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1.发明公开Spherical components and catalysts for the polymerization of olefins 失效KugelförmigeKomponenten und Katalysatoren zur Polymerisation von Olefinen。
公开(公告)号：EP0543227A1
公开(公告)日：1993-05-26
申请号：EP92118955.1
申请日：1992-11-05
CPC分类号： C08F10/00 , C08F4/6343 , C08F4/68
摘要： Spherical components of catalysts for the polymerization of olefins comprising:
(a) a vanadium compound selected from the compounds of formula VOX₂Y or VX n Y n-4n , where X is Cl or Br and Y is Cl, Br, OR or NR I ₂
(b) MgCl₂ in spherical form.
Said components have an average diameter greater than 1 µm, a surface area of at least 10 m²/g, a porosity of at least 0.1 g/cm³ and an X-ray spectrum having particular characteristics.摘要翻译： 用于烯烃聚合的催化剂的球形组分包括：（a）选自式VOX2Y或VXnYn-4n的钒化合物，其中X为Cl或Br，Y为Cl，Br，OR或NR2（ b）球形MgCl2。 所述组分具有大于1μm的平均直径，至少10m 2 / g的表面积，至少0.1g / cm 3的孔隙率和具有特定特征的X射线光谱。
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公开(公告)号：EP0543227B1
公开(公告)日：1996-04-10
申请号：EP92118955.1
申请日：1992-11-05
CPC分类号： C08F10/00 , C08F4/6343 , C08F4/68
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3.发明公开Components and catalysts for the polymerization of olefins 失效Katalysatorbestandteile und KatalysatorefürOlefinpolymerisation。
公开(公告)号：EP0646605A1
公开(公告)日：1995-04-05
申请号：EP94115455.1
申请日：1994-09-30
发明人： Morini, Giampiero , Albizzati, Enrico , Giannini, Umberto , Scordamaglia, Raimondo , Barino, Luisa
CPC分类号： B01J31/0204 , B01J27/138 , B01J31/0208 , B01J31/0237 , B01J31/0274 , B01J31/26 , B01J31/38 , C07C45/455 , C07C45/68 , C07C49/12 , C07C49/784 , C08F10/00 , C08F4/6465 , C08F4/6494 , C08F4/651
摘要： Disclosed is a catalyst for the polymerization of olefins, comprising the product of the reaction between an Al-alkyl compound and a solid catalyst component containing a magnesium halide in active form, a titanium compound and an electron-donor selected from the 1,3-diketones of formula:
wherein the radicals R are the same or different, the radicals R I are the same or different, and R and R I are C₁-C₂₀ alkyl, C₃-C₂₀ cycloalkyl, C₆-C₁₂ aryl, C₇-C₂₀ arylalkyl or alkylaryl radicals or hydrogen, with the proviso that at least one of the R radicals is not hydrogen and can be bonded with the other R radical to form a cyclic structure, and at least one of the R I radicals, which are not bonded to one another to form a cyclic structure, is a branched alkyl, cycloalkyl or aryl radical, or is bonded to one or both R radicals to form a cyclic structure.摘要翻译： 公开了一种用于烯烃聚合的催化剂，其包括在烷基化合物和含有活性形式的卤化镁的固体催化剂组分之间的反应的产物，钛化合物和选自1,3-丁二烯的电子给体， 式：
的二酮，其中基团R相同或不同，基团R 1相同或不同，R和R 1为C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 12 芳基，C 7 -C 20芳基烷基或烷基芳基或氢，条件是至少一个R基团不是氢并且可以与其它R基团键合以形成环状结构，并且至少一个R I >基团彼此不结合以形成环状结构，是支链烷基，环烷基或芳基，或者键合到一个或两个R基团以形成环状结构。 -
公开(公告)号：EP0589474A2
公开(公告)日：1994-03-30
申请号：EP93115444.7
申请日：1993-09-24
发明人： Morini, Giampiero , Barino, Luisa , Socrdamaglia, Raimondo , Barbassa, Elisabetta , Baruzzi, Giovanni
CPC分类号： C08F10/00 , C07C211/11 , C07C211/25 , C07C211/27 , C07C2601/14 , C07C2601/16 , C08F4/6543 , C08F4/651 , C08F4/6495
摘要： Disclosed are catalyst components for the polymerization of olefins comprising magnesium halide in active form, and, supported thereon, a titanium halide or titanium halogen alcoholate and an electron-donor compound selected from the diamines of formula
wherein the radicals R 1 to R 1 0 are the same or different and are hydrogen or C 1 -C 1 8 hydrocarbon radicals, with the proviso that at least one of the R 7 and R 8 radicals and at least one of the R 9 and R 10 radicals are not hydrogen. Also, disclosed are catalysts obtained from said catalyst components and an AI-alkyl compound, as well as catalysts obtained by reaction of an AI-alkyl compound and a diamine of formula (I) with a solid catalyst component comprising a titanium halide or a titanium halogen alcoholate, and an electron-donor compound having particular characteristics of extractability with AI-triethyl, supported on magnesium halide in active form.摘要翻译： 公开了用于烯烃聚合的催化剂组分，所述烯烃包含呈活性形式的卤化镁并且负载在其上的卤化钛或卤代醇钛和选自式II的二胺的电子给体化合物，其中基团R 1至R 10相同 或不同并且是氢或C1-C18烃基，条件是R7和R8基团中的至少一个和R9和R10基团中的至少一个不是氢。 还公开了由所述催化剂组分和烷基铝化合物获得的催化剂，以及通过式（I）的烷基铝化合物和二胺与包含卤化钛或钛的固体催化剂组分反应获得的催化剂 卤素醇化物和具有与三乙基铝提取性特定特征的电子给体化合物，负载在活性形式的卤化镁上。
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公开(公告)号：EP0506073A2
公开(公告)日：1992-09-30
申请号：EP92105294.0
申请日：1992-03-27
CPC分类号： C08F10/00 , Y10S526/904 , C08F4/027 , C08F4/6543
摘要： Catalyst components for the polymerization of olefins obtained by reacting a tetravalent titanium halide or halogen alcoholate and an electron-donor compound with a porous polymer support on which is supported a magnesium dihalide or a magnesium compound which does not contain Mg-C bonds and can be transformed into a dihalide, characterized in that the Mg content before and after the reaction with titanium compound ranges from 6 to 12% by weight.
摘要翻译： 通过使四价钛卤化物或卤素醇化物与电子给体化合物与多孔聚合物载体反应获得的烯烃聚合的催化剂组分，其上负载有二卤化镁或不含Mg-C键的镁化合物，并且可以是 转化成二卤化物，其特征在于与钛化合物反应前后的Mg含量为6〜12重量％。
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6.发明授权Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution 失效具有高熔体流动速率和分子量分布窄的结晶丙烯聚合物
公开(公告)号：EP0622380B2
公开(公告)日：2006-03-15
申请号：EP94106280.4
申请日：1994-04-22
CPC分类号： D01F6/30 , B29C33/02 , C08F10/06 , C08F110/06 , D01F6/06 , D04H1/4291 , C08F4/651 , C08F4/6543 , C08F4/6494 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/24 , C08F2500/06
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7.发明公开Diethers suitable for use in the preparation of Ziegler-Natta catalysts 失效Bei der Herstellung von Ziegler-Natta-Katalysatoren verwendbare Diether
公开(公告)号：EP0728724A1
公开(公告)日：1996-08-28
申请号：EP96102586.3
申请日：1996-02-21
IPC分类号： C07C43/168 , C07C43/162 , C07C41/16 , C08F4/649
CPC分类号： C07F7/0818 , C07C41/16 , C07C43/162 , C07C43/168 , C07C43/1747 , C07C2601/10 , C07C2602/08 , C07C2603/18 , C07C2603/24 , C07C2603/28 , C07D311/82 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C07C41/38
摘要： Diethers suitable for use in the preparation of Ziegler-Natta catalysts having the formula:
where A, B, C, and D are carbon atoms or heteroatoms, v, x, and y are 0 or 1; u and z are either 0, 1, or 2; the radicals R and R I , equal or different, are H; halogens; linear or branched alkyl radicals; cycloalkyl, aryl, alkylaryl, and aralkyl radicals; the R II radicals, equal or different, are linear or branched alkyl radicals; cycloalkyl, aryl, alkylaryl, and aralkyl radicals; at least two R radicals can be bonded to one another to form saturated or unsaturated condensed cyclic structures, optionally substituted with R III radical selected from halogens; linear or branched alkyl radicals; cycloalkyl, aryl, alkylaryl, and aralkyl radicals; said radicals from R to R III optionally containing at least one heteroatom.摘要翻译： 适用于制备具有下式的齐格勒 - 纳塔催化剂的二乙酸酯：其中A，B，C和D为碳原子或杂原子，v，x和y为0或1; u和z是0,1或2; 基团R和R 1相同或不同，为H; 卤素; 直链或支链烷基; 环烷基，芳基，烷基芳基和芳烷基; 相同或不同的R II基团是直链或支链烷基; 环烷基，芳基，烷基芳基和芳烷基; 至少两个R基团可以彼此键合形成饱和或不饱和的稠合环状结构，任选地被选自卤素的R III基团取代; 直链或支链烷基; 环烷基，芳基，烷基芳基和芳烷基; 所述从R至R III的基团任选地含有至少一个杂原子。
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8.发明公开Process for the preparation of stabilized polyolefins and products obtained therefrom 失效Verfahren zur Herstellung stableisierter Polyolefine und daraus hergestellte Produkte。
公开(公告)号：EP0546573A1
公开(公告)日：1993-06-16
申请号：EP92121170.2
申请日：1992-12-11
摘要： Polyolefins stabilized against oxidation phenomena are obtained by using a process comprising the polymerization of monomers by way of a catalyst prepared by reacting an aluminum alkyl compound, and optionally an electron donor compound, with a solid component comprising a Ti compound and an electron-donor compound supported on magnesium chloride, the polymerization being carried out in the presence of one or more phenolic stabilizers and using, as electron-donor compound in the solid catalyst component, a compound selected from particular classes of ethers.
摘要翻译： 通过使用包括通过使烷基铝化合物和任选的电子给体化合物与包含Ti化合物和电子给体化合物的固体组分反应制备的催化剂聚合单体的方法获得对氧化现象稳定的聚烯烃 支持氯化镁，聚合在一种或多种酚类稳定剂的存在下进行，并且使用作为固体催化剂组分中的电子给体化合物的选自特定类别的醚的化合物。
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公开(公告)号：EP0506073A3
公开(公告)日：1992-12-02
申请号：EP92105294.0
申请日：1992-03-27
CPC分类号： C08F10/00 , Y10S526/904 , C08F4/027 , C08F4/6543
摘要： Catalyst components for the polymerization of olefins obtained by reacting a tetravalent titanium halide or halogen alcoholate and an electron-donor compound with a porous polymer support on which is supported a magnesium dihalide or a magnesium compound which does not contain Mg-C bonds and can be transformed into a dihalide, characterized in that the Mg content before and after the reaction with titanium compound ranges from 6 to 12% by weight.
摘要翻译： 通过四价钛卤化物或卤代醇化物和电子给体化合物与多孔聚合物载体反应获得的用于烯烃聚合的催化剂组分，所述多孔聚合物载体负载不含Mg-C键的二卤化镁或镁化合物，并且可以是 转化为二卤化物，其特征在于与钛化合物反应之前和之后的Mg含量为6-12重量％。
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公开(公告)号：EP0891988A3
公开(公告)日：2000-05-17
申请号：EP98119781.7
申请日：1991-03-28
发明人： Albizzati, Enrico , Morini, Giampiero , Giannini, Umberto , Barino, Luisa , Scordamaglia, Raimondo , Barbé, Pier Camillo , Noristi, Luciano
CPC分类号： C08F10/00 , C08F4/6495 , C08F4/6496 , C08F4/6497 , C08F4/651 , C08F4/6494 , C08F4/6465
摘要： Catalyst components for the polymerization of olefins comprising a titanium halide or alkoxyhalide and an electron-donor compound selected from ethers having two or more ether groups and containing at least one heteroatom selected from the group consisting of N, S, P, Si, non-ether O and halogen atoms or at least one double bond, or both at least one heteroatom and at least one double bond, supported on a magnesium halide in active form. Catalysts obtained from said catalyst components and an Al-alkyl compound.
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