摘要:
A blown film comprising a polyolefin composition (I) comprising: A) from 40 to 75 wt.% of a polyethylene having a density of 0.920-0.940 g/cm3 and a fraction soluble in xylene (XSA) of less than 10% wt.%; and B) from 25 to 60 wt.% of a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC2=CHRI, where RI is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, comprising from 50 to 70 wt.% of ethylene and having a fraction soluble in xylene (XSB) of at least 50 wt.%.
摘要:
Films especially suitable for the packaging of fresh foodstuff, like salad and vegetables, due to their valuable balance of high permeability to oxygen and optimal permeability to water vapour, comprising at least one layer A) and at least one layer B), wherein the layer A) comprises a copolymer of propylene with hexene-1 containing from 3 to 9% by weight of recurring units derived from hexene-1, said copolymer having a melting temperature from 125° C. to 143° C., and the layer B) comprises a polyolefin composition containing (all percentages being by weight): a) 10-40% of one or more propylene homopolymers or copolymers containing over 85% of propylene and having a fraction insoluble in xylene at room temperature greater than 80%; and b) 60-90 of one or more copolymers of ethylene with alpha-olefin(s), containing ethylene in a quantity from 20 to 80%, and having solubility in xylene at room temperature greater than 70%.
摘要:
wherein the amounts of A) and B) are referred to the total weight of A)+B) and the DSC second heating scan is carried out with a heating rate of about 10° C. per minute.
摘要:
The present disclosure provides a low density polyethylene (LDPE) having (A) a density from 0.910 to 0.924 g/cm3, determined according to ISO 1183 at 23° C.; (B) an elongational hardening of at least 4.2, at 150° C. at an elongational rate of 1 s−1; (C) a ratio Mw/Mn of at least 18, where (i) Mw is the weight average molar mass, measured by a MALLS detector coupled to a GPC, and (ii) Mn is the number average molar mass, measured by GPC (Gel Permeation Chromatography); and (D) a Mw of at least 230,000 g/mol. The present disclosure also provides an article of manufacture made from or containing (A) a substrate and (B) a coating layer made from or containing the disclosed LDPE. The present disclosure further provides a polymerization process occurring (A) in the presence of oxygen as the only radical initiating agent and (B) in the absence of solvents.
摘要翻译:本公开提供了一种低密度聚乙烯(LDPE),其具有(A)根据ISO 1183在23℃下测定的0.910至0.924g / cm 3的密度; (B)在150℃以1s -1的拉伸速率拉伸硬化至少4.2; (C)至少为18的比例M w / M n,其中(i)M w是通过与GPC偶联的MALLS检测器测量的重均摩尔质量,和(ii)M n是通过GPC测量的数均摩尔质量 (凝胶渗透色谱); 和(D)至少230,000g / mol的Mw。 本发明还提供由(A)基材和(B)由所公开的LDPE制成或包含所述LDPE的涂层制成或含有(A)基材和(B)涂层的制品。 本发明进一步提供了在作为唯一自由基引发剂的氧存在下和(B)在不存在溶剂的情况下发生的聚合过程(A)。
摘要:
A polyethylene composition having density from 0.943 to 1.1 g/cm3, comprising: A) carbon black, or a UV stabilizer, or a mixture of carbon black and a UV stabilizer; B) a polyethylene comprising copolymers of ethylene with 1-alkenes, or mixtures of ethylene homopolymers and said copolymers of ethylene with 1-alkenes, which polyethylene has molar mass distribution width (MWD) Mw/Mn of from 7 to 15, density of from 0.942 to 0.954 g/cm3, a weight average molar mass Mw of from 20,000 g/mol to 500,000 g/mol, a MIE of from 1.0 to 3.0 g/10 min, a MIF of from 100 to 200 g/10 min, and a ratio MIF/MIE of from 40 to 50.
摘要:
An ethylene polymer composition having an eta (0.01) equal to or higher than 35,000 Pa.s, comprising, all per cent amounts being by weight: A) 25-75% of an ethylene polymer selected from ethylene homopolymers, copolymers of ethylene with 10% or less of one or more olefin comonomers, and mixtures of said homopolymers and copolymers; B) 25-75% of a copolymer of ethylene and propylene containing from 45% to 70% of ethylene; wherein eta (0.01) is the complex shear viscosity at an angular frequency of 0.01 rad/s, measured with dynamic oscillatory shear in a plate-plate rotational rheometer at a temperature of 200º C, and the amounts of A) and B) are referred to the total weight of A) + B).