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    Vorrichtung zur Durchführung von elektrochemischen Messungen
    2.
    发明公开
    Vorrichtung zur Durchführung von elektrochemischen Messungen 失效
    Vorrichtung zurDurchführungvon elektrochemischen Messungen在Glas- oder Salzschmelzen

    公开(公告)号：EP0813056A2

    公开(公告)日：1997-12-17

    申请号：EP97106853.1

    申请日：1997-04-25

    申请人： Heraeus Electro-Nite International N.V.

    发明人： Plessers, Jacques Josef, Dr. ,  Straetemans, Marc

    IPC分类号： G01N27/411

    CPC分类号： G01N33/386 ,  G01N27/4115

    摘要： Die Erfindung betrifft eine Vorrichtung zur Durchführung von elektrochemischen Messungen in Glas- oder Salzschmelzen mit mindestens einer Meßelektrode und einer Referenzelektrodenanordnung. Um sehr genaue Messungen durchführen zu können, ist die zum Eintauchen in die Schmelze bestimmte Spitze der Meßelektrode aus einem Edelmetall gebildet und mit einem Ende eines Quarzglasrohres gasdicht gehaltert, wobei die Meßelektrode durch das Quarzglasrohr hindurchgeführt ist.

    摘要翻译： 用于玻璃或盐熔体的电化学测量装置具有用于浸入熔体中的具有贵金属端头的测量电极，其新颖性是尖端（11）熔接在石英玻璃管（8）中，通过该测量电极 测量电极通过。 优选地，测量电极和石英玻璃管（8）之间的熔接在管（8）的浸入端。

    METHOD OF AND DEVICE FOR MEASURING OXYGEN ACTIVITY IN SLAG AND CONSUMABLE TYPE CRUCIBLE USED FOR SAID DEVICE
    3.
    发明公开
    METHOD OF AND DEVICE FOR MEASURING OXYGEN ACTIVITY IN SLAG AND CONSUMABLE TYPE CRUCIBLE USED FOR SAID DEVICE 失效
    用于测量SLAG中的氧活性的方法和装置以及用于上述装置的消耗型可硬化

    公开(公告)号：EP0450090A4

    公开(公告)日：1992-06-24

    申请号：EP90914968

    申请日：1990-10-15

    申请人： YAMARI ELECTRONITE KABUSHIKIGAISHA

    发明人： IWASE, M. 216-GO, KYOTO DAIGAKU KUMANO SHOKUIN ,  FUJIWARA, RYUJI ,  MOCHIZUKI, RYO

    IPC分类号： G01N27/411 ,  G01N27/417 ,  G01N33/20

    CPC分类号： G01N27/4115 ,  G01N33/203

    摘要： This invention relates to a method and device permitting measurement of oxygen activity in the molten pig iron slag and molten steel slag with high precision. According to the conventional method of measurement depending on the oxygen-concentration cell composed of a one-end-closed tube type solid electrolyte fixed to the tip of the probe, having a contrasting platinum electrode wound around the outer surface thereof, and located directly in the molten slag layer, positioning of the cell in the flowing slag is difficult and insufficient contact of the contrasting electrode with the slag layer is caused on account of thermal contraction of the electroyte resulting from heat of the slag, whereby errors possibly occur in measurement. Unlike the direct measurement of oxygen activity in the slag, this invention provides a method in which a specific metal whose oxygen activity equilibrates with that of the slag when brought into contact with the slag is contained in the same vessel together with the slag and oxygen activity in the specific metal is measured for indirect measurement of oxygen activity in the slag, whereby the problem resulting from insufficient contact of the solid electrolyte with the contrasting electrode can be solved and measurement of oxygen activity in the slag with high precision is ensured.

    Dimensionally stable anode for molten salt electrowinning and method of electrolysis
    4.
    发明公开
    Dimensionally stable anode for molten salt electrowinning and method of electrolysis 失效
    尺寸稳定的阳极的熔盐电解和电解过程。

    公开(公告)号：EP0203884A1

    公开(公告)日：1986-12-03

    申请号：EP86810183.3

    申请日：1986-04-22

    申请人： MOLTECH Invent S.A.

    发明人： Durus, Jean-Jacques

    IPC分类号： C25C7/02 ,  C25C3/12 ,  C25D9/06 ,  G01N27/56

    CPC分类号： G01N27/4115 ,  C25C3/12 ,  C25C7/025 ,  C25D9/06

    摘要： The morphology of a coating of Ce oxyfluoride on a conductive substrate is improved by addition of yttrium, lanthanum, praseodymium and/or other rare earth metals. Whereas the pure Ce-oxycompound coating shows cracks which frequently extend throughout the entire thickness of the coating, thus exposing finite portions of the substrate to eventual corrosive attack from the environment, the improved coating including the above doping element(s) comprises a substantially impervious structure. Coatings of this nature may be employed with non-consumable anodes in molten aluminum electrowinning cells or as chemical sensors, corrosion protection and other applications.

    CONTAMINANT DETECTION DEVICE AND METHOD
    5.
    发明公开
    CONTAMINANT DETECTION DEVICE AND METHOD 审中-公开
    污染物检测装置和方法

    公开(公告)号：EP3227671A1

    公开(公告)日：2017-10-11

    申请号：EP15865172.9

    申请日：2015-12-03

    申请人： The Uwm Research Foundation, Inc.

    发明人： GUNASEKARAN, Sundaram ,  CHANG, Woo-Jin ,  YANG, Jiang ,  SEENIVASAN, Rajesh

    IPC分类号： G01N27/06 ,  G01N27/07 ,  G01N33/20 ,  B41M1/12

    CPC分类号： G01N27/4115 ,  G01N27/301 ,  G01N27/302 ,  G01N27/308 ,  G01N27/333 ,  G01N27/4148 ,  G01N27/4167 ,  G01N27/42 ,  G01N33/1813

    摘要： A device for measuring pH levels and contaminant concentration includes an electrode assembly that is electrically coupled to a control unit. The electrode assembly includes a FLUID first contact electrically coupled to a reference electrode, a second contact electrically coupled to a working electrode, and a third contact electrically coupled to a counter electrode. The working electrode may be modified to include a cysteine functionalized graphene oxide with polypyrrole nanocomposite. In operation, the control unit may apply a complex signal to the working electrode via the second contact in order to adhere and subsequently strip contaminant ions from the fluid sample to the working electrode. During this process, a current may be measured across the reference electrode and the counter electrode to measure contaminant ion concentration. The pH of the fluid sample may also be determined by a current measured across the reference electrode and the counter electrode. In some examples, the pH may be used to calibrate the measured levels of the contaminant ions.

    摘要翻译： 用于测量pH水平和污染物浓度的装置包括电耦合到控制单元的电极组件。 电极组件包括电耦合到参考电极的第一触点，电耦合到工作电极的第二触点以及电耦合到反电极的第三触点。 工作电极可以被修饰以包括半胱氨酸官能化石墨烯氧化物和聚吡咯纳米复合材料。 在操作中，控制单元可以通过第二触点向工作电极施加复合信号，以便将污染物离子从流体样品附着并随后剥离到工作电极。 在此过程中，可以在参比电极和反电极上测量电流，以测量污染物离子浓度。 流体样本的pH值也可以通过在参考电极和反电极上测量的电流来确定。 在一些示例中，pH可以用于校准污染物离子的测量水平。

    Tauchsensor für Metallschmelzen
    6.
    发明公开
    Tauchsensor für Metallschmelzen 失效
    TauchsensorfürMetallschmelzen。

    公开(公告)号：EP0543081A1

    公开(公告)日：1993-05-26

    申请号：EP92110944.3

    申请日：1992-06-29

    申请人： Heraeus Electro-Nite International N.V.

    发明人： Verstreken, Paul Clement ,  Neyens, Guido Jacobus

    IPC分类号： G01N27/411

    CPC分类号： G01N33/206 ,  G01N27/4115

    摘要： Die Erfindung betrifft einen Tauchsensor für Metallschmelzen, der einen elektrisch leitenden Trägerstift (1) aufweist, dessen eines Ende in einem feuerfesten Halterungs-Werkstoff (2) gehaltert ist und dessen anderes, freies Ende einen ersten Überzug aus einem Referenz-Material (3) und darauf einen zweiten Überzug aus einem Festelektrolyt-Material (6) aufweist, wobei der Trägerstift (1) im Bereich seines gehalterten Endes einen dritten Überzug aus einem feuerfesten Werkstoff (4) aufweist, der einerseits in den Halterungs-Werkstoff (2) hineinreicht und der sich andererseits bis zum Festelektrolyt-Material erstreckt. Um eine kurze Ansprechzeit und einen stabilen EMK-Meßwert zu erreichen, überdeckt das Festelektrolyt-Material (6) mindestens den Endbereich des ihm benachbarten feuerfesten Werkstoffes (4). Die Erfindung betrifft ebenfalls ein Verfahren zur Herstellung eines Zwischenproduktes eines Tauchsensors; wonach die verschiedenen Schichtwerkstoffe des Tauchsensors in vorgegebener Reihenfolge aufgebraucht werden.

    摘要翻译： 本发明涉及一种用于金属熔体的浸没传感器，其包括导电支撑销（1），其一端安装在耐火材料安装材料（2）中，并且其另一个自由端具有由参考的第一涂层 材料（3），其上由固体电解质材料（6）制成的第二涂层，所述支撑销（1）在其安装端的区域中具有耐火材料（4）的第三涂层，所述第三涂层一方面 ，延伸到固定电解质材料（2）中，另一方面延伸到固体电解质材料。 为了达到较短的响应时间和稳定的E.M.F. 固体电解质材料（6）至少覆盖与其相邻的耐火材料（4）的端部区域。 本发明同样涉及一种用于制备浸没传感器的中间产品的方法，根据该方法，以预设的顺序施加浸没传感器的各种涂层材料。

    METHOD OF AND DEVICE FOR MEASURING OXYGEN ACTIVITY IN SLAG AND CONSUMABLE TYPE CRUCIBLE USED FOR SAID DEVICE
    10.
    发明授权
    METHOD OF AND DEVICE FOR MEASURING OXYGEN ACTIVITY IN SLAG AND CONSUMABLE TYPE CRUCIBLE USED FOR SAID DEVICE 失效
    方法和设备以便在其测量氧活度炉渣和坩埚，其使用

    公开(公告)号：EP0450090B1

    公开(公告)日：1996-01-17

    申请号：EP90914968.4

    申请日：1990-10-15

    申请人： HERAEUS ELECTRONITE CO., LTD.

    发明人： IWASE, M. 216-go, Kyoto Daigaku Kumano Shokuin ,  FUJIWARA, Ryuji ,  MOCHIZUKI, Ryo

    IPC分类号： G01N27/406

    CPC分类号： G01N27/4115 ,  G01N33/203

    摘要： This invention relates to a method and device permitting measurement of oxygen activity in the molten pig iron slag and molten steel slag with high precision. According to the conventional method of measurement depending on the oxygen-concentration cell composed of a one-end-closed tube type solid electrolyte fixed to the tip of the probe, having a contrasting platinum electrode wound around the outer surface thereof, and located directly in the molten slag layer, positioning of the cell in the flowing slag is difficult and insufficient contact of the contrasting electrode with the slag layer is caused on account of thermal contraction of the electroyte resulting from heat of the slag, whereby errors possibly occur in measurement. Unlike the direct measurement of oxygen activity in the slag, this invention provides a method in which a specific metal whose oxygen activity equilibrates with that of the slag when brought into contact with the slag is contained in the same vessel together with the slag and oxygen activity in the specific metal is measured for indirect measurement of oxygen activity in the slag, whereby the problem resulting from insufficient contact of the solid electrolyte with the contrasting electrode can be solved and measurement of oxygen activity in the slag with high precision is ensured.