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    Catalyst component production and use
    1.
    发明公开
    Catalyst component production and use 失效
    Katalysatorkomponente，ihre Herstellung und Verwendung。

    公开(公告)号：EP0131359A1

    公开(公告)日：1985-01-16

    申请号：EP84303408.3

    申请日：1984-05-18

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Kiff, Frank Thomas

    IPC分类号： C08F10/00 ,  C08F4/62

    CPC分类号： C08F10/00 ,  C08F4/6343 ,  C08F4/6543

    摘要： A catalyst component is prepared by treating a magnesium halide with a Lewis Base compound and a transition metal compound and subjecting the treated productto at least one washing step using a halogenated ethylene, for example tetrachloroethlene, at a temperature of greaterthan 80°C. The transition metal compound can be titanium tetrachloride and the Lewis Base compound an ester of an aromatic carboxylic acid, for example ethyl benzoate or di-isobutyl phthalate. The treatment can be effected in the presence of a non-metallic halide such as thionyl chloride. The treatment can be effected using a milling process. The product can be used for the polymerisation of olefin monomers such as propylene.

    摘要翻译： 通过用路易斯碱化合物和过渡金属化合物处理卤化镁并使用卤化乙烯（例如四氯乙烯）在大于80℃的温度下对经处理的产物进行至少一个洗涤步骤来制备催化剂组分。 过渡金属化合物可以是四氯化钛，路易斯碱化合物是芳族羧酸的酯，例如苯甲酸乙酯或邻苯二甲酸二异丁酯。 处理可以在非金属卤化物如亚硫酰氯的存在下进行。 可以使用研磨方法进行处理。 该产品可用于烯烃单体如丙烯的聚合。

    Transition metal composition, production and use
    2.
    发明公开
    Transition metal composition, production and use 失效
    过渡金属组合物，生产和使用

    公开(公告)号：EP0044735A3

    公开(公告)日：1982-08-25

    申请号：EP81303311

    申请日：1981-07-20

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Hartshorn, Angus John ,  Jones, Eric

    IPC分类号： C08F10/00 ,  C08F04/60 ,  C08F04/02 ,  C08F04/64

    CPC分类号： C08F10/00 ,  C08F4/022 ,  C08F4/6145 ,  C08F4/6355 ,  C08F4/618 ,  C08F4/6343

    摘要： A transition metal composition has the composition M m ,X p ,TYn'Z where M is a metal of Groups Ib, IIa, IIIb, Vila or VIII of the Periodic Table, X is an anion, T is a transition metal of Groups IVA-VIA of the Periodic Table, Y is an anion, Z is a melt-producing compound, m' is greater than zero and less than 100, n' is greater than zero and less than 8 (m' + 1), and p' is m' x(valency of M)/(valency of X). The compositions of this type may be transformed into a liquid by heating and the hot liquid sprayed and the spray cooled. The sprayed material has a useful particle form and may be used as a component of a polymerisation catalyst to polymerise an unsaturated monomer such as ethylene.

    Process for producing spherical carrier particles for olefin polymerisation catalyst, catalyst comprising such carrier particles, and use of such catalyst in olefin polymerisation
    3.
    发明公开
    Process for producing spherical carrier particles for olefin polymerisation catalyst, catalyst comprising such carrier particles, and use of such catalyst in olefin polymerisation 失效
    一种用于制造球形载体颗粒的烯烃聚合催化剂的方法，这些催化剂和使用烯烃聚合催化剂含有载体。

    公开(公告)号：EP0018737A1

    公开(公告)日：1980-11-12

    申请号：EP80301159.2

    申请日：1980-04-10

    申请人： MITSUI PETROCHEMICAL INDUSTRIES, LTD.

    发明人： Ushida, Yoshihisa ,  Amimoto, Yoshikatu ,  Toyota, Akinori ,  Kashiwa, Norio

    IPC分类号： C08F10/00 ,  C08F4/02 ,  C08F4/62

    CPC分类号： C08F10/00 ,  C08F4/6555 ,  C08F4/022 ,  C08F4/6545 ,  C08F4/6383 ,  C08F4/6343

    摘要： Catalysts comprising a transition metal compound supported on a carrier, and an organometallic compound have been used in the polymerisation of olefins. When the carrier particles are spherical olefin polymers can be produced in the form of spherical particles, but known spherical carrier particles either are insufficiently robust or are difficult and expensive to prepare.
    In accordance with the invention spherical carrier particles are prepared by:-

    (i) forming a suspension of molten particles of an adduct of a halogen-containing magnesium compound and an active hydrogen-containing organic compound in an organic liquid medium in the presence of at least one auxiliary component selected from surface-active agents and siloxanes, and
    (ii) quenching the resulting suspension to solidify the adduct particles.

    The resulting spherical carrier particles are robust and readily prepared in reproducible manner from conventional starting material. When used in catalysts for the polymerisation of olefins they provide polymers having a good balance of physical properties.

    摘要翻译： 催化剂包括负载在载体上，以及有机金属化合物的过渡金属化合物havebeen烯烃的聚合中使用。 当载体颗粒是球形的烯烃聚合物可以以球形颗粒的形式来产生，但公知的球形载体颗粒无论是不够健壮或是困难和昂贵的准备。 （i）如在存在在有机液体介质中形成悬浮液的含卤素的镁化合物含有活性氢的有机化合物的和的加合物的熔融颗粒 - ：在与本发明的球形载体颗粒雅舞蹈通过制备 从表面活性剂和硅氧烷，和（ii）淬火将所得悬浮液以固化加合物颗粒中选择至少一个辅助分量。 将得到的球形载体颗粒是健壮和在从传统的起始材料可重复的方式容易地制备。 当在催化剂的烯烃的聚合中使用它们提供具有物理特性的良好平衡的聚合物。

    Supported ziegler-natta catalysts for polyolefin production
    5.
    发明公开
    Supported ziegler-natta catalysts for polyolefin production 失效
    Ziegler-NattageträgerteKatalysatorefürPolyolefin-Herstellung

    公开(公告)号：EP0771820A1

    公开(公告)日：1997-05-07

    申请号：EP95117325.1

    申请日：1995-11-03

    申请人： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    发明人： Fowler, Elton Doyle ,  Awe, Michael David ,  Jorgensen, Robert James

    IPC分类号： C08F10/00 ,  C08F4/654

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/6355 ,  C08F4/6343 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

    摘要： Ziegler Natta catalysts for production of polyolefins, particularly polyethylene and copolymers thereof. Catalysts having improved activities are produced in a multi-stage procedure in which a porous supporting material is impregnated with a precursor composition, and then this is further treated one or more times with subpore volumes of secondary solutions of precursor components. Claims to the process for producing the catalysts, and to a process for making polyolefins using the catalysts are also presented.

    摘要翻译： 用于生产聚烯烃的齐格勒纳塔催化剂，特别是聚乙烯及其共聚物。 具有改善的活性的催化剂是在多阶段方法中制备的，其中多孔支撑材料用前体组合物浸渍，然后用次级体积的前体组分的二级溶液进一步处理一次或多次。 还提出了用于生产催化剂的方法的要求，以及使用该催化剂制备聚烯烃的方法。

    Vanadium based components and catalysts for the polymerization of olefins and polymerization processes using the same
    7.
    发明公开
    Vanadium based components and catalysts for the polymerization of olefins and polymerization processes using the same 失效
    基于VANADIUM的组分和用于烯烃聚合的催化剂和使用其的聚合方法

    公开(公告)号：EP0584606A3

    公开(公告)日：1994-07-06

    申请号：EP93112561.1

    申请日：1993-08-05

    申请人： Montell Technology Company bv

    发明人： Zucchini, Umberto ,  Dall'occo, Tiziano ,  Angelini, Antonella

    IPC分类号： C08F4/62 ,  C08F10/00 ,  C08F210/02

    CPC分类号： C08F10/00 ,  C08F4/6343 ,  C08F4/631 ,  C08F4/68

    摘要： Catalysts component of the (co)polymerization of alpha-olefins CH₂=CHR, wherein R is hydrogen or an alkyl radical having from 1 to 8 carbon atoms, comprising a product of the composition:
            VCl y . z(b)
    wherein (b) represents an organic compound selected from alkyl, aryl and acyl halides, y is a number higher than 2 and lower than 4, and preferably comprised between 2.5 and 3.5 and z is a number higher than zero and lower than or equal to 2, and preferably between 0.002 and 1. Components can be obtained as products of the reaction, carried out at temperatures higher than 10°C, between VCl₄ and the compound (b). Particularly preferred among compounds (b) are benzoyl chloride, p-methoxybenzoyl chloride and p-chloro benzoyl chloride.
    From the components of the invention, either supported or not, catalysts having high activity particularly useful for the production of ethylene polymers showing broad molecular weight distribution can be prepared.