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    PROCESS FOR PRODUCTION OF METHYLENE-BRIDGED POLYPHENYL POLYAMINES
    131.
    发明公开
    PROCESS FOR PRODUCTION OF METHYLENE-BRIDGED POLYPHENYL POLYAMINES 有权
    用于生产亚甲基多苯基多胺

    公开(公告)号：EP2379486A1

    公开(公告)日：2011-10-26

    申请号：EP09764227.6

    申请日：2009-11-26

    申请人： Huntsman International LLC

    发明人： MITCHELL, Christopher, John ,  CORMA CANOS, Avelino ,  CARR, Robert, Henry ,  BOTELLA ASUNCION, Pablo

    IPC分类号： C07C209/60 ,  C07C209/78

    CPC分类号： C07C209/60 ,  C07C209/78 ,  C07C211/50

    摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps of a) condensing aniline and formaldehyde, providing a condensate, the molar ratio of aniline to formaldehyde being chosen in the range of 2 to 3.5; b) reacting, in a first catalytic reaction step, at a reaction temperature within the range of about 30°C to about 100°C, said condensate over a solid catalyst being chosen from the group consisting of clays, silicates, silica-aluminas and ion exchange resins, whereby an intermediate mixture is provided, the intermediate mixture comprising amino benzyl amines; c) converting, in a subsequent catalytic reaction step, at a temperature within the range of about 70°C to about 250°C, the reaction temperature in said subsequent catalytic reaction step is higher than the reaction temperature in said first catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst being chosen from the group consisting of zeolites, delaminated zeolites and ordered mesoporous materials, thereby providing said methylene-bridged polyphenyl polyamines.

    PROCESS FOR MANUFACTURING ISOCYANATES
    132.
    发明公开
    PROCESS FOR MANUFACTURING ISOCYANATES 有权
    制造异氰酸酯的方法

    公开(公告)号：EP2370400A1

    公开(公告)日：2011-10-05

    申请号：EP09751888.0

    申请日：2009-11-05

    申请人： Huntsman International LLC

    发明人： CARR, Robert Henry ,  KOOLE, Johannes Lodewijk ,  BRUINSMA, Udo Brian Dave Mike Rodger

    IPC分类号： C07C263/10 ,  C07C265/14

    摘要： The present invention relates to a process for manufacturing isocyanates from an amine compound. The process comprises the steps of a) Providing chlorine; b) Providing carbon monoxide; c) Reacting said chlorine and said carbon monoxide for providing phosgene, the carbon monoxide being provided in an adjustable molar excess; d) Providing an amine compound and phosgenating said amine compound using said phosgene thereby providing said isocyanate; the process further comprises adjusting said adjustable molar excess, i.e. the molar excess of carbon monoxide, for adjusting the color of the isocyanate.

    摘要翻译： 本发明涉及由胺化合物制造异氰酸酯的方法。 该方法包括以下步骤：a）提供氯; b）提供一氧化碳; c）使所述氯和所述一氧化碳反应以提供光气，所述一氧化碳以可调的摩尔过量提供; d）提供胺化合物并使用所述光气使所述胺化合物光气化，从而提供所述异氰酸酯; 该方法还包括调节所述可调节的摩尔过量，即一氧化碳的摩尔过量，以调节异氰酸酯的颜色。

    NATURAL OIL BASED AUTOCATALYTIC POLYOLS
    134.
    发明公开
    NATURAL OIL BASED AUTOCATALYTIC POLYOLS 审中-公开
    自动催化多元醇对石油基地

    公开(公告)号：EP2303964A1

    公开(公告)日：2011-04-06

    申请号：EP09798377.9

    申请日：2009-05-21

    申请人： Huntsman Petrochemical LLC

    发明人： ZHAO, Haibo ,  HERRINGTON, Ron ,  RODRIGUEZ, Frank

    IPC分类号： C08L75/04

    CPC分类号： C08G18/36 ,  C08G18/3821

    摘要： The present invention relates to a vegetable oil based autocatalytic polyol derived from the reaction product of an epoxidized vegetable oil and an alkanolamine. The autocatalytic polyol according to the present invention may be used as a replacement for all or a portion of petroleum derived polyols generally used in the production of polyurethane materials. The polyurethane materials produced may be used in a variety of applications, such as, foam, elastomer and coating applications.