公开(公告)号：EP2193174A1

公开(公告)日：2010-06-09

申请号：EP08799058.6

申请日：2008-09-02

申请人： 3M Innovative Properties Company

发明人： POKORNY, Richard, J. ,  KLUN, Thomas, P. ,  RADCLIFFE, Marc, D. ,  KAMRATH, Robert, F. ,  WALKER, Christopher, B., Jr.

IPC分类号： C09D5/00 ,  G02B1/11

CPC分类号： G02B1/11 ,  B82Y20/00 ,  C08K3/22 ,  C08K9/06 ,  C09D5/006 ,  C09D7/62 ,  G02B2207/101 ,  Y10T428/24942

摘要： Presently described are self-assembling antireflective (“AR”) coating compositions comprising high refractive index surface modified nanoparticles. Also described are various articles such as protective films, optical displays, and windows, comprising such (e.g. dried and cured) AR coating.

公开(公告)号：EP1660612B1

公开(公告)日：2009-01-07

申请号：EP04777612.5

申请日：2004-07-06

申请人： 3M Innovative Properties Company

发明人： RADCLIFFE, Marc, D. ,  POKORNY, Richard, J. ,  SPAWN, Terence, D. ,  SOLOMONSON, Steven, D.

IPC分类号： C09K19/40 ,  C09K19/42

CPC分类号： C09K19/3852 ,  C09K19/2007 ,  C09K2019/0448 ,  C09K2019/2035 ,  C09K2019/2078 ,  C09K2019/3095 ,  C09K2219/03 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/105

摘要： A cholesteric liquid crystal composition includes a) a cholesteric liquid crystal compound or a cholesteric liquid crystal precursor; and b) a compound of formula (I), formula (II) or formula (III): where, n is 1, 2, 3, or 4; m is 1, 2, or 3; R is an acrylate, methacrylate, acrylamide, isocyanate, epoxy, or silane; R1 is a (C3-C8) alkylene, (C3-C8) alkenylene, or (C3-C8) alkylyne; R2 is a bond, -O-, -C(O)O-, -O(O)C-, -OC(O)O-, -C(O)N-, -CH=N-, -N=CH-, or -NC(O)-; R3 is a cycloalkylene, cycloalkenylene, heterocyclylene, arylene, or hetroarylene; R4 is a bond, (C1-C8) alkylene, (C2-C8) alkenylene, (C2-C8) alkylyne, carbonyl, -O-, -C(O)O-, -O(O)C-, -OC(O)O-, -C(O)N-, -CH=N-, -N=CH-, or -NC(O)-; R5 is a bond, cycloalkylene, cycloalkenylene, hetrocyclylene, arylene, or hetroarylene; R6 is hydrogen, cyano, halo, (C1-C8) alkoxy, (C1-C8) alkyl, nitro, amino, carboxy, mercapto, (C1-C4)thioalkyl, COCH3, CF3, OCF3, or SCF3; R7 is a (C1-C2) alkylene, (C2) alkenylene, or (C2) alkylyne; R8 is is hydrogen, halo, (C1-C8) alkoxy, (C1-C8) alkyl, nitro, amino, carboxy, mercapto, (C1-C4)thioalkyl, COCH3, CF3, OCF3, or SCF3, R9 is a cycloalkylene, cycloalkenylene, heterocyclylene, arylene, or hetroarylene; and R10 is a (C1-C8) alkylene, (C2-C8) alkenylene, or (C2-C8) alkylyne.

公开(公告)号：EP1597337B1

公开(公告)日：2007-04-18

申请号：EP04701469.1

申请日：2004-01-12

申请人： 3M Innovative Properties Company

发明人： SOLOMONSON, Steven, D. ,  RADCLIFFE, Marc, D. ,  POKORNY, Richard, J.

IPC分类号： C09K19/52

CPC分类号： C09K19/52

摘要： The invention provides methods of forming a cholesteric liquid crystal layer that include forming a cholesteric liquid crystal composition, depositing the cholesteric liquid crystal composition onto a substrate, and initially drying the cholesteric liquid crystal composition at a temperature at or below about 90 °C so that the cholesteric liquid crystal composition has at least 80 % solids remaining. The invention also provides methods of forming a cholesteric liquid crystal layer that include forming a cholesteric liquid crystal composition, depositing the cholesteric liquid crystal composition onto a substrate, and initially drying the cholesteric liquid crystal composition at a temperature at or below about 90 °C, wherein the drying is accomplished using a technique that provides little or no airflow. The invention further provides a cholesteric liquid crystal composition that includes at least one cholesteric liquid crystal precursor and 1,3-dioxolane.

公开(公告)号：EP1751589A1

公开(公告)日：2007-02-14

申请号：EP05753253.3

申请日：2005-05-10

申请人： 3M Innovative Properties Company

发明人： POKORNY, Richard, J. ,  RADCLIFFE, Marc, D. ,  SOLOMONSON, Steven, D. ,  SPAWN, Terence, D.

IPC分类号： G02B5/30 ,  G02F1/13357

CPC分类号： G02B5/3016 ,  G02F1/133536 ,  G02F2201/343

摘要： Methods of making an optical body are disclosed. A method includes the steps of coating a mixture including a first cholesteric liquid crystal polymer, a second cholesteric liquid crystal monomer, a second cholesteric liquid crystal polymer formed from a portion of the second cholesteric liquid crystal monomer, and a solvent on a substrate. The first cholesteric liquid crystal polymer is different than the second cholesteric liquid crystal polymer. Then, forming from the mixture an optical body including a first layer, a second layer, and a third layer disposed between the first and second layer. The first layer includes a majority of the first cholesteric liquid crystal polymer. The second layer includes a majority of a second cholesteric liquid crystal monomer. The third layer includes the second cholesteric liquid crystal polymer.

公开(公告)号：EP2872537A1

公开(公告)日：2015-05-20

申请号：EP13740141.0

申请日：2013-07-10

申请人： 3M Innovative Properties Company

发明人： POKORNY, Richard, J. ,  SOLOMONSON, Steven, D. ,  KAMRATH, Robert, F. ,  RENSTROM, Anthony, M. ,  BARTON, Roger, W. ,  SYKORA, Craig, R.

IPC分类号： C08F2/48

CPC分类号： C09D4/00 ,  C08F2/48 ,  C08F222/1006 ,  C08K3/36 ,  C08K2201/005 ,  C09D7/61 ,  C09D7/67 ,  C09D135/02 ,  G02B1/04 ,  G02B1/14 ,  G03F7/0046 ,  G03F7/0047 ,  G03F7/027 ,  G03F7/0757 ,  G06F3/044 ,  Y10T428/31544

摘要： Presently described are hardcoat compositions comprising at least one first (meth)acrylate monomer comprising at least three (meth)acrylate groups and C2-C4 alkoxy repeat units wherein the monomer has a molecular weight per (meth)acrylate group ranging from about 220 to 375 g/mole and at least one second (meth)acrylate monomer comprising at least three (meth)acrylate groups. In one embodiment, the hardcoat composition further comprises and at least 30 wt-% solids of silica nanoparticles having an average particle size ranging from 50 to 150 nm. In another embodiment, the hardcoat composition further comprises and at least 30 wt-% solids of inorganic oxide nanoparticles having an average particle size ranging from 50 to 150 nm. Also described are articles, such as protective films, displays, and touch screens comprising such cured hardcoat compositions.

摘要翻译： 目前描述的是包含至少一种包含至少三个（甲基）丙烯酸酯基团和C 2 -C 4烷氧基重复单元的至少一种第一（甲基）丙烯酸酯单体的硬涂层组合物，其中单体具有约220至375的（甲基）丙烯酸酯基团的分子量 g / mol和至少一种包含至少三个（甲基）丙烯酸酯基团的（甲基）丙烯酸酯单体。 在一个实施方案中，硬涂层组合物还包含至少50重量％的二氧化硅纳米颗粒固体。 还描述了诸如保护膜，显示器和包含这种固化的硬涂层组合物的触摸屏的制品。

公开(公告)号：EP2310884A1

公开(公告)日：2011-04-20

申请号：EP09774014.6

申请日：2009-06-11

申请人： 3M Innovative Properties Company

发明人： LIU, Lan, H. ,  KAMRATH, Robert, F. ,  HAO, Encai ,  MCKENZIE, Taun, L. ,  RADCLIFFE, Marc, D. ,  POKORNY, Richard, J. ,  WALKER, Christopher, B., Jr. ,  RENSTROM, Anthony, M.

IPC分类号： G02B1/11

CPC分类号： G02B1/111 ,  B82Y20/00 ,  B82Y30/00 ,  G02F1/133502 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/26 ,  Y10T428/265 ,  Y10T428/2995 ,  Y10T428/31855

摘要： Antireflective films comprising a flexible high refractive index layer that comprises at least 60 wt-% of inorganic nanoparticles, the nanoparticles having a refractive index of at least 1.60, dispersed in a crosslinked organic material. Also described are surface treated nanoparticles.

公开(公告)号：EP2268417A1

公开(公告)日：2011-01-05

申请号：EP09723736.6

申请日：2009-03-19

申请人： 3M Innovative Properties Company

发明人： YAPEL, Robert, A. ,  LUDEMANN, Thomas, J. ,  HEDDING, Brent, A. ,  POKORNY, Richard, J. ,  BAETZOLD, John, P. ,  NORTON, Daniel, V. ,  TANLEY, Chris, J.

IPC分类号： B05D1/26 ,  B05D7/00

CPC分类号： B05C5/007 ,  B05C9/06 ,  B05D1/26 ,  B05D7/542 ,  B05D2252/02 ,  B05D2601/20

摘要： A method of slide coating that includes providing a first fluid, wherein the first fluid includes at least one solvent, at least one single unit polymeric precursor or a combination thereof; providing a second fluid, wherein the second fluid includes multi unit polymeric precursors; flowing the first fluid down a first slide surface, to create a first fluid layer on the first slide surface, the first slide surface being positioned adjacent a substrate; flowing the second fluid down a second slide surface, the second slide surface positioned relative to the first slide surface such that the second fluid flows from the second slide surface to above the first slide surface onto the first fluid layer to create the second fluid layer on the first slide surface; coating the substrate with the first and second fluid by flowing the first fluid layer and the second fluid layer from the first slide surface to the substrate forming first and second coated layers; moving the substrate; and at least partially curing the first coated layer, the second coated layer, or some combination thereof.

摘要翻译： 一种包括提供第一流体的滑动涂布方法，其中所述第一流体包括至少一种溶剂，至少一种单一单元聚合物前体或其组合; 提供第二流体，其中所述第二流体包括多单元聚合物前体; 使第一流体沿第一滑动表面向下流动，以在第一滑动表面上形成第一流体层，第一滑动表面定位在基底附近; 使第二流体沿第二滑动表面向下流动，第二滑动表面相对于第一滑动表面定位，使得第二流体从第二滑动表面流动到第一滑动表面上方到第一流体层上以在第一流体层上产生第二流体层 第一滑动表面; 通过使第一流体层和第二流体层从第一滑动表面流到形成第一和第二涂层的基板，用第一和第二流体涂覆基板; 移动基板; 并且至少部分地固化第一涂层，第二涂层或它们的一些组合。

公开(公告)号：EP2265981A1

公开(公告)日：2010-12-29

申请号：EP09727097.9

申请日：2009-03-30

申请人： 3M Innovative Properties Company

发明人： BÖSL, Ellen, R. ,  CHIEN, Bert, T. ,  FRANKE, Carsten ,  HART, Shandon, D. ,  HEDDING, Brent, A. ,  KARG, Donovan, C., Jr. ,  LUDEMANN, Thomas, J. ,  NOONEY, Meghan, A. ,  O'NEILL, Mark, B. ,  PETERSON, Jeffrey, A. ,  STROBEL, Joan, M. ,  TAI, Huiwen, ,  VAN DERLOFSKE, John, F. III ,  WEBER, Michael, F. ,  WONG, Chiu, Ping ,  POKORNY, Richard, J. ,  BAETZOLD, John, P.

IPC分类号： G02B5/30 ,  G02F1/1335 ,  G02F1/13363 ,  G02F1/13357

CPC分类号： G02B5/3083 ,  G02B5/3033 ,  G02F1/133536 ,  G02F1/133606 ,  G02F1/13362 ,  G02F1/133634 ,  G02F2001/133531 ,  G02F2001/133543 ,  G02F2413/12 ,  Y02P20/582

摘要： An optical film that includes a reflective polarizer and a stretched polymer film is disclosed. The stretched polymer film is laminated to the reflective polarizer, and the stretched polymer film exhibits a refractive index symmetry point at an angle of incidence in air of at least about 60 degrees in a plane of incidence parallel to a direction of greatest stretch.

摘要翻译： 公开了一种包括反射偏振器和拉伸聚合物膜的光学膜。 拉伸的聚合物膜被层压到反射偏振器上，并且拉伸的聚合物膜在平行于最大拉伸方向的入射平面中在空气中的入射角呈现至少约60度的折射率对称点。

公开(公告)号：EP2044471A1

公开(公告)日：2009-04-08

申请号：EP07761862.7

申请日：2007-05-04

申请人： 3M Innovative Properties Company

发明人： RADCLIFFE, Marc, D. ,  KLUN, Thomas, P. ,  LIU, Lan, H. ,  POKORNY, Richard, J. ,  IYER, Suresh ,  QIU, Zai-Ming

IPC分类号： G02B1/11 ,  C09D4/02 ,  C09D163/00

CPC分类号： G02B1/111 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/3154 ,  Y10T428/31678 ,  Y10T428/31935

摘要： Antireflective film articles and low refractive index coating compositions are described that comprises a fluorinated free-radically polymerizable polymeric (e.g. intermediate) material. The free-radically polymerizable fluorinated polymeric intermediate comprises the reaction product of i) at least one multi-functional free-radically polymerizable material having a fluorine content of at least 25 wt-%, and ii) optionally other multi-functional free-radically polymerizable material. The total amount of multi-functional materials is preferably at least about 25 wt-%.

公开(公告)号：EP1352000B1

公开(公告)日：2005-12-21

申请号：EP01932822.8

申请日：2001-05-01

申请人： 3M Innovative Properties Company

发明人： OLSON, David, B. ,  POKORNY, Richard, J. ,  FONG, Bettie, C.

IPC分类号： C08F228/02 ,  C08F220/30 ,  G02B1/04

CPC分类号： C08F228/02 ,  C08F220/30 ,  G02B1/04 ,  Y10T428/31507 ,  Y10T428/31576 ,  Y10T428/31649 ,  Y10T428/31797 ,  Y10T428/3188 ,  Y10T428/31917 ,  C08L33/14

摘要： A polymerizable composition that includes a monomer of the formula (I) wherein X is hydrogen or one or more of methyl, chlorine, bromine or iodine, R1 is a straight or branched alkyl linking group of 2 to 12 carbon atoms, R2 is hydrogen or methyl, and n is 1 to 3; and a monomer of the formula (II) wherein X¿1? and X2 are each independently hydrogen or one or more of methyl, chlorine, bromine or iodine, and R?2¿ is hydrogen or methyl is described having a high index of refraction and being suitable for use in forming an optical product.

摘要翻译： 包含式（I）的单体的可聚合组合物，其中X为氢或甲基，氯，溴或碘中的一种或多种，​​R 1为2至12个碳原子的直链或支链烷基连接基团，R 2为氢或 甲基，并且n是1至3; 和式（II）的单体，其中X' 和X2各自独立地为氢或甲基，氯，溴或碘中的一种或多种，​​并且R 2'为氢或甲基的化合物被描述为具有高折射率并且适用于形成光学产品。