公开(公告)号：EP3778992A1

公开(公告)日：2021-02-17

申请号：EP19776652.0

申请日：2019-03-28

Applicant: Japan Science and Technology Agency

Inventor： HOSONO, Hideo ,  YOKOYAMA, Toshiharu ,  TODA, Yoshitake ,  ISHIYAMA, Shintaro ,  TAGUCHI, Masami ,  TAKAHASHI, Hiroki

IPC: C25B11/06 ,  C01F7/16 ,  C25B1/02 ,  C25B9/00 ,  C25B13/04

Abstract: An electrolytic cell capable of simply electrolyzing carbon dioxide into carbon monoxide and oxygen with low activation energy, and an electrolytic device. The carbon dioxide electrolytic cell includes a cathode, an anode, and a solid electrolyte having oxide ion conductivity. The cathode is the following (A) or (B); (A) a metal and a first mayenite-type compound are included therein or (B) a metal and a second mayenite-type compound are included therein, said second mayenite type compound including a mayenite type compound having electron conductivity.

公开(公告)号：EP4112166A1

公开(公告)日：2023-01-04

申请号：EP21760680.5

申请日：2021-02-16

Applicant: Japan Science and Technology Agency

Inventor： KITANO, Masaaki ,  HOSONO, Hideo ,  YOKOYAMA, Toshiharu ,  KUJIRAI, Jun ,  OGASAWARA, Kiya

IPC: B01J27/24 ,  B01J32/00 ,  B01J37/08 ,  C01C1/04

Abstract: The present invention is related to an oxynitride-hydride which is capable of achieving both stabilization and improvement of catalyst performance when used as a support, and the oxynitride-hydride can be easily synthesized. The oxynitride-hydride is represented by the following general formula (1),

        A n B m O l-x N y H z      (1)

wherein in the general formula (1), x represents a number represented by 0.1 ≤ x ≤ 3.5; y represents a number represented by 0.1 ≤ y ≤ 2.0; and z represents a number represented by 0.1 ≤ z ≤ 2.0.

公开(公告)号：EP2898946B1

公开(公告)日：2020-07-22

申请号：EP13839735.1

申请日：2013-08-20

Applicant: Tokyo Institute of Technology ,  Japan Science and Technology Agency

Inventor： HOSONO, Hideo ,  HAYASHI, Fumitaka ,  YOKOYAMA, Toshiharu ,  TODA, Yoshitake ,  HARA, Michikazu ,  KITANO, Masaaki

IPC: B01J23/58 ,  B01J23/78 ,  B01J35/10 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  B01J37/16 ,  C01B3/00 ,  C01B3/04 ,  B01J37/18 ,  B01J37/10 ,  B01J37/34 ,  B01J35/00 ,  B01J21/16 ,  B01J23/46

公开(公告)号：EP3932546A1

公开(公告)日：2022-01-05

申请号：EP20762193.9

申请日：2020-02-26

Applicant: Japan Science and Technology Agency

Inventor： KITANO, Masaaki ,  HOSONO, Hideo ,  YOKOYAMA, Toshiharu ,  KUJIRAI, Jun

IPC: B01J27/24 ,  B01J32/00 ,  B01J37/08 ,  C01B21/092 ,  C01C1/02

Abstract: The invention provides a perovskite-type oxynitride hydride which can be easily synthesized by achieving both improvement in catalytic performance and stabilization when used as a support of a catalyst. The oxynitride hydride is represented by general formula (1a) or (1b).

        ABO 3-x N y H z      (1a)

        AB 2 O 4-x N y H z      (lb)


(In the above general formulas (1 a) and (1 b), A is at least one selected from the group consisting of Ba and Sr; B is at least one selected from the group consisting of Ce, La and Y; x represents a number represented by 0.2 ≤ x ≤ 2.0; y represents a number represented by 0.1 ≤ y ≤ 1.0; and z represents a number represented by 0.1 ≤ z ≤ 1.0.)

公开(公告)号：EP3228386B1

公开(公告)日：2020-04-22

申请号：EP15864436.9

申请日：2015-12-04

Applicant: Japan Science and Technology Agency ,  Tokyo Institute of Technology

Inventor： HOSONO, Hideo ,  HARA, Michikazu ,  KITANO, Masaaki ,  YOKOYAMA, Toshiharu ,  INOUE, Yasunori

IPC: B01J27/24 ,  B01J35/10 ,  C01C1/04 ,  B01J37/04 ,  B01J37/08 ,  B01J37/02 ,  B01J21/18 ,  B01J23/58 ,  B01J23/63 ,  B01J23/64 ,  B01J35/00 ,  C01B3/04 ,  C01B21/09 ,  B01J23/648 ,  C01B21/092

公开(公告)号：EP3395441A1

公开(公告)日：2018-10-31

申请号：EP16878915.4

申请日：2016-12-22

Applicant: Tokyo Institute of Technology ,  Japan Science and Technology Agency

Inventor： HOSONO, Hideo ,  KITANO, Masaaki ,  TADA, Tomofumi ,  YOKOYAMA, Toshiharu ,  TODA, Yoshitake ,  LU, Yangfan ,  LI, Jiang

IPC: B01J23/63 ,  C01C1/04

CPC classification number: B01J23/462 ,  B01J23/10 ,  B01J23/14 ,  B01J23/63 ,  B01J35/0006 ,  C01C1/04 ,  C01C1/0411 ,  Y02P20/52

Abstract: An electride, which is more stable and can be more easily obtained, is provided or is made available, and as a result, a catalyst particularly useful for chemical synthesis, in which the electride is particularly used, is provided.
A transition metal-supported intermetallic compound having a transition metal supported on an intermetallic compound represented by the following formula (1):

        A 5 X 3 ...     (1)

wherein A represents a rare earth element, and X represents Si or Ge.

公开(公告)号：EP4431456A1

公开(公告)日：2024-09-18

申请号：EP22892684.6

申请日：2022-11-02

Applicant: Japan Science and Technology Agency

Inventor： KITANO, Masaaki ,  HOSONO, Hideo ,  YOKOYAMA, Toshiharu ,  OKUNAKA, Masaaki

IPC: C01C1/04 ,  B01J37/04 ,  B01J37/08 ,  B01J23/58 ,  B01J23/63 ,  B01J23/78 ,  B01J23/89 ,  B01J27/22

CPC classification number: Y02P20/52 ,  B01J23/58 ,  B01J23/63 ,  B01J23/78 ,  B01J23/89 ,  B01J27/22 ,  B01J37/04 ,  B01J37/08 ,  C01C1/04

Abstract: The invention provides a catalyst composition capable of improving catalyst performance by adding a catalyst additive. The catalyst composition comprises a catalyst additive represented by formula (1): LmAn; and a chemical reaction catalyst that includes a catalyst substance represented by formula (2): MpOqCwNsHt. In formula (1), L represents at least one selected from the group consisting of transition elements and Al; A represents at least one selected from the group consisting of Si, O, N, and C; m represents a numerical value of 1 or more; and n represents a numerical value of 0 or more. In formula (2), M represents one or more selected from the group consisting of typical elements and transition elements, wherein M does not include Al and Ca at the same time; p represents a numerical value of 0 or more; q represents a numerical value of 0 or more; w represents a numerical value of 0 or more; s represents a numerical value of 0 or more; and t represents a numerical value of 0 or more; q, w, s, and t are not 0 at the same time.)

公开(公告)号：EP2650047B1

公开(公告)日：2018-01-31

申请号：EP11847578.9

申请日：2011-12-06

Applicant: Tokyo Institute of Technology ,  Japan Science and Technology Agency

Inventor： HOSONO, Hideo ,  HARA, Michikazu ,  KITANO, Masaaki ,  KIM, Sung Wng ,  MATSUISHI, Satoru ,  TODA, Yoshitake ,  YOKOYAMA, Toshiharu ,  HAYASHI, Fumitaka

IPC: B01J23/58 ,  B01J23/78 ,  C01C1/04

CPC classification number: C01C1/0411 ,  B01J21/04 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/1009 ,  B01J37/0201 ,  B01J37/086 ,  B01J37/16 ,  B01J37/18 ,  Y02P20/52

Abstract: The present invention provides a catalyst substance that is stable and performs well in the synthesis of ammonia, one of the most important chemical substances for fertilizer ingredients and the like. The catalyst substance exhibits catalytic activity under mild synthesis conditions not requiring high pressure, and is also advantageous from a resource perspective. Further provided is a method for producing the same. This catalyst comprises a supported metal catalyst that is supported on a mayenite type compound including conduction electrons of 10 15 cm -3 or more and serving as a support for the ammonia synthesis catalyst. The mayenite type compound used as the support may take any form, including that of powder, a porous material, a sintered body, a thin-film, or a single crystal. Use of this catalyst makes it possible to increase the electron donating ability toward a transition metal, and to promote ammonia synthesis by reacting nitrogen and hydrogen as starting materials on the catalyst under low reaction pressure between about 10kPa and 30MPa at reactive temperature between 100 and 600°C.