摘要:
A rubber composition is disclosed wherein the rubber composition contains at least an effective amount of at least one substituted or unsubstituted diaryl amine- containing compound having at least one substituted or unsubstituted, saturated or partially saturated C5-C30 ring structure optionally containing one or more heteroatoms fused to at least one of the aryl rings.
摘要:
Disclosed is a method for the reduction of residual peroxides in vegetable oils, preferably epoxidized vegetable oils using a phosphorous compound preferably alkyl / aryl substituted phosphite compounds or hypophosphorous acid and its derivatives.
摘要:
A process for the preparation of a poly(α-olefin) copolymer is disclosed wherein the process comprises polymerizing at least one α-olefin, preferably 1-decene, and at least one bulky olefin, preferably norbornene, in the presence of hydrogen and a catalytically effective amount of catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst, the metallocene procatalyst being at least one compound of general formula: (CP1R1m)R3(Cp2R2p)MXq wherein Cp1 of ligand (Cp1R1m) and Cp2 of ligand (Cp2R2p) are the same or different cyclopentadienyl rings, R?1 and R2¿ each is, independently, hydrogen or a hydrocarbyl, halocarbyl, heterocarbyl, hydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, m is 0 to 5, p is 0 to 5 and two R1 and/or R2 substituents on adjacent carbon atoms of the cyclopentadienyl ring associated therewith can be joined together to form a ring containing from 4 to about 20 carbon atoms, R3 is a bridging group bridging Cp1 with Cp2, M is a transition metal having a valence of from 3 to 6, each X is a non-cyclopentadienyl ligand and is, independently, halogen or a hydrocarbyl, oxyhydrocarbyl, halocarbyl, hydrocarbyl-substituted organometalloid, oxyhydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, and q is equal to the valence of M minus 2, the cocatalyst being an aluminoxane and it being provided that ligand (Cp1R1m) is different that ligand (Cp2R2p) and bridging group R3 contains at least two bulky groups.
摘要:
A metal carbonate/carboxylate microemulsion imparting static and dynamic thermal stability to a halogen-containing polymer is provided which comprises (a) a metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof and an aliphatic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in an oil; b) one or more non-phenolic compounds having about two or about three hydroxyl groups; and, c) one or more polyols, alcohol ethoxylates and/or alcohol propoxylates having from about 6 to about 24 carbon atoms in the alcohol and/or 0 to 3 ethylene oxide units and/or 0 to 3 propylene oxide units.
摘要:
Disclosed herein is a process for the preparation of alkylated diarylamines comprising adding said diarylamine an olefin mixture containing highly reactive fractions, as well as fractions exhibiting a relatively lower chemical reactivity, in the presence of an acidic clay catalyst at a temperature low enough to prevent substantial deactivation of the catalyst until the addition is complete and then increasing the temperature to increase the alkylation rate of the less reactive fractions.
摘要:
Disclosed herein is a method for inhibiting and retarding the premature polymerization and the polymer growth of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor that is a sulfonated nitrophenol of the formula: (I) wherein: R
摘要:
In one aspect, the invention relates to storage-stable and flowable polyurethane compositions comprising (a) one or more isocyanate-terminated polyurethane prepolymers derived from one or more hydrocarbon ring-containing diisocyanates and/or triisocyanates and one or more polyols; (b) one or more metal salt complexes of methyl enedianiline; and (c) one or more organic acid halide compounds having one or more acid halide groups, wherein the one or more organic acid halide compounds are in an amount wherein the acid halide groups are present in a minimum concentration of about 100 parts per million by weight of the polyurethane prepolymer. In other aspects, the invention relates to methods for storing the curable polyurethane compositions, as well as methods for producing polyurethane elastomers.
摘要:
An antiozonant mixture is disclosed wherein said mixture comprises at least two compounds, (A) at least one of which is of the structure, Formula (I); and (B) at least one other of which is of the structure, Formula (II); wherein R1 is a straight chain, branched, or cyclic alkyl group comprising from three to seven carbon atoms, and R2 is a straight chain, branched, or cyclic alkyl group comprising at least eleven carbon atoms.
摘要:
A single-step process is disclosed for the ring alkylation of at least one N-alkyl-N'-phenyl-phenylenediamine with at least one olefin wherein the process comprises heating a mixture of the N-alkyl-N'-phenyl-phenylenediamine(s) and olefin(s) in the presence of a catalytic amount of at least one alkyl aluminum halide at a temperature of from about 50 to about 350 °C in a sealed vessel for from about one to about 30 hours.
摘要:
A process for ring-alkylating aniline or an aniline derivative in which aniline or an aniline derivative is reacted with an alkylating agent in the presence of an ionic liquid which includes a Lewis acid and a quaternary cation, to produce a ring-alkylated alkylaniline .or a ring-alkylated aniline derivative. The use of an ionic liquid permits convenient separation of the alkylated reaction product from the reactants.