Coating and lithiation of inorganic oxidants by reaction with lithiated reductants
    182.
    发明公开
    Coating and lithiation of inorganic oxidants by reaction with lithiated reductants 审中-公开
    Beschichtung und Lithiierung von anorganischen Oxidantien durch Reaktion mit lithiierten Reduktionsmitteln

    公开(公告)号:EP2634845A1

    公开(公告)日:2013-09-04

    申请号:EP12157429.7

    申请日:2012-02-29

    摘要: A method for producing conductive carbon coated particles of an at least partially lithiated electroactive core material comprises the step of premixing an oxidant electroactive material with a metallated reductant followed by chemically reacting the oxidant electroactive material with the metallated reductant, said reductant being a coating precursor, said metal being at least one alkaline and/or at least one alkaline earth metal, and said chemically reacting being performed under conditions allowing reduction and metallation of the electroactive material via insertion/intercalation of the alkaline metal cation(s) and/or the alkaline earth metal cation(s) and coating formation via a polymerisation reaction like polyanionic or radicalic polymerisation of the reductant.

    摘要翻译: 用于制备至少部分锂化电活性芯材的导电碳涂覆颗粒的方法包括以下步骤:将氧化剂电活性材料与金属化还原剂预混合,随后使氧化剂电活性材料与金属化还原剂发生化学反应,所述还原剂是涂料前体, 所述金属是至少一种碱性和/或至少一种碱土金属,并且所述化学反应在允许电活性材料通过碱金属阳离子和/或碱性金属阳离子的插入/插入而还原和金属化的条件下进行 接地金属阳离子和通过聚合反应如还原剂的聚阴离子或自由基聚合形成涂层。

    Synthesis of metal compounds useful as cathode active materials
    183.
    发明公开
    Synthesis of metal compounds useful as cathode active materials 审中-公开
    的是适合于用作阴极活性材料的金属化合物的合成

    公开(公告)号:EP2583939A2

    公开(公告)日:2013-04-24

    申请号:EP13152075.1

    申请日:2003-05-06

    摘要: A solid state method for synthesizing a reduced inorganic metal compound of the invention comprises the steps of: (i) combining starting materials free of lithium and comprising one or more metal compounds and at least one source of reducing carbon to form a mixture; and (ii) heating the mixture at a temperature and for a time sufficient to form a reaction product comprising the reduced inorganic metal compound; wherein at least one metal of the starting materials is reduced in oxidation state during heating. Furthermore, a method of preparing a finely dispersed mixture of electrochemically active material and a conductive carbon of the invention comprises the steps of: (i) preparing a mixture comprising at least one alkali metal compound, at least one metal compound, and a carbon-containing composition selected from the group consisting of elemental carbon and an organic material; and (ii) heating the mixture for a time and at a temperature sufficient to form a reaction product.

    摘要翻译: 用于合成本发明的降低的无机金属化合物的固态方法,包括以下步骤:(ⅰ)无锂和包含一种或多种金属化合物和还原性碳,以形成混合物中的至少一个源的起始材料组合; 和(ii)的温度下加热和足够的时间,以形成反应产物,其包括还原的无机金属化合物的混合物; worin起始材料中的至少一种金属在加热过程中在氧化态降低。 进一步,制备的电化学活性材料的细分散的混合物和本发明的导电性碳的方法包括以下步骤:(i)制备包含至少一种碱金属化合物,至少一种金属化合物的混合物,以及碳 - 选自元素碳和有机材料的组合物含有选择; 和(ii)加热一段时间,并在足以形成反应产物的温度下该混合物。

    METHOD FOR PRODUCING LITHIUM VANADIUM POLYANION POWDERS FOR BATTERIES
    189.
    发明公开
    METHOD FOR PRODUCING LITHIUM VANADIUM POLYANION POWDERS FOR BATTERIES 审中-公开
    生产电池用锂钒多金属粉末的方法

    公开(公告)号:EP2156490A1

    公开(公告)日:2010-02-24

    申请号:EP08770177.7

    申请日:2008-06-05

    CPC分类号: H01M4/5825 C01B25/45

    摘要: A process for producing a cathode powder for making lithium ion batteries wherein the powder comprises lithium, vanadium and a polyanion. The process includes forming a solution-suspension of the precursors, including vanadium pentoxide, with a reducing agent, a solvent, and a carbon-residue-forming material. The reducing agent reduces the vanadium in vanadium pentoxide from V5+ to V3+. The solution-suspension is heated in inert environment to drive synthesis of the LVP so the carbon-residue-forming material is oxidized and precipitates, forming CCLVP. Liquids are separated from solids and the dry powder is heated to drive crystallization of the product. The product retains small particle size, includes carbon in the LVP for conductivity, and is created with low cost precursors and with no need to reduce the product size for use in batteries. Addition of carbon black, graphite or other form of carbon is unnecessary to provide the conductivity required for use in batteries.

    摘要翻译: 一种制造用于制造锂离子电池的阴极粉末的方法,其中所述粉末包含锂,钒和聚阴离子。 该方法包括用还原剂,溶剂和碳残余物形成材料形成前体的溶液 - 悬浮液,包括五氧化钒。 还原剂将五氧化二钒中的钒从V5 +还原成V3 +。 在惰性环境中加热溶液 - 悬浮液以驱动LVP的合成,因此形成碳残留物质被氧化并沉淀,形成CCLVP。 液体与固体分离,加热干粉以促使产品结晶。 该产品保留了小颗粒尺寸,在LVP中含有碳,用于传导性,并且是用低成本的前体制造的,并且不需要缩小用于电池的产品尺寸。 不需要添加碳黑,石墨或其他形式的碳来提供电池所需的导电性。

    Composition for negative electrodes and non-aqueous rechargeable battery prepared using Same
    190.
    发明公开
    Composition for negative electrodes and non-aqueous rechargeable battery prepared using Same 审中-公开
    使用它制备的负极组合物和非水可充电电池

    公开(公告)号:EP1935850A3

    公开(公告)日:2008-07-02

    申请号:EP07123519.6

    申请日:2007-12-18

    IPC分类号: C01G31/00 H01M4/48 H01M10/40

    摘要: The present invention relates to a negative material for a non-aqueous rechargeable battery and a non-aqueous rechargeable battery including the same. The negative material for a non-aqueous rechargeable battery includes lithium vanadium oxide that is obtained by mixing a lithium compound such as lithium carbonate (Li 2 CO 3 ) and a vanadium compound such as vanadium pentaoxide (V 2 O 5 ) with an organic acid such as oxalic acid (COOH) 2 to obtain an organic acid salt precursor and firing the organic acid salt precursor. The negative material for a non-aqueous rechargeable battery can improve charge and discharge characteristics of a non-aqueous rechargeable battery due to uniform composition.

    摘要翻译: 本发明涉及用于非水可再充电电池的负极材料和包含该负极材料的非水可充电电池。 非水可再充电电池的负极材料包括通过将诸如碳酸锂(Li 2 CO 3)的锂化合物和诸如五氧化二钒(V 2 O 5)的钒化合物与有机酸如草酸(COOH)混合而获得的锂钒氧化物 )2以获得有机酸盐前体并烧制有机酸盐前体。 由于组成均匀,用于非水可再充电电池的负极材料可改善非水可充电电池的充电和放电特性。