摘要:
The ions other than lithium ions and having a greater ion radius are interposed, before the lithium ions are doped, as an interlayer securing member in a vanadium oxide having a layered crystal into which the lithium ions can be doped. Since the interlayer securing member is interposed, the doping or dedoping of the lithium ions into or from the vanadium oxide afterward can be smoothly performed. Sodium ions or the like can be employed as the interlayer securing member.
摘要:
A negative active material for a rechargeable lithium battery of the present invention includes a lithium-vanadium oxide core material capable of performing reversible electrochemical oxidation and reduction, and an inorganic oxide coating layer disposed on the surface of the core material. The negative active material can improve stability at the interface between a negative electrode and an electrolyte, charge and discharge efficiency, and cycle-life, and can be applied along with all kinds of aqueous and non-aqueous binders.
摘要:
The invention concerns a method for making transition metal oxide containing lithium or extra lithium comprising the three following steps performed successively or simultaneously: Preparing a lithium alkoxide solution by dissolving metal lithium in corresponding alcohol, said alcohol being selected among alcohols derived from linear or branched alkanes containing at least 3 carbon atoms, the alcohols derived from unsaturated aliphatic hydrocarbons, and their mixtures; adding a transition metal oxide powder to said lithium alkoxide solution to obtain a dispersion; controlled reduction of said transition metal oxide by said lithium alkoxide until a transition metal oxide containing lithium or extra lithium is obtained having a specific stoichiometry Li:Metal; Said method further consists in the following steps: evaporating the residual alcohol; washing the resulting powder; drying the powder.
摘要:
The invention relates to the use of layered double hydroxide salts as charge control agents in electrophotographic toners and developers, in coating powders, electret materials and in electrostatic separation processes, characterized in that the double hydroxide salt contains monovalent and/or bivalent and even trivalent metal cations, in addition to one or several organic anions of formula X-R-Y (I), wherein X = hydroxy, carboxy, sulphato or sulpho; Y = carboxy, sulphato or sulpho, and R = a bivalent aliphatic, cycloaliphatic, heterocycloaliphatic, olefinic, cycloolefinic, heterocycloolefinic, aromatic, heteroaromatic, araliphatic or heteroaraliphatic radical having at least 8 C atoms which can be substituted by one or several substituents from the group of hydroxy, amino, halogen, C1-C22-alkyl, C1-C22-alkoxy, carboxy, sulpho, nitro or cyano.
摘要:
The invention relates to a pigment of the formula (I)
Bi x V (2-x) O (5-x) (I)
wherein x is a number of 0,1 to 2, characterized by a particle size d 50,BET of 10 to 100 nm. The bismuth vanadate pigments can be prepared by a spray flame pyrolysis process.
摘要:
The present invention relates to compounds on apatite basis, having the general formula M5 (A04)3X wherein X is situated in the hexagonal channels of the apatite structure and includes Cu-atoms, processes for the preparation thereof as well as applications of these compounds. The compounds presented herein are particularly useful as pigments.
摘要:
High purity refractory metals, valve metals, refractory metals oxides, valve metal oxides, or alloys thereof suitable for a variety of electrical, optical and mill product/fabricated parts usages are produced from their respective oxides by metalothermic reduction of a solid or liquid form of such oxide (18) using a reducing agent that establishes (after ignition) a highly exothermic reaction, the reaction preferably taking place in a continuously or step-wise moving oxide such as gravity fall (24) with metal retrievable at the bottom (30) and an oxide of the reducing agent being removable as a gas or in other convenient form and unreacted reducing agent derivatives being removable by leaching or like process.
摘要:
A process for producing a vanadyl sulphate solution (VOSO4) comprises forming a suspension of vanadium trioxide (V2O3) in a sulphuric acid solution and contacting the V2O3 suspension with a strong oxidising agent under controlled conditions to produce the VOSO4 solution. A preferred oxidising agent is hydrogen peroxide, which is added very slowly to the V2O3 suspension due to the violent nature of the reaction.
摘要:
A non-oxide, transition metal-based ceramic material has the general formula AyM2Zx, wherein A is a group IA element, M is a transition metal and Z is selected from the group consisting of N, C, B, Si, and combinations thereof, and wherein x ≤ 2 and y ≤ 6-x. In these materials, the group IA element occupies interstitial sites in the metallic lattice, and may be readily inserted into or released therefrom. The materials may be used as catalysts and as electrodes. Also disclosed herein are methods for the fabrication of the mates.