公开(公告)号：EP1473343A1

公开(公告)日：2004-11-03

申请号：EP04008204.2

申请日：2004-04-05

申请人： E. I. du Pont de Nemours and Company

发明人： Wissing, Klaus ,  Flosbach, Carmen ,  Frese, Peter ,  Reis, Oliver

IPC分类号： C09D175/16

CPC分类号： C08G18/672 ,  C08G18/7831 ,  C08G18/8032 ,  C08G18/809 ,  C09D175/16

摘要： The invention relates to a process for multi-layer coating of substrates which comprises the steps of applying at least two coating layers and curing of the applied coatings with high energy radiation and moisture; wherein at least one of the coating layers is formed from a coating composition comprising a binder system of resin solids wherein the resin has free-radically polymerizable olefinic double bonds and hydrolysable alkoxysilane groups, wherein the resin solids content of the coating composition has an equivalent weight of C=C double bonds of 200 - 2000 and has a silicon content of 1 - 10 wt-%, wherein the silicon is bound in alkoxysilane groups and wherein the coating composition contains 10-60 wt.%, relative to the complete coating composition, of polar water-miscible organic solvents with a water solubility at 20°C of at least 220 g/l and wherein the step of curing of the at least one coating layer comprises irradiation with high energy radiation thereby polymerizing the C=C double bonds via free radical polymerization and exposure to moisture thereby forming siloxane bridges from the alkoxysilane groups.

摘要翻译： 本发明涉及一种用于多层涂覆基材的方法，其包括以下步骤：施加至少两个涂层并用高能量辐射和湿气固化涂覆的涂层; 其中所述涂层中的至少一个由包含树脂固体的粘合剂体系的涂料组合物形成，其中所述树脂具有可自由基聚合的烯属双键和可水解的烷氧基硅烷基团，其中所述涂料组合物的树脂固体含量具有当量 的C = C双键为200-2000，硅含量为1-10重量％，其中硅以烷氧基硅烷基结合，其中涂料组合物相对于完整的涂料组合物为10-60重量％ 的在20℃下的水溶性为至少220g / l的极性水混溶性有机溶剂，并且其中所述至少一个涂层的固化步骤包括用高能量辐射照射，由此聚合C = C双键 通过自由基聚合和暴露于湿气，从而由烷氧基硅烷基团形成硅氧烷桥。

公开(公告)号：EP1201690B1

公开(公告)日：2004-07-28

申请号：EP01122704.8

申请日：2001-09-21

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Delmotte, Ann ,  Huybrechts, Josef ,  Kerber, Hermann ,  Ley, Olaf ,  Paulussen, Harold ,  Vaes, Ann

IPC分类号： C08F220/28 ,  C09J133/14 ,  C09D133/14

CPC分类号： C09D175/04 ,  C08F8/14 ,  C08F2810/20 ,  C08G18/6237 ,  Y10T428/31511 ,  Y10T428/31522 ,  Y10T428/31786 ,  Y10T428/31928 ,  Y10T428/31935 ,  C08F220/28

公开(公告)号：EP1431367A1

公开(公告)日：2004-06-23

申请号：EP03027926.9

申请日：2003-12-04

申请人： E. I. du Pont de Nemours and Company

发明人： Kleineberg, Olaf ,  Temeltas, Engin ,  Pfeiffer, Heinz-Peter

IPC分类号： C09J175/06 ,  C08G18/12 ,  C08G18/66

CPC分类号： C09J175/06 ,  C08G18/0895 ,  C08G18/12 ,  C08G18/4202 ,  C08G18/664 ,  C08G2170/20 ,  C08G2250/00 ,  C08K3/04 ,  C08L67/00 ,  C08L67/02 ,  C08L75/06 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/20 ,  Y10T428/31591 ,  C08G18/307 ,  C08G18/2855 ,  C08G18/48

摘要： A thermally curable hot-melt adhesive composition, comprising

a polyurethane prepolymer having isocyanate groups, wherein at least 50 % of the reactive isocyanate groups of the prepolymer are blocked, said prepolymer being the reaction product of

(1) 20 to 40 wt% of at least one straight-chain amorphous polyester having a number average molecular mass Mn of 3000 to 6000 with
(2) 40 to 60 wt% of at least one polyurethane elastomer,
(3) 10 to 20 wt% of at least one polyester elastomer,
(4) at least one diisocyanate,
(5) at least one polyol as a chain extender, and
(6) at least one blocking agent; and

at least one isocyanate reactive component selected from the group consisting of polyalcohols, polyamines and hydroxy-functionalized epoxide resins;
   wherein the percentages are based on the total weight of polyester, polyurethane elastomer and polyester elastomer.

摘要翻译： 一种可热固化的热熔粘合剂组合物，其包含具有异氰酸酯基团的聚氨酯预聚物，其中至少50％的预聚物的活性异氰酸酯基团被封闭，所述预聚物是（1）20至40重量％ 至少一种数均分子量Mn为3000至6000的直链无定形聚酯，（2）40至60重量％的至少一种聚氨酯弹性体，（3）10至20重量％的至少一种聚酯弹性体（ 4）至少一种二异氰酸酯，（5）至少一种作为扩链剂的多元醇，和（6）至少一种封端剂; 和至少一种选自多元醇，多胺和羟基官能化环氧树脂的异氰酸酯反应性组分; 其中百分比是基于聚酯，聚氨酯弹性体和聚酯弹性体的总重量。

公开(公告)号：EP2203532B1

公开(公告)日：2013-06-12

申请号：EP08840569.1

申请日：2008-10-01

申请人： E. I. du Pont de Nemours and Company

发明人： FLOSBACH, Carmen ,  HEARLEY, Andrew ,  BECKER, Wiebke ,  STROPP, Jurgen

IPC分类号： C09D175/04 ,  C08G18/28

CPC分类号： C08G18/792 ,  C08G18/2825 ,  C08G18/3206 ,  C08G18/6254 ,  C09D175/04 ,  C08L2666/20

公开(公告)号：EP2580287A2

公开(公告)日：2013-04-17

申请号：EP11792983.6

申请日：2011-06-07

申请人： E.I. Du Pont De Nemours And Company

发明人： GAM, Allisa

IPC分类号： C08L75/06

CPC分类号： C09D5/4465 ,  C08G18/246 ,  C08G18/4291 ,  C08G18/581 ,  C08G18/6407 ,  C08G18/7664 ,  C08G18/8029 ,  C08L75/06 ,  C09D5/4419 ,  C09D7/65 ,  C09D175/06

摘要： The present disclosure relates to an improved electrocoating coating composition wherein the improvement is the addition of a non-water reducible anticrater agent. The non-water reducible anticrater agent is a polyesterurethane that is the reaction product of an aliphatic carboxylic acid anhydride, a monofunctional epoxy compound, a monofunctional alcohol and a diisocyanate and/or a polyisocyanate. The improved electrocoating composition provides cured coatings that have fewer craters and have a smooth surface when compared to coatings utilizing other anticrater additives.

公开(公告)号：EP2124105B1

公开(公告)日：2012-12-12

申请号：EP09158991.1

申请日：2009-04-28

申请人： E. I. du Pont de Nemours and Company

发明人： McMillen, Robert, A. ,  Dudek, Dietmar ,  Vestergaard, Ib

IPC分类号： G03F7/34 ,  G03F7/36

CPC分类号： G03F7/36

公开(公告)号：EP2510322A1

公开(公告)日：2012-10-17

申请号：EP10793082.8

申请日：2010-11-29

申请人： E.I. Du Pont De Nemours And Company

发明人： KETTLER, Wilhelm

IPC分类号： G01J3/28

CPC分类号： G01J3/28 ,  G01J3/504

摘要： The invention relates to a method for generating calibrated colour data of a target using colour measurement instruments distributed in the network comprising the steps A) generating at least one standard instrument profile for the colour measurement instruments distributed in the network to correct photometric and wavelength scale differences, and B) generating at least one geometry instrument profile for the colour measurement instruments distributed in the network to correct geometry scale differences. The method can be used in applications where colour measurement instrument networks are used, particularly in robotic systems where colour measurement instruments are integrated.

公开(公告)号：EP2354201A3

公开(公告)日：2012-09-26

申请号：EP11003513.6

申请日：2009-07-23

申请人： E. I. du Pont de Nemours and Company

发明人： Lin, Jun

IPC分类号： C09J183/04 ,  C09D183/04

CPC分类号： C09D7/00 ,  C07F7/0859 ,  C07F7/18 ,  C08G77/045 ,  C08G77/26 ,  C09D4/00 ,  C09D183/04 ,  C09J183/04

摘要： Disclosed herein is the use of a surface active adhesion promoting agent in a clearcoat composition. The adhesion promoting agent is a blocked isocyanate functional siloxane containing material. The adhesion promoting agent helps to provide adhesion to a variety of materials that may be subsequently applied to the clearcoat composition.

公开(公告)号：EP2493630A1

公开(公告)日：2012-09-05

申请号：EP10773221.6

申请日：2010-10-27

申请人： E. I. du Pont de Nemours and Company

发明人： DOESSEL, Karl-Friedrich ,  RICHTER, Gunter

IPC分类号： B05D7/00 ,  B05D7/14

CPC分类号： B05D7/14 ,  B05D1/02 ,  B05D5/06 ,  B05D7/16 ,  B05D7/572

摘要： A process for the production of a dark-color multi-layer coating, comprising the successive steps: (1) applying an NIR-opaque coating layer A' from a solventborne coating composition A to a substrate, (2) applying a coating layer B' from a solventborne coating composition B onto the substrate provided with coating layer A', (3) subjecting the coated substrate obtained in step (2) to a drying step, (4) applying a clear coat layer, and (5) curing the coating layers simultaneously; wherein both coating compositions A and B comprise binders and crosslinkers comprising melamine-formaldehyde resin crosslinker, wherein both coating compositions A and B comprise certain proportions of cellulose ester binder and NAD binder and/or sheet silicate and/or fumed silica and/or urea SCA and/or polyolefine wax, wherein the pigment content of coating composition A consists 90 to 100 wt.% of aluminum flake pigment and 0 to 10 wt.% of further pigment, wherein the pigment content of coating composition B consists 50 to 100 wt.% of black pigment with low NIR absorption and 0 to 50 wt.% of further pigment.

摘要翻译： 一种制备深色多层涂层的方法，其包括以下连续步骤：（1）将来自溶剂型涂料组合物A的不透光的涂层A'施加到基材上，（2）将涂层B （3）将步骤（2）中获得的经涂布的基材进行干燥步骤，（4）施加透明涂层，和（5）固化所述涂布层A' 同时涂层; 其中涂料组合物A和B都包含含有三聚氰胺 - 甲醛树脂交联剂的粘合剂和交联剂，其中涂料组合物A和B都包含一定比例的纤维素酯粘合剂和NAD粘合剂和/或片状硅酸盐和/或煅制二氧化硅和/或脲SCA 和/或聚烯烃蜡，其中涂料组合物A的颜料含量包含90至100重量％的铝片状颜料和0至10重量％的其他颜料，其中涂料组合物B的颜料含量为50至100重量％。 具有低NIR吸收率的黑色颜料和0至50重量％的其他颜料。

公开(公告)号：EP2493629A1

公开(公告)日：2012-09-05

申请号：EP10773220.8

申请日：2010-10-27

申请人： E. I. du Pont de Nemours and Company

发明人： DOESSEL, Karl-Friedrich ,  RICHTER, Gunter

IPC分类号： B05D7/00 ,  B05D7/14

CPC分类号： B05D7/572 ,  B05D7/14

摘要： A process for the production of a dark-color multi-layer coating, comprising the successive steps: (1) applying an NIR-opaque coating layer A' from a solventborne coating composition A to a substrate, (2) applying a coating layer B' from a solventborne coating composition B onto the substrate provided with coating layer A', (3) subjecting the coated substrate obtained in step (2) to a drying step, (4) applying a clear coat layer, and (5) curing the coating layers simultaneously; wherein both coating compositions A and B comprise binders and crosslinkers comprising melamine-formaldehyde resin crosslinker, wherein both coating compositions A and B comprise certain proportions of cellulose ester binder and NAD binder and/or sheet silicate and/or fumed silica and/or urea SCA and/or polyolefine wax, wherein the pigment content of coating composition A comprises

摘要翻译： 一种制备深色多层涂层的方法，其包括以下连续步骤：（1）将来自溶剂型涂料组合物A的不透光的涂层A'施加到基材上，（2）将涂层B （3）将步骤（2）中获得的经涂布的基材进行干燥步骤，（4）施加透明涂层，和（5）固化所述涂布层A' 同时涂层; 其中涂料组合物A和B都包含含有三聚氰胺 - 甲醛树脂交联剂的粘合剂和交联剂，其中涂料组合物A和B都包含一定比例的纤维素酯粘合剂和NAD粘合剂和/或片状硅酸盐和/或煅制二氧化硅和/或脲SCA 和/或聚烯烃蜡，其中涂料组合物A的颜料含量包含<90重量％的铝片状颜料并且以这样的方式组成，使得不透光不透明涂层A'呈现低NIR吸收，其中涂料的颜料含量 组合物B由50至100重量％的具有低NIR吸收的黑色颜料和0至50重量％的其他颜料组成。