔比为0.05-0.2。 本发明对于烯烃聚合的铝/过渡金属比例为约100至约500有效。实现了大于10％的聚合产率增加。 二乙基烷氧基铝优选为二乙基乙氧基铝。
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