摘要:
A method for producing conductive carbon coated particles of an at least partially lithiated electroactive core material comprises the step of premixing an oxidant electroactive material with a metallated reductant followed by chemically reacting the oxidant electroactive material with the metallated reductant, said reductant being a coating precursor, said metal being at least one alkaline and/or at least one alkaline earth metal, and said chemically reacting being performed under conditions allowing reduction and metallation of the electroactive material via insertion/intercalation of the alkaline metal cation(s) and/or the alkaline earth metal cation(s) and coating formation via a polymerisation reaction like polyanionic or radicalic polymerisation of the reductant.
摘要:
A solid state method for synthesizing a reduced inorganic metal compound of the invention comprises the steps of: (i) combining starting materials free of lithium and comprising one or more metal compounds and at least one source of reducing carbon to form a mixture; and (ii) heating the mixture at a temperature and for a time sufficient to form a reaction product comprising the reduced inorganic metal compound; wherein at least one metal of the starting materials is reduced in oxidation state during heating. Furthermore, a method of preparing a finely dispersed mixture of electrochemically active material and a conductive carbon of the invention comprises the steps of: (i) preparing a mixture comprising at least one alkali metal compound, at least one metal compound, and a carbon-containing composition selected from the group consisting of elemental carbon and an organic material; and (ii) heating the mixture for a time and at a temperature sufficient to form a reaction product.
摘要:
The current invention relates to a method of making metal oxide nanoparticles comprising the reaction of - at least one metal oxide precursor (P) containing at least one metal (M) with - at least one monofunctional alcohol (A) wherein the hydroxy group is bound to a secondary, tertiary or alpha-unsaturated carbon atom - in the presence of at least one aliphatic compound (F) according to the formula Y 1 -R 1 -X-R 2 -Y 2 , wherein - R 1 and R 2 each are the same or different and independently selected from aliphatic groups with from 1 to 20 carbon atoms, - Y 1 and Y 2 each are the same or different and independently selected from OH, NH 2 and SH, and - X is selected from the group consisting of chemical bond, -O-, -S-, -NR 3 -, and CR 4 R 5 , wherein R 3 , R 4 and R 5 each are the same or different and represent a hydrogen atom or an aliphatic group with from 1 to 20 carbon atoms which optionally carries functional groups selected from OH, NH 2 and SH. This invention also relates to metal oxide nanoparticles, to a method of making dispersions of said nanoparticles and to dispersions containing them.
摘要:
The present invention relates to iron-doped vanadium(V) oxides of formula FeyV2O5, a process for their preparation and their uses as positive electrodes, especially in microbattehes.
摘要:
The invention provides a novel method for making lithium mixed metal materials in electrochemical cells. The lithium mixed metal materials comprise lithium and at least one other metal besides lithium. The invention involves the reaction of a metal compound, a phosphate compound, with a reducing agent to reduce the metal and form a metal phosphate. The invention also includes methods of making lithium metal oxides involving reaction of a lithium compound, a metal oxide with a reducing agent.
摘要:
The ions other than lithium ions and having a greater ion radius are interposed, before the lithium ions are doped, as an interlayer securing member in a vanadium oxide having a layered crystal into which the lithium ions can be doped. Since the interlayer securing member is interposed, the doping or dedoping of the lithium ions into or from the vanadium oxide afterward can be smoothly performed. Sodium ions or the like can be employed as the interlayer securing member.
摘要:
A process for producing a cathode powder for making lithium ion batteries wherein the powder comprises lithium, vanadium and a polyanion. The process includes forming a solution-suspension of the precursors, including vanadium pentoxide, with a reducing agent, a solvent, and a carbon-residue-forming material. The reducing agent reduces the vanadium in vanadium pentoxide from V5+ to V3+. The solution-suspension is heated in inert environment to drive synthesis of the LVP so the carbon-residue-forming material is oxidized and precipitates, forming CCLVP. Liquids are separated from solids and the dry powder is heated to drive crystallization of the product. The product retains small particle size, includes carbon in the LVP for conductivity, and is created with low cost precursors and with no need to reduce the product size for use in batteries. Addition of carbon black, graphite or other form of carbon is unnecessary to provide the conductivity required for use in batteries.
摘要:
The present invention relates to a negative material for a non-aqueous rechargeable battery and a non-aqueous rechargeable battery including the same. The negative material for a non-aqueous rechargeable battery includes lithium vanadium oxide that is obtained by mixing a lithium compound such as lithium carbonate (Li 2 CO 3 ) and a vanadium compound such as vanadium pentaoxide (V 2 O 5 ) with an organic acid such as oxalic acid (COOH) 2 to obtain an organic acid salt precursor and firing the organic acid salt precursor. The negative material for a non-aqueous rechargeable battery can improve charge and discharge characteristics of a non-aqueous rechargeable battery due to uniform composition.
摘要翻译:本发明涉及用于非水可再充电电池的负极材料和包含该负极材料的非水可充电电池。 非水可再充电电池的负极材料包括通过将诸如碳酸锂(Li 2 CO 3)的锂化合物和诸如五氧化二钒(V 2 O 5)的钒化合物与有机酸如草酸(COOH)混合而获得的锂钒氧化物 )2以获得有机酸盐前体并烧制有机酸盐前体。 由于组成均匀,用于非水可再充电电池的负极材料可改善非水可充电电池的充电和放电特性。