VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN UND/ODER POLYISOCYANATEN
    3.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN UND/ODER POLYISOCYANATEN 审中-公开
    用于生产异氰酸酯和/或多异氰酸酯

    公开(公告)号:EP2771314A1

    公开(公告)日:2014-09-03

    申请号:EP12777924.7

    申请日:2012-10-26

    Applicant: BASF SE

    CPC classification number: C07C263/10 C07C265/14

    Abstract: The invention relates to a method for producing isocyanates and/or polyisocyanates by reacting the corresponding amines with phosgene, optionally in the presence of an inert medium, in a reactor (1), wherein a first reactant stream containing the amine is fed to the reactor (1) in liquid form and a second reactant stream containing the phosgene is fed to the reactor in gaseous form. The reactor is a centrifugal reactor (1), which has a packing (9) rotating about a central axis (7) in a housing (13), the first reactant stream and the second reactant stream being fed to the rotating packing (9) in such a manner that the reactant streams are mixed and transported outward by the centrifugal force in the rotating packing (9), wherein the phosgene reacts with the amine due to the mixing in the rotating packing (9) to form the corresponding isocyanate or polyisocyanate.

    VERFAHREN ZUR HERSTELLUNG VON AROMATISCHEN ISOCYANATEN
    7.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON AROMATISCHEN ISOCYANATEN 有权
    用于生产芳族异氰酸

    公开(公告)号:EP2323973B1

    公开(公告)日:2012-03-21

    申请号:EP09781542.7

    申请日:2009-08-06

    Applicant: BASF SE

    CPC classification number: C07C263/10 C07C265/14

    Abstract: The invention relates to a method for producing isocyanates through reaction of the corresponding amines with phosgene in the liquid phase, optionally in the presence of at least one inert medium, in which first the amine and the phosgene are mixed in a mixing chamber (1) to form a reaction mixture and the reaction mixture is fed to a reactor, wherein the amine is added through an opening (3) that is disposed coaxially to the mixing chamber (1) and wherein the phosgene is added through feed openings (5) in at least two planes (7, 9) disposed perpendicular to the axis (11) of the mixing chamber (1), or the phosgene is added through the opening (3) that is coaxial to the mixing chamber and the amine is added through the feed openings (5) in at least two planes (7, 9) disposed perpendicular to the axis (11) of the mixing chamber (1). At least one plane (9) is disposed upstream in the main flow direction of the reaction mixture and at least one plane (7) is disposed downstream relative to the opening (3) disposed coaxially to the mixing chamber (1). The average residence time of the reaction mixture in the mixing chamber (1) is no more than 20 ms.

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