摘要:
Improved membranes and improved membrane processes for treating gas streams containing hydrogen sulfide and methane, plus water vapor, carbon dioxide or both. The processes rely on th availability of two membrane of two membrane types, one of which has a high hydrogen sulfide/methane selectivity and a high water vapor/methane selectivity, when measured with multicomponent gas mixtures at high pressures. Based on the different permeation properties of the two membrane types, optimized separation processes can be designed. In favorable cases, the processes can simultaneously dehydrate the gas stream and remove the hydrogen sulfide to very low levels.
摘要:
A spiral-wound pervaporation module, incorporating membrane envelopes (2), within and between which are channels through which the feed and permeate streams flow. The feed and permeate channels are created by feed spacers (3) and permeate spacers (4). The module is unconventional in that the permeate spacer is tailored for optimum permeate flow throughput, based on the discovery that the total permeate flow throughput passes through a maximum as the resistance to vapor transport of the permeate spacer material is progressively decreased. The resistance to vapor transport along the permeate channel is kept below a value at which it has a significant adverse effect on the membrane flux and the membrane separation properties, yet at the same time the total module throughput is within an optimum range. The increase in throughput per unit membrane area obtained more than compensates for the loss in membrane area brought about by use of a thicker permeate spacer.
摘要:
A separation process for recovering organic components from liquid streams. The process is a combination of pervaporation and decantation. In cases where the liquid stream contains the organic to be separated in dissolved form, the pervaporation step is used to concentrate the organic to a point above the solubility limit, so that a two-phase permeate is formed and then decanted. In cases where the liquid stream is a two-phase mixture, the decantation step is performed first, to remove the organic product phase, and the residue from the decanter is then treated by pervaporation. Embodiments using two decanters, particularly suited to handling feed streams containing multiple organic compounds of different properties, are included.
摘要:
A membrane process for separating fluorinated hydrocarbon vapors is disclosed. The process employs a permselective membrane that is selectively permeable to fluorinated hydrocarbons over oxygen or nitrogen. The process involves contacting the feed side of the membrane with a gas mixture containing the fluorinated hydrocarbon vapor, and withdrawing from the permeate side a vapor enriched in the fluorinated hydrocarbon component. The driving force for membrane permeation is preferably provided by maintaining a partial vacuum on the permeate side of the membrane. Eighty to 99% of the fluorinated hydrocarbon contained in the feedstream can be removed by the process. The permeate may be sufficiently enriched in fluorinated hydrocarbon to permit recovery and reuse. Very high membrane selectivities are not required
摘要:
A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.
摘要:
A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.