POLYCARBONATE MOLDED ARTICLE
    3.
    发明公开
    POLYCARBONATE MOLDED ARTICLE 审中-公开
    POLYCARBONATFORMARTIKEL

    公开(公告)号:EP2963075A1

    公开(公告)日:2016-01-06

    申请号:EP14756701.0

    申请日:2014-02-21

    申请人: Teijin Limited

    IPC分类号: C08G64/02 C08L69/00 F21S8/10

    摘要: A molded article such as a resin window or a lamp lens for vehicles which is formed from a polycarbonate and excellent in heat resistance, weather resistance, low water absorption, surface hardness and low-temperature impact properties.
    The molded article is formed from a polycarbonate which contains a unit (A) represented by the following formula (A) in an amount of 50 mol% or more based on the total of all recurring units and has a maximum impact energy of 20 J or more in a high-speed surface impact test based on ASTM D3763 in a -20°C environment and a brittle fracture rate of 50 % or less.

    摘要翻译: 由聚碳酸酯形成的耐候性,耐候性,低吸水性,表面硬度,低温冲击性优异的车辆用树脂窗或灯透镜等成型品。 模塑制品由聚碳酸酯形成,该聚碳酸酯包含基于所有重复单元的总和为50摩尔%以上的由下式(A)表示的单元(A),并且具有20J的最大冲击能量或 更多的是在-20℃环境下基于ASTM D3763的高速表面冲击试验,脆性断裂率为50%以下。

    POLYMER HAVING EXCELLENT COMPATIBILITY WITH THERMOPLASTIC RESIN

    公开(公告)号:EP4130103A1

    公开(公告)日:2023-02-08

    申请号:EP21781196.7

    申请日:2021-03-29

    申请人: Teijin Limited

    摘要: The purpose of the present invention is to provide a polymer having excellent compatibility with thermoplastic resins. The present invention is a polymer (B), which essentially contains units represented by the following formulas (1), (2) and (3), wherein the number of moles of the unit (1) is 0 to 95, the number of moles of the unit (2) is 0 to 50, and the number of moles of unit (3) is 2 to 80 when the total number of moles of the units (1), (2) and (3) is 100.

    in the units (1) to (3), "X" is a recurring unit having a benzene ring, in the unit (2), -CH 3 is a methyl group substituted for the hydrogen atom of the benzene ring of "X", "m" is an integer of 1 to 6 indicative of the number of the methyl group, the unit (3) is a unit obtained by substituting the hydrogen atom of -CH 3 in the unit (2) by a substituent "Z" derived from a carboxylic acid or anhydride thereof, "n" is an integer of 1 to 6 indicative of the number of substitutions, l+n=m, and the unit (3) is a unit in which "n" is 1, 2, 3, 4, 5, 6 or a combination thereof.

    POLYCARBONATE RESIN COMPOSITION
    5.
    发明授权

    公开(公告)号:EP3135727B1

    公开(公告)日:2018-09-26

    申请号:EP15783907.7

    申请日:2015-04-20

    申请人: Teijin Limited

    摘要: A polycarbonate resin composition comprising a polycarbonate resin and 0.001 to 1 parts by weight of an N-R type (R represents an alkyl group) hindered amine-based optical stabilizer per 100 parts by weight of the polycarbonate resin, wherein the polycarbonate resin comprises 40 mol% or more of a recurring unit (A) represented by the following formula and satisfies the following formulas (i) to (v), and the resin composition has excellent heat resistance, a low water absorption coefficient and high transparency, and suppresses deterioration during long-term use: (i) a metal compound comprising a negative ion represented by the following formula (B) and a positive ion constituted by a metal is used as a polymerization catalyst in an amount of 1 × 10 -9 to 1 × 10 -5 molar equivalent relative to the total diol compounds used for polymerization; (ii) the specific viscosity measured with a methylene chloride solution at 20°C is 0.23 to 0.60; (iii) the glass transition temperature is 100°C to 160°C; (iv) the saturated water absorption coefficient is 2.5% or less; and (v) the relationship between the glass transition temperature (Tg°C) and the saturated water absorption coefficient (Wa%) satisfies the following formula (I): 2.5 ‰¤ Tw value = Tg × 0.04 ˆ’ Wa wherein R 1 is an alkylene group, a cycloalkylene group, or an arylalkylene group which has 1 to 22 carbon atoms and may be linear or branched.

    FLAME-RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE PRODUCED FROM SAME
    6.
    发明公开
    FLAME-RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE PRODUCED FROM SAME 审中-公开
    阻燃树脂组合物和由其制成的模制制品

    公开(公告)号:EP3249010A1

    公开(公告)日:2017-11-29

    申请号:EP16740159.5

    申请日:2016-01-19

    申请人: Teijin Limited

    IPC分类号: C08L33/04 C08K5/5357

    摘要: A flame retardant resin composition containing 1 to 100 parts by weight of (B) an organophosphorus compound (component B) presented by the following formula (1) per 100 parts by weight of (A) a resin component (component A) containing at least 60 wt% of an acrylic resin has high flame retardancy, high transparency and satisfactory physical properties.

    (wherein X 1 and X 2 are the same or different, and represent alkyl groups substituted with aromatic groups represented by the following formula (2):),

    (wherein AL represents a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar represents a phenyl group, a naphthyl group, or an anthryl group each optionally substituted, n represents an integer of 1 to 3, and Ar can be bonded to any carbon atom in AL.)

    摘要翻译: 一种阻燃性树脂组合物,相对于100重量份的(A)至少含有(B)有机磷化合物(B成分)的树脂成分(A成分) 60wt%的丙烯酸树脂具有高阻燃性,高透明度和令人满意的物理性能。 (式中,X 1和X 2相同或不同,表示用下述式(2)表示的芳香族基团取代的烷基:)(式中,AL表示碳原子数1〜5的支链状或直链状的脂肪族烃基,Ar表示 苯基,萘基或蒽基各自任选被取代,n表示1至3的整数,并且Ar可以与AL中的任何碳原子键合)。

    COPOLYCARBONATE
    7.
    发明公开
    COPOLYCARBONATE 审中-公开
    共聚碳酸酯

    公开(公告)号:EP3018162A1

    公开(公告)日:2016-05-11

    申请号:EP15199396.1

    申请日:2013-04-18

    申请人: TEIJIN LIMITED

    IPC分类号: C08G64/02 C08G63/64

    CPC分类号: C08G64/0208 C08G63/64

    摘要: A copolycarbonate having a low water absorption coefficient and excellent heat resistance, low temperature characteristics and surface hardness is provided.
    The copolycarbonate (Z) of the present invention contains a unit (A) represented by the following formula and a unit (B) represented by the following formula (B) as main recurring units, the (A/B n=1 ) molar ratio of the unit (A) and the unit (B n=1 ) being 40/60 to 99/1. The unit (B n=1 ) is a single unit constituting a block.


    (R 1 is an alkylene group or cycloalkylene group, all of which may be substituted by an aromatic group having 6 to 12 carbon atoms. R 2 is an alkylene group, cycloalkylene group or arylene group, all of which may be substituted by an aromatic group having 6 to 12 carbon atoms. "r" and "s" are each independently an integer of 0 to 4. "l" is 0; "m" is 0; and "n" is an integer of 2 to 100; or "l" is 1; "m" is 1; and "n" is an integer of 1 to 100.)

    摘要翻译: 提供具有低吸水系数和优异的耐热性,低温特性和表面硬度的共聚碳酸酯。 本发明的共聚碳酸酯(Z)包含作为主要重复单元的由下式表示的单元(A)和由下式(B)表示的单元(B),(A / Bn = 1) 单元(A)和单元(Bn = 1)为40/60至99/1。 单位(Bn = 1)是构成块的单个单位。 (R 1是亚烷基或亚环烷基,它们都可以被具有6-12个碳原子的芳族基团取代,R 2是亚烷基,亚环烷基或亚芳基,其全部可以被具有 6个或12个碳原子,“r”和“s”各自独立地为0至4的整数。“l”为0;“m”为0;“n”为2至100的整数;或“l “是1;”m“是1;”n“是1到100的整数。)

    ORGANOPHOSPHORUS COMPOUND, FLAME RETARDANT, AND FLAME-RETARDANT PRODUCT INCLUDING SAME

    公开(公告)号:EP3514161A1

    公开(公告)日:2019-07-24

    申请号:EP17850461.9

    申请日:2017-03-10

    申请人: Teijin Limited

    IPC分类号: C07F9/6574 C09K21/12

    摘要: To provide a non-halogen-based flame retardant for obtaining a flame-retardant product having high flame retardancy and a good appearance and a flame-retardant product comprising the same.
    An organic phosphorus-based compound which satisfies the following requirements (i) to (viii) and is represented by the following formula (1):
    (i) the organic purity should be not lower than 98 %;
    (ii) the solubility in 20°C water should be not higher than 0.1 g/100 g of water;
    (iii) the total halogen component content should be not higher than 1,000 ppm;
    (iv) the total volatile organic matter content should be not higher than 800 ppm;
    (v) the Δ pH value should be not larger than 1.0;
    (vi) the volume standard median diameter should be not larger than 30 µm;
    (vii) the maximum particle diameter should be not larger than 200 µm; and
    (viii) the standard deviation represented by the following formula (6) should be not larger than 20 µm. Standard deviation = d 84 % + d 16 % / 2
    d84 %: particle diameter at a point where the cumulative curve becomes 84 % (µm)
    d16 %: particle diameter at a point where the cumulative curve becomes 16 % (µm)

    (In the above formula, R 2 and R 5 may be the same or different and are each a phenyl group which may have a substituent, naphthyl group which may have a substituent, anthryl group which may have a substituent, or branched or linear alkyl group having 1 to 4 carbon atoms which may have an aromatic substituent. R 1 , R 3 , R 4 and R 6 may be the same or different and are each a hydrogen atom, branched or linear alkyl group having 1 to 4 carbon atoms, phenyl group which may have a substituent, naphthyl group which may have a substituent, or anthryl group which may have a substituent.)