摘要:
The invention is based on the finding that when conducting crystallization of FDCA at high temperatures, the formation of significant amounts of colored byproduct can be reduced or even avoided when the FDCA mixture is kept at temperatures above 100 °C for less than 15 minutes. This is achieved by conducting the crystallization process in a continuous reactor. Accordingly, the method comprises the steps of feeding a mixture comprising undissolved FDCA and a solvent to a reactor; and dissolving FDCA by superheating the mixture in the reactor to a temperature of at least 130 °C; and crystallizing FDCA by cooling the mixture in the reactor, wherein the reactor is a continuous reactor and the residence time in the reactor zone wherein the FDCA mixture has a temperature above 100 °C is less than 15 minutes.
摘要:
The invention is in the field of recycling plastic waste. In particular, the invention is directed to a method separate polyolefins from plastic waste based on a dissolution/precipitation approach. The method according to the present invention may be used to separate polyolefins with a high selectivity by using at least a first and a second cooling surface. The invention is particularly suitable to at least partially separate LLDPE and LDPE or polypropylene and polyethylene from plastic waste.
摘要:
The invention is in the field of recycling plastic waste. In particular, the invention is directed to a method to separate polycarbonate and a first-component from plastic waste. In particular, the method according to the present invention may be used to efficiently separate polycarbonate and the first component with high purity and yield. The method is based on nonselective dissolution and selective precipitation.
摘要:
The invention is directed to a method and apparatus for carrying out a continuous physical or chemical process, in particular crystallisation, sad process comprising flowing a fluid through a channel comprising an inlet and an outlet for said fluid, wherein said channel is at least in part curved and comprises at least two curvatures, allowing said chemical process to occur, while reversing the direction of the flow of said fluid in said channel multiple times.
摘要:
The invention is directed to a system for energy storage comprising a chemical combustion reactor comprising a reactor segment that comprises at least one porous active fixed beds that is at least partially surrounded by an insulating mantle. The active beds comprise a metal and/or oxide thereof.
摘要:
The invention is directed to a process for the purification of a raw hydrogen gas stream comprising hydrogen gas in an amount of 85-99%, said process comprising the step of contacting said raw hydrogen gas stream with an oxidized bed comprising an oxidized metal resulting in a waste gas stream comprising water and less than 5% hydrogen gas, and in a reduction of said oxidized metal; and a step of contacting a bed comprising a reduced metal with water to produce a purified hydrogen gas stream comprising more than 99% hydrogen gas, preferably comprising 99.97% or more hydrogen gas, and the oxidized metal. In a further aspect, the invention is directed to an apparatus suitable to carry out said process.