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公开(公告)号：EP0209382A2
公开(公告)日：1987-01-21
申请号：EP86305493.8
申请日：1986-07-16
发明人： Inoue, Takao , Sakairi, Tadashi , Aritomi, Mitsutoshi Mitsubishi Petrochem. Co. Ltd. , Takeyama, Tadao Mitsubishi Petrochem. Co. Ltd. , Matuo, Takahiro
CPC分类号： B29C35/0222 , B29C35/02 , B29C35/08 , B29C39/006 , B29K2033/04
摘要： A mixture of polyfunctional (meth)acrylate compound containing a C2-50 alcohol residue (100 parts),0.01-10 parts by wt of a radical initiatior and optionally up to 10 wt % of another radical polymerisable monomer as viscosity controller (e.g. styrene) is poured into a mold (formed by a ring on a glass plate), and polymerised at 10-200°C for not more than 2 hours under heating, light or electron beam irradiation, until the glass transition temperature (Tg) is 10 to 100°C, and the transparent plastics disc formed is removed from the mold without breakage.
The substrate is then post-cured on a flat surface by heating or UV or electron beam irradiation until its Tg is 150°C, and preferably further post-cured until its Tg is 200°C, to remove residual strain and double bonds.
A recording layer for an optical or magneto-optical disc is formed on the substrate; a higher post-curing temperature reduces the number of pinholes in the layer.摘要翻译： 含有C2-50醇残基（100份）的多官能（甲基）丙烯酸酯化合物的混合物，0.01-10重量份的引发剂和任选的至多10重量％的另一个可自由基聚合的单体作为粘度控制剂（例如苯乙烯） 倒入模具中（由玻璃板上的环形成），并在加热，光或电子束照射下在10-200℃下聚合不超过2小时，直到玻璃化转变温度（Tg）为10〜 100℃，形成的透明塑料盘从模具中除去而不破裂。 然后通过加热或UV或电子束照射将基底在平坦表面上后固化，直到其Tg为150℃，并且优选进一步后固化直到其Tg为200℃，以除去残余应变 和双重债券。 在基板上形成用于光学或磁光盘的记录层; 较高的后固化温度降低了该层中针孔的数量。
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公开(公告)号：EP0210036B1
公开(公告)日：1993-02-10
申请号：EP86305412.8
申请日：1986-07-14
发明人： Aritomi, Mitsutoshi Mitsubishi Petrochem. Co. Ltd. , Terauchi, Makoto Mitsubishi Petrochem. Co. Ltd.
IPC分类号： C08G73/14
CPC分类号： C08G73/14
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公开(公告)号：EP0210036A2
公开(公告)日：1987-01-28
申请号：EP86305412.8
申请日：1986-07-14
发明人： Aritomi, Mitsutoshi Mitsubishi Petrochem. Co. Ltd. , Terauchi, Makoto Mitsubishi Petrochem. Co. Ltd.
IPC分类号： C08G73/14
CPC分类号： C08G73/14
摘要： An aromatic poly(thioetheramide-imide) has a recurring unit of the following general formula (II):
wherein each -Ar-, which may be the same or different represents a divalent aromatic residue.
Preparation is by reacting an aromatic diamine H₂N-C₆H₄-S-Ar-S-C₆H₄-NH₂ with trimellitic anhydride or its chloride, preferably in a polar organic solvent in the presence of a HCl trapping agent, followed by dehydration.
The polymer is moldable optionally with a filler, to form a shaped product, film or fibres of good strength.
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