公开(公告)号：EP2225220B1

公开(公告)日：2013-05-22

申请号：EP08863798.8

申请日：2008-12-10

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  TEBBEN, Dr. Gerd-Dieter ,  BREUNINGER, Daniel ,  SIRCH, Tilman ,  BAUDUIN, Christophe ,  GUIXA GUARDIA, Maria ,  KRUG, Thomas

IPC: C07D313/04

CPC classification number: C07D313/04

公开(公告)号：EP2417089A2

公开(公告)日：2012-02-15

申请号：EP10711899.4

申请日：2010-03-31

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  BREUNINGER, Daniel ,  TEBBEN, Gerd-Dieter

IPC: C07C29/149 ,  C07C29/80 ,  C07C31/20 ,  C07D315/00

CPC classification number: C07C29/145 ,  C07C29/149 ,  C07C29/80 ,  C07C51/313 ,  C07C67/08 ,  C07D307/33 ,  C07D313/04 ,  C07C35/14 ,  C07C31/125 ,  C07C59/185 ,  C07C59/01 ,  C07C55/14 ,  C07C69/02

Abstract: The invention relates to a method for producing 1,6-hexanediol and caprolactone, preferably of at least 99.5% purity, which are especially substantially free from 1,4 cyclohexanediols, starting from a carboxylic acid mixture which is obtained as a byproduct of the catalytic oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or gases containing oxygen and by extraction of the reaction mixture with water, and by hydrogenation of the carboxylic acid mixture, esterification and hydrogenation of a partial flow to hexanediol and cyclization of 6-hydroxycaproic ester, the 1,4-cyclohexanediols being removed during fractionation of the esterification mixture or finally from the caprolactone.

公开(公告)号：EP2158192A1

公开(公告)日：2010-03-03

申请号：EP08760684.4

申请日：2008-06-06

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  TEBBEN, Gerd ,  BAUDUIN, Christophe ,  BREUNINGER, Daniel ,  GUIXA GUARDIA, Maria ,  SIRCH, Tilman ,  KRUG, Thomas

IPC: C07D313/04 ,  C07C67/02

CPC classification number: C07D313/04

Abstract: The invention relates to a method for producing ε-caprolacton at a purity of 99%, wherein 6-hydroxycaproic acid ester having 0.5 to 40 weight % adipic acid diesters is cyclisized in the gas phase at 150 to 450˚C in the presence of oxidic catalysts, and ε-caprolacton is obtained by distillation of the cyclisization product.

公开(公告)号：EP2614056B1

公开(公告)日：2014-07-23

申请号：EP11749864.2

申请日：2011-09-05

Applicant: BASF SE

Inventor： ABILLARD, Olivier ,  BREUNINGER, Daniel ,  KLEINMANN, Eva ,  PINKOS, Rolf

IPC: C07D313/04 ,  C07C29/149

CPC classification number: C07D313/04 ,  C07C29/149 ,  C07C29/80 ,  C07C29/86 ,  C07C51/316 ,  C07C31/20 ,  C07C55/14

公开(公告)号：EP2417089B1

公开(公告)日：2013-06-05

申请号：EP10711899.4

申请日：2010-03-31

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  BREUNINGER, Daniel ,  Dr. TEBBEN, Gerd-Dieter

IPC: C07C29/149 ,  C07C31/125 ,  C07C29/145 ,  C07C29/80 ,  C07C35/14 ,  C07C51/31 ,  C07C59/185 ,  C07C59/01 ,  C07C55/14 ,  C07C67/08 ,  C07C69/02 ,  C07D313/04 ,  C07D307/33

CPC classification number: C07C29/145 ,  C07C29/149 ,  C07C29/80 ,  C07C51/313 ,  C07C67/08 ,  C07D307/33 ,  C07D313/04 ,  C07C35/14 ,  C07C31/125 ,  C07C59/185 ,  C07C59/01 ,  C07C55/14 ,  C07C69/02

公开(公告)号：EP2421818A1

公开(公告)日：2012-02-29

申请号：EP10713992.5

申请日：2010-04-20

Applicant: BASF SE

Inventor： STROEFER, Eckhard ,  SCHELLING, Heiner ,  REINHARDT, Robert ,  ZOELLINGER, Michael ,  BREUNINGER, Daniel ,  KRAEMER, Markus ,  THIELE, Kai ,  VAN DEN ABEEL, Peter

IPC: C07C209/78 ,  C07C263/10 ,  C07C211/50 ,  C07C265/14

CPC classification number: C07C209/78 ,  C07C263/10 ,  C07C211/50 ,  C07C265/14

Abstract: The invention relates to a method for producing methylene diphenyl diamine (MDA) by reacting formaldehyde and aniline in the presence of an acidic catalyst, characterized in that in the production of MDA, the oxygen content in the process is

公开(公告)号：EP2417088A1

公开(公告)日：2012-02-15

申请号：EP10711879.6

申请日：2010-03-29

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  BREUNINGER, Daniel ,  TEBBEN, Gerd-Dieter

IPC: C07C29/149 ,  C07C29/80 ,  C07C31/20

CPC classification number: C07C29/145 ,  C07C29/149 ,  C07C29/80 ,  C07C51/313 ,  C07C67/08 ,  C07C35/14 ,  C07C31/20 ,  C07C59/185 ,  C07C59/01 ,  C07C69/44 ,  C07C69/675

Abstract: The invention relates to a method for producing 1,6-hexanediol, preferably of at least 99.5% purity, which hexanediol is especially substantially free from 1,4 cyclohexanediols, starting from a carboxylic acid mixture which is obtained as a byproduct of the catalytic oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or gases containing oxygen and by extraction of the reaction mixture with water, and by hydrogenation of the carboxylic acid mixture, esterification and hydrogenation of a partial flow to hexanediol.

Abstract translation: 本发明涉及生产1,6-己二醇的方法，优选至少99.5％纯度的己二醇特别基本上不含1,4环己二醇，起始于作为催化氧化的副产物获得的羧酸混合物 的环己烷转化为环己酮/环己醇与氧气或含氧气体并且通过用水萃取反应混合物，并且通过氢化羧酸混合物，酯化并且将部分流的氢化成己二醇。

公开(公告)号：EP2321241A1

公开(公告)日：2011-05-18

申请号：EP09781102.0

申请日：2009-07-27

Applicant: BASF SE

Inventor： WEIS, Martine ,  BREUNINGER, Daniel ,  EBEL, Klaus ,  WINSEL, Harald

IPC: C07C29/149 ,  C07C67/317 ,  C07C67/343 ,  C07C69/65 ,  C07C69/738

CPC classification number: C07C67/317 ,  C07C29/149 ,  C07C67/343 ,  C07C69/65 ,  C07C69/738 ,  C07C33/46

Abstract: The present invention relates to a method for producing phenylalkane-1-ols 5 using three steps, wherein in the first step an ester condensation is carried out in the presence of alkali or alkaline earth alcoholates.

公开(公告)号：EP2051972B1

公开(公告)日：2010-08-18

申请号：EP08761344.4

申请日：2008-06-24

Applicant: BASF SE

Inventor： WABNITZ, Tobias ,  BREUNINGER, Daniel ,  HEIMANN, Jens ,  BACKES, Rene ,  PINKOS, Rolf

IPC: C07D307/06

CPC classification number: C07D307/06

公开(公告)号：EP2167456A1

公开(公告)日：2010-03-31

申请号：EP08760734.7

申请日：2008-06-09

Applicant: BASF SE

Inventor： WLOKA, Veronika ,  MATTKE, Torsten ,  KNÖSCHE, Carsten ,  BREUNINGER, Daniel ,  BOTTKE, Nils

IPC: C07C209/78 ,  C01B7/05 ,  C01B7/07

CPC classification number: C01B7/055 ,  B01D15/00 ,  B01J20/18 ,  C01B7/0718 ,  C07C209/78 ,  C07C211/50

Abstract: The invention relates to a method for the recovery of diphenylmethane diamine, comprising the steps of A) reaction of aniline with formaldehyde in the presence of a mineral acid, B) neutralization of the mineral acid with a base, C) separation of the organic and inorganic phase, D) removal of the base from the inorganic phase by adsorption, c) recovery of the mineral acid.